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Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin

Product Name
Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin
CAS No.
160661-60-9
Chemical Name
Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin
Synonyms
Per-6-thio-β-cyclodextrin;Heptakis(6-deoxy-6-thio)-beta-cyclodextrin;Seven (6-Mercapto-6-Deoxy) Beta Cyclodextrin;Heptakis-(6-Mercapto-6-deoxy)-β-Cyclodextrin;Heptakis-(6-Mercapto-6-deoxy)-β-Cyclodextrin;β-Cyclodextrin,6A,6B,6C,6D,6E,6F,6G-heptathio;Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin;cyclodextrin Heptakis-(6-mercapto-6-deoxy)-β-cyclodextrin
CBNumber
CB03054028
Molecular Formula
C42H70O28S7
Formula Weight
1247.41
MOL File
160661-60-9.mol
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Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin Property

Boiling point:
1502.1±60.0 °C(Predicted)
Density 
1.531±0.06 g/cm3(Predicted)
solubility 
Soluble in DMF, DMSO. Insoluble in water, acetone, methanol, chloroform.
form 
Solid powder
pka
8.58±0.10(Predicted)
color 
Off-white
CAS DataBase Reference
160661-60-9
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Safety

HS Code 
9999999999
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Biosynth Carbosynth
Product number
OD44682
Product name
6-Deoxy-6-thio-b-cyclodextrin
Packaging
250mg
Price
$125
Updated
2021/12/16
Biosynth Carbosynth
Product number
OD44682
Product name
6-Deoxy-6-thio-b-cyclodextrin
Packaging
500mg
Price
$225
Updated
2021/12/16
Biosynth Carbosynth
Product number
OD44682
Product name
6-Deoxy-6-thio-b-cyclodextrin
Packaging
1g
Price
$425
Updated
2021/12/16
Biosynth Carbosynth
Product number
OD44682
Product name
6-Deoxy-6-thio-b-cyclodextrin
Packaging
2g
Price
$825
Updated
2021/12/16
Biosynth Carbosynth
Product number
OD44682
Product name
6-Deoxy-6-thio-b-cyclodextrin
Packaging
5G
Price
$1475
Updated
2021/12/16
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Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin Chemical Properties,Usage,Production

Description

Heptakis-(6-azido-6-deoxy)-beta-cyclodextrin is an useful reactant for preparation for cyclodextrin amino acid derivatives.

Uses

Addition of Per-6-thio-β-cyclodextrin to a colloidal dispersion of Au nanoparticles results in the attachment of thiolated cyclodextrins to the Au particles.

Uses

Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin(Cas#160661-60-9)is a modified beta-cyclodextrin as a reagent in lab& research institution. Sulphur is lively group by oxidation or replace to create higher levels of supramolecular structure.Mercaptoacetic extremely easy adherent to gold surface, thus realize novel applications.Mercaptoacetic cyclodextrins derivatives extremely suitable for drug induction of anesthesia neuromuscular reversal.

Synthesis


The thiuronium salt (12.2 g, 0.005 mol) was heated around 100 ??C in deoxygenated (He/ultrasound) 0.25 M NaOH (120 mL) for 4 h. As the reaction was completed the reaction mixture was cooled to around 5-10 ??C and the pH was adjusted to 1.0-1.5 with 3 M HCl solution, when the product started to crystallize. As the pH became stable, the suspension was allowed to crystallize for 15 min, the solids were removed by filtration, washed with deoxygenated deionized water to around pH 5-6, then dried in vacuo at rt in the presence of P2O5 and KOH, and yielded 6.5 g of dark orange, glassy crystals. The obtained product was recrystallized by dissolution in deoxygenated 1 M NaOH solution (12 mL) and precipitated with 1 M HCl (18 mL). Filtration and washing to neutral pH with deoxygenated water afforded 3.8 g (61% theor.) light orange crystals. RF = 0.00-0.05 10:7 dioxane/cc. NH3.3.5. Regeneration of thiol group from its oxidized statePartially oxidized heptakis(6-deoxy-6-thio)cyclomaltoheptaose (6.2 g, approx. 0.010 mol) was suspended in deoxygenated water and deoxygenated (He/ultrasound) 3 M NaOH solution (30 mL) was added at rt. Sodium borohydride (1.1 g, 0.030 mol) is added and stirred overnight. The occasionally found solids were filtered through a sintered glass funnel, the filtrate was cooled with an ice-water bath and the pH was adjusted to around 1.5-2 with 3 M HCl solution (approx. 45 mL). Upon acidification the product started to crystallize, and as the pH became stable and foaming stopped, the suspension was allowed to crystallize for an additional 15 min. The product was removed by filtration and washed to pH 5-7 with deoxygenated deionized water, then dried in vacuo at rt in the presence of P2O5 and KOH, yielded 3.2 g (50%) |?-CDSH as a yellowish substance.

Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin Preparation Products And Raw materials

Raw materials

Preparation Products

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Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin Suppliers

Tocopharm Co., Ltd.
Tel
+86-021-69895597 13776836200 +86-13776836200
Fax
021-61292409
Email
tocopharm@gmail.com
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China
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190
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55
Shanghai DiBai Chemicals Co., Ltd.
Tel
021-54359730 400-008-9730
Fax
021-54353864
Email
info@chemxyz.com
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China
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3991
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Shanghai Macklin Biochemical Co.,Ltd.
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15221275939 15221275939
Fax
021-50706099
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shenlinxing@macklin.cn
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China
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16166
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Anhui Shixing Chemical Co., Ltd.
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0551-65361219 17756579152
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0551-65361219
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hfchuandi@163.com
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China
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Amadis Chemical Company Limited
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571-89925085
Fax
0086-571-89925065
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sales@amadischem.com
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China
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131957
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Zhengzhou Huiju Chemical Co., Ltd.
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0371-55900031 18137872243
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QQ:2853979815
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2853979815@qq.com
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China
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10001
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Aikon International Limited
Tel
025-66113011 18112977050
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
16027
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58
Linyi Azelasi Biological Co., Ltd.
Tel
17753923223
Fax
0539-6222546
Email
2805221329@qq.com
Country
China
ProdList
1474
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58
Cool Pharm, Ltd
Tel
18019463053
Fax
021-50966098
Email
sales@coolpharm.com
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China
ProdList
13010
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58
Beijing Minruida Technology Co., Ltd.
Tel
010-82387566 18001021521;
Fax
82387566-801
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sales@mreda.com.cn
Country
China
ProdList
10789
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View Lastest Price from Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin 160661-60-9
Price
US $0.00/g
Min. Order
1g
Purity
98%min
Supply Ability
1000g
Release date
2022-12-27
Henan Aochuang Chemical Co.,Ltd.
Product
Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin 160661-60-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-16
Shandong Binzhou Zhiyuan Biotechnology Co., Ltd.
Product
Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin 160661-60-9
Price
US $150.00-0.00/g
Min. Order
1g
Purity
>98%
Supply Ability
1000g
Release date
2020-01-17

160661-60-9, Heptakis-(6-Mercapto-6-deoxy)-beta-CyclodextrinRelated Search:


  • Heptakis-(6-Mercapto-6-deoxy)-beta-Cyclodextrin
  • β-Cyclodextrin,6A,6B,6C,6D,6E,6F,6G-heptathio
  • Heptakis-(6-Mercapto-6-deoxy)-β-Cyclodextrin
  • Heptakis(6-deoxy-6-thio)-beta-cyclodextrin
  • Per-6-thio-β-cyclodextrin
  • Heptakis-(6-Mercapto-6-deoxy)-β-Cyclodextrin
  • Seven (6-Mercapto-6-Deoxy) Beta Cyclodextrin
  • cyclodextrin Heptakis-(6-mercapto-6-deoxy)-β-cyclodextrin
  • 160661-60-9
  • C42H70O28S7