ChemicalBook > CAS DataBase List > 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE

Product Name
4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE
CAS No.
95740-49-1
Chemical Name
4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE
Synonyms
2-bromo-5-methylbenzyl ether;1-bromo-2-methoxy-4-methylbenzene;Benzene,1-broMo-2-Methoxy-4-Methyl-;4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE
CBNumber
CB22130017
Molecular Formula
C8H9BrO
Formula Weight
201.06
MOL File
95740-49-1.mol
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4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Property

Melting point:
104-105℃
Boiling point:
107-109℃ (11 Torr)
storage temp. 
Sealed in dry,Room Temperature
Appearance
Colorless to light yellow Liquid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
B696720
Product name
1-Bromo-2-methoxy-4-methylbenzene
Packaging
250mg
Price
$55
Updated
2021/12/16
Oakwood
Product number
038665
Product name
2-Bromo-5-methylanisole
Purity
99%
Packaging
5g
Price
$73
Updated
2021/12/16
AK Scientific
Product number
X8417
Product name
2-Bromo-5-methylanisole
Packaging
1g
Price
$81
Updated
2021/12/16
AK Scientific
Product number
X8417
Product name
2-Bromo-5-methylanisole
Packaging
5g
Price
$148
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0103790
Product name
2-BROMO-5-METHYLANISOLE
Purity
95.00%
Packaging
1G
Price
$166.95
Updated
2021/12/16
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4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Chemical Properties,Usage,Production

Synthesis

39538-68-6

95740-49-1

General procedure for the synthesis of 2-bromo-5-methylanisole from 2-methoxy-4-methylaniline: under nitrogen protection, copper bromide (4.88 g, 21.8 mmol) was dissolved in acetonitrile (20 ml), ethyl nitrite (2.13 ml, 17.9 mmol) was added, and the reaction system was subsequently slowly heated up to 65 °C and maintained. A solution of 2-methoxy-4-methylaniline (2.24 g, 16.3 mmol) in acetonitrile (20 ml) was slowly added to the above reaction mixture and stirring was continued for 15 minutes. After completion of the reaction, the solvent was removed by vacuum distillation, the residue was dissolved in cyclohexane, washed sequentially with 3 x 3 NH3 aqueous solution and water, and the organic phase was dried with anhydrous Na2SO4. The solvent was again removed by vacuum distillation, and the resulting crude product was purified by fast chromatography (with chloroform as eluent) to afford the target product 2-bromo-5-methylanisole (1.92 g, 59% yield).1H-NMR (CDCl3) δ: 2.32 (s, 3H), 3.86 (s, 3H), 6.64 (dd, J = 8.0,1.4 Hz, 1H) , 6.72 (d, J = 1.4Hz, 1H), 7.39 (d, J = 8.0Hz, 1H). 13C-NMR (CDCl3) δ: 21.4,56.1,108.3,113.1,122.5,132.9,138.7,155.6.

References

[1] Patent: WO2005/123676, 2005, A1. Location in patent: Page/Page column 36-37
[2] Patent: WO2011/15641, 2011, A1. Location in patent: Page/Page column 134
[3] Patent: US2012/316161, 2012, A1. Location in patent: Page/Page column 44
[4] Zhurnal Obshchei Khimii, 1932, vol. 2, p. 472,475
[5] Chem. Zentralbl., 1933, vol. 104, # I, p. 604

4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE Suppliers

China 87 India 3 Switzerland 1 United Kingdom 2 United States 5 Global 98
Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
Fluorochem Ltd.
Tel
--
Fax
--
Email
enquiries@fluorochem.co.uk
Country
United Kingdom
ProdList
6401
Advantage
74
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View Lastest Price from 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE manufacturers

Career Henan Chemical Co
Product
4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE 95740-49-1
Price
US $1.00/g
Min. Order
1g
Purity
98%
Supply Ability
100KG
Release date
2020-01-12
Career Henan Chemical Co
Product
4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE 95740-49-1
Price
US $9.80/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-03

95740-49-1, 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATERelated Search:

4-BROMO-2,5-DIMETHOXYPHENETHYLAMINE HCL 2,4-DIBROMO-5-METHOXYTOLUENE 4-Bromo-2,5-dimethoxybenzaldehyde 4-BROMO-3,5-DIMETHOXYBENZOIC ACID Brodimoprim 4-BROMO-3,5-DIMETHOXYBENZALDEHYDE METHYL 3,5-DIBROMO-2,4-DIMETHOXY-6-METHYLBENZOATE 4-BROMO-2,5-DIMETHOXYTOLUENE 5-BROMO-4-METHOXY-7-METHYLINDANE (+/-)-2,5-DIMETHOXY-4-BROMO-AMPHETAMINE HYDROBROMIDE 2-[(5-BROMO-7-METHYL-2,3-DIHYDRO-1H-INDEN-4-YL)OXY]ACETOHYDRAZIDE AKOS BBS-00001989 SPECS AB-131/40897143 (+/-)DOB, [PROPYL-1,2-3H]- 2,5-DIMETHOXY-4-BROMAMPHETAMIN 4-(4-BROMO-2,5-DIETHOXY-PHENYL)-THIAZOL-2-YLAMINE 2,4,6-tribromo-3,5-dimethylphenyl 4-chlorobenzenecarboxylate AKOS BBS-00001986

  • 4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE
  • 1-bromo-2-methoxy-4-methylbenzene
  • Benzene,1-broMo-2-Methoxy-4-Methyl-
  • 2-bromo-5-methylbenzyl ether
  • 95740-49-1