3-(Benzyloxy)phenol

Product Name: 3-(Benzyloxy)phenol
CAS No.: 3769-41-3
Chemical Name: 3-(Benzyloxy)phenol
Synonyms: 3-Aenzyloxyphenol;3-(benzloxy)phenol;3-(BENZYLOXY)PHENOL;TIMTEC-BB SBB008506;M-(BENZYLOXY)PHENOL;3-(Benzyloxy)phenol>MONOBENZYL RESOURCINOL;3-(phenylmethoxy)phenol;3-(Benzyloxy)phenol ,95%;Phenol, 3-(phenylmethoxy)-
CBNumber: CB2209878
Molecular Formula: C13H12O2
Formula Weight: 200.23
MOL File: 3769-41-3.mol

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3-(Benzyloxy)phenol Property

Melting point:: 50°C
Boiling point:: 200 °C / 5mmHg
Density: 1.0907 (rough estimate)
refractive index: 1.5906 (estimate)
storage temp.: Inert atmosphere,Room Temperature
form: powder to crystal
pka: 9.59±0.10(Predicted)
color: White to Almost white
CAS DataBase Reference: 3769-41-3
NIST Chemistry Reference: Benzyl 3-hydroxyphenyl ether(3769-41-3)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-41
Safety Statements: 26-36/37/39-39
HS Code: 29095000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B2070
Product name: 3-(Benzyloxy)phenol
Purity: >95.0%(GC)
Packaging: 5g
Price: $179
Updated: 2025/07/31

TCI Chemical

Product number: B2070
Product name: 3-(Benzyloxy)phenol
Purity: >95.0%(GC)
Packaging: 25g
Price: $563
Updated: 2025/07/31

TRC

Product number: B521465
Product name: 3-(Benzyloxy)phenol
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: B521465
Product name: 3-(Benzyloxy)phenol
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB147402
Product name: 3-(Benzyloxy)phenol
Packaging: 2g
Price: $89
Updated: 2021/12/16

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3-(Benzyloxy)phenol Chemical Properties,Usage,Production

Chemical Properties

White solid

Uses

3-(Benzyloxy)phenol is an isomer of benzyloxyphenol (BLP), which contains the structures 2-BLP, 3-BLP, and 4-BLP. 3-BLP is used for chromatographic identification or isomer extraction and separation studies.

Synthesis

100-39-0

108-46-3

3769-41-3

General procedure for the preparation of 3-benzyloxyphenol: Resorcinol (10.0 g, 90.9 mmol) was dissolved in acetone (50 mL) and cooled to 5-10 °C. With continuous stirring, anhydrous potassium carbonate (18.8 g, 136.3 mmol) was added. Maintaining this temperature, benzyl bromide (10.88 g, 63.6 mmol) was added slowly and the cooling bath was removed after 10 minutes. The reaction mixture was refluxed for 12 to 17 hours. After the temperature was reduced to 20 to 40°C, the solid potassium carbonate was removed by filtration. The filtrate was concentrated, poured into ice water, acidified with 6N hydrochloric acid and subsequently extracted with ethyl acetate (3 x 25 mL). The organic layers were combined, washed with water, dried over anhydrous sodium sulfate and evaporated to give a brown colloidal substance. Purification by column chromatography (230-400 mesh silica gel, eluent ethyl acetate:petroleum ether = 10:90), discarding the dibenzyloxyditerpene by-product, gave pure light brown colloidal target product 3-benzyloxyphenol. Yield: 13.5 g, 68% yield. Product characterization data: 1H NMR (CDCl3, 200MHz): δ 7.50-7.30 (m, 5H), 7.12 (t, J = 8.2Hz, 1H), 6.57 (dd, J = 1.8, 6.2Hz, 1H), 6.50-6.40 (m, 2H), 5.02 (s, 2H), 4.86 (bs, 1H, D2O exchangeable). Mass spectrum (CI): m/z 201 (M++1). IR (KBr, cm-1): 3406, 3032, 1595, 1490, 1454.

References

[1] Patent: US2014/256657, 2014, A1. Location in patent: Paragraph 0399
[2] Tetrahedron, 2007, vol. 63, # 43, p. 10698 - 10708
[3] Journal of Organic Chemistry, 1997, vol. 62, # 10, p. 3062 - 3075
[4] Journal of Medicinal Chemistry, 2004, vol. 47, # 17, p. 4155 - 4158
[5] Chemical Communications, 2018, vol. 54, # 39, p. 4935 - 4938

3-(Benzyloxy)phenol Preparation Products And Raw materials

Raw materials

Xylene Benzyl chloride Resorcinol

Preparation Products

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3-(Benzyloxy)phenol Suppliers

Americas 1 China 98 Europe 1 Germany 2 India 2 Japan 2 The Netherlands 1 United Kingdom 1 United States 14 Global 122

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TimTec Corporation

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View Lastest Price from 3-(Benzyloxy)phenol manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 3-Benzyloxyphenol 3769-41-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20t
Release date: 2024-07-14

Career Henan Chemical Co

Product: 3-Benzyloxyphenol 3769-41-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KGS
Release date: 2020-01-08

3769-41-3, 3-(Benzyloxy)phenolRelated Search:

Butylated hydroxyanisole 3-Bromophenol 3-Aminophenol Triclosan Monobenzone m-Anisyl alcohol 2-Ethoxyphenol 1,3-Dimethoxybenzene Benzylparaben 3-Hydroxybenzoic acid Guaiacol 4-Methoxybenzylchloride 3'-Hydroxypropiophenone 2-Phenylphenol Resorcinol Methylparaben 4-Hydroxybenzoic acid 4-Methoxyphenol

M-(BENZYLOXY)PHENOL

TIMTEC-BB SBB008506

RESORCINOL MONOBENZYL ETHER

Phenol, 3-(phenylmethoxy)-

MONOBENZYL RESOURCINOL

3-(Benzyloxy)phenol ,95%

3-(phenylmethoxy)phenol

3-(benzloxy)phenol

3-(BENZYLOXY)PHENOL

3-Aenzyloxyphenol

3-(Benzyloxy)phenol&gt

3-(Benzyloxy)phenol, 95%, for synthesis

3769-41-3