Descriptioin
ChemicalBook > CAS DataBase List > TRANS-2-HEXENAL

TRANS-2-HEXENAL

Descriptioin
Product Name
TRANS-2-HEXENAL
CAS No.
6728-26-3
Chemical Name
TRANS-2-HEXENAL
Synonyms
(E)-2-Hexenal;(E)-hex-2-enal;TRANS-2-HEXEN-1-AL;(2E)-2-Hexenal;trans-Hex-2-enal;2-Hexenal (E);trans-2-HEXANAL;(e)-2-hexena;2-(E)-hexenal;(E)-2-hexanal
CBNumber
CB2164584
Molecular Formula
C6H10O
Formula Weight
98.14
MOL File
6728-26-3.mol
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TRANS-2-HEXENAL Property

Melting point:
-78°C (estimate)
Boiling point:
47 °C17 mm Hg(lit.)
Density 
0.846 g/mL at 25 °C(lit.)
vapor density 
3.4 (vs air)
vapor pressure 
10 mm Hg ( 20 °C)
refractive index 
n20/D 1.446(lit.)
FEMA 
2560 | HEXEN-2-AL
Flash point:
101 °F
storage temp. 
2-8°C
solubility 
Acetonitrile (Slightly), Chloroform (Slightly), Methanol
form 
Liquid
color 
Clear colorless to light yellow
Odor
at 10.00 % in dipropylene glycol. green banana aldehydic fatty cheesy
Odor Type
green
Water Solubility 
Insoluble
JECFA Number
1353
BRN 
1699684
LogP
1.58 at 25℃
CAS DataBase Reference
6728-26-3(CAS DataBase Reference)
NIST Chemistry Reference
2-Hexenal, (E)-(6728-26-3)
EPA Substance Registry System
2-Hexenal, (2E)- (6728-26-3)
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Safety

Hazard Codes 
Xn,Xi,F
Risk Statements 
10-21/22-36/37/38-20/21/22-43
Safety Statements 
16-26-36-36/37
RIDADR 
UN 1988 3/PG 3
WGK Germany 
2
RTECS 
MP5900000
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29121900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H311Toxic in contact with skin

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W256009
Product name
trans-2-Hexen-1-al
Purity
natural, ≥95%, FG
Packaging
25g
Price
$132
Updated
2024/03/01
Sigma-Aldrich
Product number
W256009
Product name
trans-2-Hexen-1-al
Purity
natural, ≥95%, FG
Packaging
100g
Price
$442
Updated
2024/03/01
Sigma-Aldrich
Product number
W256009
Product name
trans-2-Hexen-1-al
Purity
natural, ≥95%, FG
Packaging
1kg
Price
$3130
Updated
2024/03/01
Sigma-Aldrich
Product number
W256005
Product name
trans-2-Hexen-1-al
Purity
≥95%, FCC, FG
Packaging
1kg
Price
$165
Updated
2024/03/01
Sigma-Aldrich
Product number
W256005
Product name
trans-2-Hexen-1-al
Purity
≥95%, FCC, FG
Packaging
4kg
Price
$454
Updated
2024/03/01
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TRANS-2-HEXENAL Chemical Properties,Usage,Production

Descriptioin

Tans-2-Hexenal is a colorless to pale yellow clear liquid. It occurs naturally in tomatoes, banana and black tea. It gives a leafy, fruity, fatty, apple banana, strawberry note.1 It is mostly used as a flavoring agent in food. It is also used in air care products, cleaning and furnishing care products, laundry and dishwashing products.

Chemical Properties

clear colorless to light yellow liquid

Chemical Properties

(E)-2-Hexenal is the simplest straight-chain unsaturated aldehyde of interest for perfumes and flavors. It occurs in essential oils obtained from green leaves of many plants.
(E)-2-Hexenal is a colorless, sharp, herbal-green-smelling liquid with a slight acrolein-like pungency. Upon dilution, however, it smells pleasantly green and apple-like. The aldehyde can be synthesized by reacting butanal with vinyl ethyl ether in the presence of boron trifluoride, followed by hydrolysis of the reaction product with dilute sulfuric acid.
Biosynthetic methods for its production as natural flavor material have been developed.
(E)-2-Hexenal has an intense odor and is used in perfumes to obtain a green-leaf note and in fruit flavors for green nuances.

Uses

Also known as “leaf aldehyde,” it is of special interest because it is naturally present in numerous fruits and is also used as a food additive for flavoring. Feron et al. identified hexenal in about 80 different types of food.

Uses

trans-2-Hexenal is used in evaluation of quality of protected designation of origin virgin olive oils by headspace solid-phase microextraction-gas chromatography using flame ionization detection and multivariate analysis. It was used in the multicomponent method for the determination of low-molecular-weight carbonyl compounds in biological samples.

Uses

trans-2-Hexen-1-al was used in evaluation of quality of protected designation of origin virgin olive oils by headspace solid-phase microextraction-gas chromatography using flame ionization detection and multivariate analysis. It was used in the multicomponent method for the determination of low-molecular-weight carbonyl compounds in biological samples.

Definition

ChEBI: A 2-hexenal in which the olefinic double bond has E configuration. It occurs naturally in a wide range of fruits, vegetables, and spices.

Synthesis Reference(s)

Journal of the American Chemical Society, 71, p. 3468, 1949 DOI: 10.1021/ja01178a061
Tetrahedron Letters, 36, p. 8513, 1995 DOI: 10.1016/0040-4039(95)01784-F

General Description

trans-2-Hexen-1-al is an important flavoring compound that occurs naturally in tomatoes, banana and black tea.

Synthesis

trans-2-HEXENAL is synthesized by the following methods: 1) by reduction of Hexenoic acid with Formic acid vapors over Manganese dioxide at 350℃. 2) by oxidation of the corresponding Hexenol. 3) by condensation of Acetaldehyde with n-Butyraldehyde.

TRANS-2-HEXENAL Preparation Products And Raw materials

Raw materials

Preparation Products

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TRANS-2-HEXENAL Suppliers

Juye Zhongyue Spices Co., Ltd
Tel
0530-8599699 13701896116
Email
liujun@zhongyuearoma.com
Country
China
ProdList
168
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
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View Lastest Price from TRANS-2-HEXENAL manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Trans-2-Hexenal 6728-26-3
Price
US $56.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-05-21
WUHAN FORTUNA CHEMICAL CO., LTD
Product
trans-2-Hexenal 6728-26-3
Price
US $0.00/kg
Min. Order
1000kg
Purity
98.0%
Supply Ability
100ton/month
Release date
2023-01-14
Shandong Deshang Chemical Co., Ltd.
Product
TRANS-2-HEXENAL 6728-26-3
Price
US $10.00-7.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-14

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