ChemicalBook > CAS DataBase List > 6-BROMO-O-CRESOL

6-BROMO-O-CRESOL

Product Name
6-BROMO-O-CRESOL
CAS No.
13319-71-6
Chemical Name
6-BROMO-O-CRESOL
Synonyms
6-BROMO-O-CRESOL;6-Bromo-o-cresol >6-Bromo-2-methylphenol;2-methyl-6-bromophenol;2-Bromo-6-methylphenol;6-Bromo-o-cresol;Phenol,2-broMo-6-Methyl-;2-Bromo-6-methylphenol96%;2-Bromo-6-methylphenol 96%;6-BroMo-o-cresol,2-BroMo-6-Methylphenol
CBNumber
CB21478981
Molecular Formula
C7H7BrO
Formula Weight
187.03
MOL File
13319-71-6.mol
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6-BROMO-O-CRESOL Property

Melting point:
16 °C
Boiling point:
208 °C
Density 
1.51
refractive index 
1.5680-1.5720
Flash point:
80°
storage temp. 
Inert atmosphere,Room Temperature
form 
clear liquid
pka
8.78±0.10(Predicted)
color 
Colorless to Light orange to Yellow
InChIKey
YXZPTVOCJLCMRO-UHFFFAOYSA-N
CAS DataBase Reference
13319-71-6
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Safety

HS Code 
2908190090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3126
Product name
6-Bromo-o-cresol
Purity
>94.0%(GC)
Packaging
5g
Price
$177
Updated
2025/07/31
TCI Chemical
Product number
B3126
Product name
6-Bromo-o-cresol
Purity
>94.0%(GC)
Packaging
25g
Price
$622
Updated
2025/07/31
TRC
Product number
B697420
Product name
2-Bromo-6-methylphenol
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
B697420
Product name
2-Bromo-6-methylphenol
Packaging
500mg
Price
$65
Updated
2021/12/16
Matrix Scientific
Product number
115209
Product name
2-Bromo-6-methylphenol
Purity
96+%
Packaging
1g
Price
$29
Updated
2021/12/16
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6-BROMO-O-CRESOL Chemical Properties,Usage,Production

Synthesis

95-48-7

13319-71-6

The general procedure for the synthesis of 2-bromo-6-methylphenol from o-cresol is as follows: Example 36 Synthesis of 2-bromo-6-methylphenol To a dichloromethane (500 mL) solution of o-cresol (20.0 g, 0.19 mol) and diisopropylamine (2.63 mL, 18.5 mmol), a dichloromethane (500 mL) solution of N-bromosuccinimide (NBS, 32.9 g, 0.19 mol) was slowly added dropwise, and the dropwise process lasted for 7 hours. After completion of the titration, the reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the reaction mixture was acidified to pH=1 with concentrated hydrochloric acid and subsequently diluted by adding sulfuric acid and water (400 mL). The organic layer was separated, dried with anhydrous sodium sulfate, and concentrated under reduced pressure to remove the solvent to give 34.6 g of crude product in 97% yield. The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 2.30 (s, 3H), 5.54 (s, 2H), 6.71 (t, J=7.6 Hz, 1H), 7.05 (d, J=7.6 Hz, 1H), 7.28 (d, J=8.0 Hz, 1H).

References

[1] Advanced Synthesis and Catalysis, 2008, vol. 350, # 9, p. 1309 - 1315
[2] Patent: US2009/203657, 2009, A1. Location in patent: Page/Page column 51
[3] Patent: US2009/197871, 2009, A1. Location in patent: Page/Page column 54
[4] Chemistry - A European Journal, 2018, vol. 24, # 10, p. 2379 - 2383
[5] Tetrahedron Letters, 1998, vol. 39, # 19, p. 2947 - 2950

6-BROMO-O-CRESOL Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMO-O-CRESOL Suppliers

Americas 1 China 110 Europe 1 Germany 3 India 6 Japan 1 United Kingdom 3 United States 9 Global 134
Puyang Borui Technology Development Co., Ltd
Tel
15203933070
Email
450281857@qq.com
Country
China
ProdList
96
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58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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61
Beijing Eternalchem Co,. Ltd.
Tel
010-59484199 18611897322
Email
sales@eternalchem.com
Country
China
ProdList
4383
Advantage
60
Aemon Chemical
Tel
0086-755-86198205
Email
acinfo@aemonchem.com
Country
China
ProdList
1931
Advantage
57
NovoChemy Ltd.
Tel
021-31261262/ 49 (0)17662837245
Fax
(0)21-33250524
Email
sales@novochemy.com
Country
Germany
ProdList
6328
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
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View Lastest Price from 6-BROMO-O-CRESOL manufacturers

Career Henan Chemical Co
Product
6-BROMO-O-CRESOL 13319-71-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-12

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