Terpinyl acetate

Product Name: Terpinyl acetate
CAS No.: 80-26-2
Chemical Name: Terpinyl acetate
Synonyms: Terpenyl acetate;Terpineol acetate;ALPHA-TERPINYL ACETATE;a-Terpinyl acetate;à-terpinyl acetate;p-Menth-1-en-8-yl acetate;FEMA 3047;TERPINYL ACETATE;Terpinyl Acctate;yisuansongyouzhi
CBNumber: CB2161886
Molecular Formula: C12H20O2
Formula Weight: 196.29
MOL File: 80-26-2.mol

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Terpinyl acetate Property

Melting point:: 112-113.5 °C
Boiling point:: 220 °C (lit.)
Density: 0.953 g/mL at 25 °C (lit.)
vapor pressure: 3.515Pa at 23℃
refractive index: n20/D 1.465(lit.)
FEMA: 3047 | TERPINYL ACETATE (ISOMER MIXTURE)
Flash point:: >230 °F
storage temp.: Store at -20°C
solubility: DMSO : 100 mg/mL (509.45 mM; Need ultrasonic)
form: clear liquid
color: Colorless to Almost colorless
Specific Gravity: 0.96
Odor: at 100.00 %. herbal bergamot lavender lime citrus
Odor Type: herbal
Water Solubility: 23mg/L at 23℃
JECFA Number: 368
BRN: 3198769
LogP: 4.4 at 30℃
CAS DataBase Reference: 80-26-2(CAS DataBase Reference)
NIST Chemistry Reference: 3-Cyclohexene-1-methanol, «alpha»,«alpha»,4-trimethyl-, acetate(80-26-2)
EPA Substance Registry System: .alpha.-Terpinyl acetate (80-26-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/38
Safety Statements: 26-36
WGK Germany: 2
RTECS: OT0200000
TSCA: Yes
HS Code: 29153900
Toxicity: The acute oral LD₅₀ value in rats was reported as 5.075 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W304799
Product name: α-Terpinyl acetate
Purity: FG
Packaging: 1kg
Price: $174
Updated: 2024/03/01

Sigma-Aldrich

Product number: W304799
Product name: α-Terpinyl acetate
Purity: FG
Packaging: 5kg
Price: $743
Updated: 2024/03/01

Sigma-Aldrich

Product number: W304799
Product name: α-Terpinyl acetate
Purity: FG
Packaging: 10Kg
Price: $1330
Updated: 2024/03/01

Sigma-Aldrich

Product number: 09206
Product name: (±)-α-Terpinyl acetate, predominantly α-isomer
Purity: analytical standard
Packaging: 1ml
Price: $108
Updated: 2024/03/01

TCI Chemical

Product number: T0023
Product name: Terpinyl Acetate
Purity: >85.0%(GC)
Packaging: 25mL
Price: $17
Updated: 2024/03/01

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Terpinyl acetate Chemical Properties,Usage,Production

Chemical Properties

The enantiomers and the racemate occur in many essential oils (e.g., Siberian pine-needle oil and cypress oil), but generally not as the main component. Pure Terpinyl acetate are colorless liquids with a fresh bergamot–lavender odor. Commercially available terpinyl acetate consists mainly of alpha-terpinyl acetate, but also contains a number of other isomeric compounds such as beta-terpinyl acetate. It can be prepared by acetylating the terpineol mixture obtained from terpin hydrate, using a customary procedure for tertiary alcohols.
Because of its odor properties, stability, and low price, large quantities of terpinyl acetate are used in perfumery for lavender and bergamot types, as well as in essential oil reconstitutions.

Physical properties

Terpinyl acetate is a p-menthane monoterpenoid that naturally found in melanoleuca, elettaria cardamomum. It is a colorless liquid with a bergamot, bergamot odor. Soluble in five or more volumes of 70% alcohol; slightly soluble in water and glycerol. Combustible.

Occurrence

Reported in over 40 essential oils, including cypress, Malabar cardamom, cajeput niaouli, Siberian pine needles, pine, Melaleuca trichostachya, Melaleuca pauciflora and others; also identified in the essential oils of bitter orange (Fenarolfs Handbook of Flavor Ingredients, 1971 ; Gildemeister & Hoffman, 1966). Terpinyl Acetate is found in Pine oil, Cajeput oil, Pine needle oil, Cardamom oil and other essential oils.

Uses

Perfumes, flavoring agent.

Definition

ChEBI: Alpha-Terpinyl acetate is a p-menthane monoterpenoid.

Preparation

Terpinyl acetate was successfully synthesized from (x-terpineol and acetic anhydride in supercritical carbon dioxide (SC-C02) by enzymatic catalysis.
By acetylation of a-terpineol or mixed isomeric terpineols (Bedoukian, 1967).

Synthesis Reference(s)

Tetrahedron, 38, p. 1843, 1982 DOI: 10.1016/0040-4020(82)80261-5

General Description

Α-Terpinyl acetate, a monoterpene ester, is a commercially important fragrance molecule. It can be prepared from α-pinene in the presence of H-beta zeolite catalysts. The essential oils obtained from Stachys setifera ssp. iranica, Chamaecyparis obtuse leaves and Thymus willkomii contain Α-terpinyl acetate as one of the main components.

Flammability and Explosibility

Non flammable

Safety Profile

Mildly toxic by ingestion. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

Terpinyl acetate Preparation Products And Raw materials

Raw materials

Sodium acetate Pinitol oil Acetic anhydride Turpentine oil (-)-alpha-Terpineol

Preparation Products

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Terpinyl acetate Suppliers

Brazil 1 China 229 Egypt 1 Europe 1 France 1 Germany 5 India 39 Italy 1 Japan 1 Mexico 1 Russia 1 Singapore 1 South Africa 1 South Korea 1 Spain 3 Switzerland 3 The Netherlands 1 Ukraine 1 United Kingdom 10 United States 67 USA 1 Global 370

Omega Ingredients Ltd.

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Kris Aromatics Ltd.

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OQEMA (Formerly Lansdowne Chemicals Plc)

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De Monchy Aromatics Limited

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Augustus Oils Ltd.

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R. C. Treatt & Co. Ltd.

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Claremont Chemical Company Limited

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Leancare Ltd.

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Lansdowne Chemicals Plc

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International Flavours & Fragrances I.F.F. (GB) Ltd.

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View Lastest Price from Terpinyl acetate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Terpinyl acetate 80-26-2
Price: US $100.00/kg1
Min. Order: 1kg1
Purity: 99
Supply Ability: 5000
Release date: 2024-04-28

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Terpinyl acetate 80-26-2
Price: US $0.00/KG
Min. Order: 25KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-14

Shandong Deshang Chemical Co., Ltd.

Product: Terpinyl acetate 80-26-2
Price: US $10.00-7.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 10 tons
Release date: 2024-06-19

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yisuansongyouzhi