ChemicalBook > CAS DataBase List > (R)-(-)-HEXAHYDROMANDELIC ACID

(R)-(-)-HEXAHYDROMANDELIC ACID

Product Name
(R)-(-)-HEXAHYDROMANDELIC ACID
CAS No.
53585-93-6
Chemical Name
(R)-(-)-HEXAHYDROMANDELIC ACID
Synonyms
hexahydromandelic acid;Cyclohexylglycolic acid;D-HEXAHYDROMANDELIC ACID;2-CYCLOHEXYLGLYCOLIC ACID;(R)-(-)-HEXAHYDROMANDELIC ACID;CYCLOHEXYL-HYDROXY-ACETIC ACID;R(-)-CYCLOHEXYLHYDROXYACETIC ACID;(R)-(-)-HEXAHYDROMANDELICACID[095H];ALPHA-HYDROXYCYCLOHEXANE-ACETIC ACID;(αR)-α-Hydroxycyclohexaneacetic acid
CBNumber
CB2162494
Molecular Formula
C8H14O3
Formula Weight
158.2
MOL File
53585-93-6.mol
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(R)-(-)-HEXAHYDROMANDELIC ACID Property

Melting point:
127-129 °C (lit.)
Boiling point:
319.3±15.0 °C(Predicted)
Density 
1.178±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
3.86±0.11(Predicted)
optical activity
[α]18/D 23°, c = 1 in acetic acid
BRN 
3196809
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
301140
Product name
(R)-(?)-Hexahydromandelic acid
Purity
98%, optical purity ee: 99% (GLC)
Packaging
1g
Price
$73.7
Updated
2023/06/20
AK Scientific
Product number
Z2102
Product name
(R)-(?)-Hexahydromandelic acid
Packaging
250mg
Price
$89
Updated
2021/12/16
AK Scientific
Product number
Z2102
Product name
(R)-(?)-Hexahydromandelic acid
Packaging
1g
Price
$124
Updated
2021/12/16
Crysdot
Product number
CD13011352
Product name
(R)-2-Cyclohexyl-2-hydroxyaceticacid
Purity
95+%
Packaging
1g
Price
$195
Updated
2021/12/16
AHH
Product number
MT-07216
Product name
Cyclohexylglycolicacid
Purity
98%
Packaging
0.25g
Price
$452
Updated
2021/12/16
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(R)-(-)-HEXAHYDROMANDELIC ACID Chemical Properties,Usage,Production

Uses

(R)-(?)-Hexahydromandelic acid can be used:

  • As an intermediate in the synthesis of antimycobacterial compound pyridomycin analogs.
  • As a model α-hydroxy acid compound in the chirality sensing studies of organic probes using circular dichroism technique.
  • As a starting material in the synthesis of chiral ionic liquids, which are applicable as chiral solvents in asymmetric synthesis and as chiral stationary phases in chromatographic separations.

Purification Methods

It forms hexagonal clusters on recrystallisation from CCl4 or Et2O. [Wood & Comley J Chem Soc 2638 1924, Lettré et al. Chem Ber 69 1594 1936]. The racemate has m 137.2-137.6o (134-135o) [Smith et al. J Am Chem Soc 71 3772 1949]. [Beilstein R-10 II 5; S-10 II 6.]

(R)-(-)-HEXAHYDROMANDELIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-HEXAHYDROMANDELIC ACID Suppliers

China 41 France 1 Germany 2 Switzerland 1 The Netherlands 1 United Kingdom 4 United States 12 Global 62
SIGMA-RBI
Tel
--
Fax
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Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from (R)-(-)-HEXAHYDROMANDELIC ACID manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-()-Hexahydromandelic acid 53585-93-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

53585-93-6, (R)-(-)-HEXAHYDROMANDELIC ACIDRelated Search:

PICROTOXIN PICROTOXININ OXYPHENCYCLIMINE Oxyphenonium bromide Oxybutynin hydrochloride Itrocinonide PICROTIN Cyclohexylacetic acid Nomilin OBACUNON Limonin Loteprednol AZADIRACHTIN H(SH) 2-Cyclohexylmandelic acid Azadirachtin DEACETYLNOMILIN RUTAEVIN (R)-(-)-HEXAHYDROMANDELIC ACID

  • (R)-(-)-HEXAHYDROMANDELIC ACID
  • R(-)-CYCLOHEXYLHYDROXYACETIC ACID
  • 2-CYCLOHEXYLGLYCOLIC ACID
  • ALPHA-HYDROXYCYCLOHEXANE-ACETIC ACID
  • CYCLOHEXYL-HYDROXY-ACETIC ACID
  • D-HEXAHYDROMANDELIC ACID
  • Cyclohexylglycolic acid
  • hexahydromandelic acid
  • (2R)-2-Hydroxy-2-cyclohexylacetic acid
  • (αR)-α-Hydroxycyclohexaneacetic acid
  • [R,(-)]-α-Hydroxycyclohexaneacetic acid
  • 1,2,3,4,5,6-Hexahydro-D-mandelic acid
  • (R)-(-)-HEXAHYDROMANDELICACID[095H]
  • (R)-2-cyclohexyl-2-hydroxyacetic acid
  • (R)-(-)-HexahydroMandelic acid 98%, optical purity ee: 99% (GLC)
  • Cyclohexaneacetic acid, α-hydroxy-, (αR)-
  • 53585-93-6
  • C6H11CHOHCO2H
  • Asymmetric Synthesis
  • Carboxylic Acids
  • Chiral Building Blocks
  • Organic Building Blocks