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3-Morpholinone, 4-phenyl-

Product Name
3-Morpholinone, 4-phenyl-
CAS No.
29518-11-4
Chemical Name
3-Morpholinone, 4-phenyl-
Synonyms
4-Phenylmorpholin-3-one;4-Phenyl-3-morpholinone;3-Morpholinone, 4-phenyl-
CBNumber
CB21871872
Molecular Formula
C10H11NO2
Formula Weight
177.2
MOL File
29518-11-4.mol
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3-Morpholinone, 4-phenyl- Property

Melting point:
113-114℃
Boiling point:
395.2±35.0 °C(Predicted)
Density 
1.187
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly)
pka
0.27±0.20(Predicted)
form 
Solid
color 
Off-White
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Safety

HazardClass 
IRRITANT
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
P322550
Product name
4-Phenyl-3-morpholinone
Packaging
1g
Price
$155
Updated
2021/12/16
Matrix Scientific
Product number
056506
Product name
4-Phenylmorpholin-3-one
Purity
>95%
Packaging
1g
Price
$100
Updated
2021/12/16
AK Scientific
Product number
Z6138
Product name
4-Phenyl-3-morpholinone
Packaging
5g
Price
$216
Updated
2021/12/16
Matrix Scientific
Product number
056506
Product name
4-Phenylmorpholin-3-one
Purity
>95%
Packaging
5g
Price
$240
Updated
2021/12/16
Apolloscientific
Product number
OR950870
Product name
4-Phenylmorpholin-3-one
Purity
95%
Packaging
5g
Price
$370
Updated
2021/12/16
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3-Morpholinone, 4-phenyl- Chemical Properties,Usage,Production

Uses

4-Phenyl-3-morpholinone is used in studies to evaluate the bactericidal activity.

Synthesis

79-04-9

122-98-5

29518-11-4

Example 1: Preparation of 4-phenylmorpholin-3-one To a solution of N-phenylethanolamine (6.0 mL, 47.8 mmol) in isopropanol (IPA, 6 mL) heated to 40°C was added chloroacetyl chloride (11.4 mL, 143.4 mmol) and 10 N sodium hydroxide solution (29.6 mL, 296 mmol) dropwise at the same time, keeping the pH of the reaction system between 7 and 8. After dropwise addition, the reaction mixture was continued to be stirred at 40 °C for 10 min, followed by cooling to 0 °C and stirring for 1 h at that temperature. Upon completion of the reaction, the white solid product formed was collected by filtration, washed with cold water and dried to afford 4-phenylmorpholin-3-one (5.27 g, 62% yield) as a white solid. The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 7.42 (t, J = 8.0 Hz, 2H), 7.34-7.27 (m, 3H), 4.35 (s, 2H), 4.04 (t, J = 5.2 Hz, 2H), 3.77 (t, J = 5.2 Hz, 2H).

References

[1] European Journal of Medicinal Chemistry, 2015, vol. 95, p. 388 - 399
[2] Patent: WO2005/26135, 2005, A1. Location in patent: Page/Page column 6
[3] Patent: WO2011/12321, 2011, A1. Location in patent: Page/Page column 30
[4] Helvetica Chimica Acta, 2013, vol. 96, # 11, p. 2160 - 2172
[5] Patent: WO2011/80341, 2011, A1. Location in patent: Page/Page column 14; 15

3-Morpholinone, 4-phenyl- Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Morpholinone, 4-phenyl- Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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jkinfo@jkchemical.com
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China
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Beijing dtftchem Technology Co., Ltd.
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ChemStrong Scientific Co.,Ltd
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Shanghai Balmxy Pharmaceutical Co., Ltd
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View Lastest Price from 3-Morpholinone, 4-phenyl- manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
4-Phenyl-3-Morpholinone 29518-11-4
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-27
Career Henan Chemical Co
Product
3-Morpholinone,4-phenyl- 29518-11-4
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
T
Release date
2019-12-17