ChemicalBook > CAS DataBase List > Di(trimethylol propane)

Di(trimethylol propane)

Product Name
Di(trimethylol propane)
CAS No.
23235-61-2
Chemical Name
Di(trimethylol propane)
Synonyms
DTMP;DI-TMP;DI(TRIMETHYLOLPROPANE);Ditrimethylol;Einecs 245-509-0;Di(trimethylolpropane)>3,3,4-trimethyl-1,2-dioxetane;Perstorp Di-Trimethylolpropane;Bis (1,1,1-trimethylolpropane);Bis[2,2-di(hydroxymethyl)butyl] ether
CBNumber
CB2187026
Molecular Formula
C12H26O5
Formula Weight
250.33
MOL File
23235-61-2.mol
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Di(trimethylol propane) Property

Melting point:
108-111 °C(lit.)
Boiling point:
215 °C4 mm Hg(lit.)
Density 
1.0187 (rough estimate)
vapor pressure 
0Pa at 25℃
refractive index 
1.4560 (estimate)
solubility 
soluble in Methanol
form 
powder to crystal
pka
13.90±0.10(Predicted)
color 
White to Almost white
Water Solubility 
21g/L at 20℃
BRN 
1860782
LogP
0.88 at 25℃
EPA Substance Registry System
1,3-Propanediol, 2,2'-[oxybis(methylene)]bis[2-ethyl- (23235-61-2)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29094990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
416134
Product name
Di(trimethylolpropane)
Purity
97%
Packaging
250g
Price
$61.3
Updated
2024/03/01
Sigma-Aldrich
Product number
416134
Product name
Di(trimethylolpropane)
Purity
97%
Packaging
1kg
Price
$174
Updated
2024/03/01
TCI Chemical
Product number
D4538
Product name
Di(trimethylolpropane)
Purity
>98.0%(GC)
Packaging
25g
Price
$21
Updated
2024/03/01
TCI Chemical
Product number
D4538
Product name
Di(trimethylolpropane)
Purity
>98.0%(GC)
Packaging
500g
Price
$70
Updated
2024/03/01
TRC
Product number
D494263
Product name
Di(trimethylolpropane)
Packaging
500mg
Price
$60
Updated
2021/12/16
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Di(trimethylol propane) Chemical Properties,Usage,Production

Description

Di(trimethylol propane), Di-TMP, 2,2-[oxybis(methylene)]-bis(2-ethyl)-1,3-propanediol is a colorless and crystalline substance (mp 112 – 114 ℃), only slightly soluble in water at ambient temperature (2.6 g/100 g at 25 ℃).It is a byproduct of 2-ethyl-2-hydroxymethyl-1,3-propanediol (TMP) production and can be isolated from the residue of the TMP distillation step. Newer investigations show that ditrimethylolpropane can be prepared in high yield and selectivity by the reaction of TMP, formaldehyde, and 2-ethylacrolein.

Uses

Di(trimethylolpropane) can be used for the synthesis of lipase catalyzed hyperbranched polymers. It can also be used in the formation of biodegradable polymers for drug delivery applications.

Application

Di-trimethylolpropane is mainly used for production of acrylic monomers and oligomers for radiation-curable coatings and inks, including lithography, ink jet, and flexography inks. Di-TMP tetraacrylate has a very high reactivity, low skin irritation, and gives coatings with good scratch and chemical resistance, hence it also find uses in hard coats for electronics. Di-TMP is used as costabilizer in some lead-free PVC stabilizers based on calcium – zinc. Minor uses are in coating resins and synthetic lubricants.

Synthesis Reference(s)

Canadian Journal of Chemistry, 53, p. 1103, 1975 DOI: 10.1139/v75-154

General Description

Di(trimethylolpropane) is a monomeric unit with primary hydroxyl groups, that can be used as a tetrafunctional core molecule.

Flammability and Explosibility

Not classified

Di(trimethylol propane) Preparation Products And Raw materials

Raw materials

Preparation Products

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Di(trimethylol propane) Suppliers

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View Lastest Price from Di(trimethylol propane) manufacturers

Henan Fengda Chemical Co., Ltd
Product
Di(trimethylol propane) 23235-61-2
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28
Hebei Yanxi Chemical Co., Ltd.
Product
Di(trimethylol propane) 23235-61-2
Price
US $20.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-16
Hebei Mojin Biotechnology Co., Ltd
Product
Di(trimethylol propane) 23235-61-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-09

23235-61-2, Di(trimethylol propane)Related Search:

Methylene Blue BIS-Tris Propane Tris(hydroxymethyl)aminomethane methylol cellulose 4,4'-Diphenylmethane diisocyanate Trihydroxymethylpropyl trioleate 2-Hydroxyethyl methacrylate Trimethylolpropane Propane Methylene Chloride DI(TRIMETHYLOLPROPANE) TETRAACRYLATE DITRIMETHYLOLPROPANE TETRASTEARATE DITRIMETHYLOLPROPANE MYRISTATE/STEARATE DITRIMETHYLOLPROPANE TETRAISOSTEARATE/TETRAHYDROXY-STEARATE DITRIMETHYLOLPROPANE TETRAHYDROXYSTEARATE DITRIMETHYLOLPROPANE TETRAISOSTEARATE Di(trimethylol propane) 19-hydroxy methyl dione

  • DI(TRIMETHYLOLPROPANE)
  • DTMP
  • 2,2'-OXYBIS(METHYLENE)BIS(2-ETHYL-1,3-PROPANEDIOL)
  • 2,2’-[oxybis(methylene)]bis[2-ethyl-3-propanediol
  • 3-Propanediol,2,2’-[oxybis(methylene)]bis[2-ethyl-1
  • Ditrimethylol
  • 1,3-Propanediol, 2,2-oxybis(methylene)bis2-ethyl-
  • Perstorp Di-Trimethylolpropane
  • Bis[2,2-di(hydroxymethyl)butyl] ether
  • Einecs 245-509-0
  • Di(trimethylolpropane),2,2′-Oxybis(methylene)bis(2-ethyl-1,3-propanediol)
  • DI-TMP
  • 2,2'-[oxybis(methylene)]bis[2-ethylpropane-1,3-diol]
  • 3,3,4-trimethyl-1,2-dioxetane
  • 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol
  • Di(trimethylolpropane)&gt
  • Bis[2-ethyl-2,2-bis(hydroxymethyl)ethyl] Ether
  • Bis (1,1,1-trimethylolpropane)
  • 2,2'-(Oxybis(methylene))bis(2-ethylpropane-1,3-diol)(Flakes or Chunks)
  • 2,2'-(Oxybis(methylene))bis(2-ethylpropane-1,3-diol)
  • 2,2'-(Oxybis(methylene))bis(2-ethylpropane-1,3-diol)(Flakes or Chunks)
  • 23235-61-2
  • OCH2CC2H5CH2OH22
  • C12H26O5
  • Building Blocks
  • Organic Building Blocks
  • Polyols
  • Oxygen Compounds