Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin
- Product Name
- Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin
- CAS No.
- 67217-55-4
- Chemical Name
- Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin
- Synonyms
- Mono-6-O-Tosyl-beta-Cyclodextrin;Mono(6-O-p-tolylsulfonyl)-β-cyclodextrin;6-Mono(O-toluenesulfonyl)-β-cyclodextrin;mono-(6-p-toluenesulfonyl)-β-cyclodextrin;Mono-(6-p-toluenesulfonyl)-b-cyclodextrin;Mono-6-O-(p-toluenesulfonyl)-b-cyclodextrin;Mono-6-O-(p-toluenesulfonyl)-β-cyclodextrin;6A-(4-methylbenzenesulfonate)- -Cyclodextrin;Mono-(6-p-toluenesulfonyl)-beta-cyclodextrin;β-Cyclodextrin, 6A-(4-methylbenzenesulfonate)
- CBNumber
- CB22130961
- Molecular Formula
- C49H76O37S
- Formula Weight
- 1289.17
- MOL File
- 67217-55-4.mol
Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin Property
- Melting point:
- 179 °C
- Density
- 1.591±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,2-8°C
- solubility
- Soluble in DMF, DMSO. Insoluble in water, methanol, chloroform.
- form
- Solid powder or crystals
- pka
- 12.47±0.70(Predicted)
- color
- White
- optical activity
- 111.603° (C=0.01 g/ml, DMF)
- InChIKey
- URYLJCBFCXEADB-UVTLCHRDNA-N
- CAS DataBase Reference
- 67217-55-4
Safety
- HS Code
- 9999999999
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P330Rinse mouth.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M3398
- Product name
- Mono-6-O-(p-toluenesulfonyl)-β-cyclodextrin
- Packaging
- 1G
- Price
- $171
- Updated
- 2026/04/30
- Product number
- M1381
- Product name
- Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin
- Purity
- >85.0%(HPLC)
- Packaging
- 200mg
- Price
- $355
- Updated
- 2023/06/20
- Product number
- M732785
- Product name
- Mono(6-O-p-tolylsulfonyl)-β-cyclodextrin
- Packaging
- 5mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- OM11989
- Product name
- Mono-6-O-(p-toluenesulfonyl)-b-cyclodextrin
- Packaging
- 100mg
- Price
- $85
- Updated
- 2021/12/16
- Product number
- OM11989
- Product name
- Mono-6-O-(p-toluenesulfonyl)-b-cyclodextrin
- Packaging
- 500mg
- Price
- $225
- Updated
- 2021/12/16
Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin Chemical Properties,Usage,Production
Uses
Mono(6-O-p-tolylsulfonyl)-β-cyclodextrin (CAS# 67217-55-4) is carbohydrate used in the preparation of electroactive polyaniline/silica hybrid sol-gels. Recently, mono(6-O-p-tolylsulfonyl)-β-cyclodextrin has been proposed for use as a catalyst for atmospheric CO2 fixation by conversion to cuclic carbonate.
Synthesis
2232-08-8
7585-39-9
67217-55-4
The general procedure for the synthesis of mono-6-O-(p-toluenesulfonyl)-β-cyclodextrin from 1-(p-toluenesulfonyl)imidazole and β-cyclodextrin was as follows: in a 1L two-necked round-bottomed flask, β-cyclodextrin (40.0 g, 35.2 mmol) was dissolved in 450 mL of deionized water at 60°C with vigorous stirring until complete dissolution. To the resulting emulsion suspension was added 1-(p-toluenesulfonyl)-imidazole (12 g, 54 mmol). After the reaction mixture was stirred for 2 hours, a 25 mL aqueous solution of sodium hydroxide (9 g, 225 mmol) was slowly added (about 20 minutes to complete the drop). After continued stirring for 20 minutes, unreacted 1-(p-toluenesulfonyl)-imidazole was removed by filtration through a sintered glass funnel. Subsequently, ammonium chloride (24.1 g, 900 mmol) was added to the reaction solution to quench the reaction and all solids were dissolved by rotary evaporation. The reaction mixture was concentrated to half the original volume by blowing a stream of air over its surface. The resulting suspension was filtered through a large sintered glass funnel and the collected solids were washed sequentially with ice water (2 x 100 mL) and acetone (1 x 200 mL), and finally dried in a vacuum desiccator with CaCl2 as the drying agent to constant weight. The product 20.63 g was obtained in 45.39% (16 mmol) yield.
References
[1] Tetrahedron Letters, 2013, vol. 54, # 25, p. 3268 - 3273
[2] Synthetic Communications, 2014, vol. 44, # 5, p. 589 - 599
[3] Green Chemistry, 2014, vol. 16, # 6, p. 3117 - 3124
[4] Carbohydrate Research, 2016, vol. 430, p. 85 - 94
[5] Organic Syntheses, 2000, vol. 77, p. 225 - 225
Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin Preparation Products And Raw materials
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View Lastest Price from Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin manufacturers
- Product
- Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin 67217-55-4
- Price
- US $0.00/g
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- 1000g
- Release date
- 2021-08-25
- Product
- Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin 67217-55-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-16
- Product
- Mono-6-O-(p-toluenesulfonyl)-beta-cyclodextrin 67217-55-4
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1000kg
- Release date
- 2023-03-27