ChemicalBook > CAS DataBase List > N-Cyanoimido-S,S-dimethyl-dithiocarbonate

N-Cyanoimido-S,S-dimethyl-dithiocarbonate

Product Name
N-Cyanoimido-S,S-dimethyl-dithiocarbonate
CAS No.
10191-60-3
Chemical Name
N-Cyanoimido-S,S-dimethyl-dithiocarbonate
Synonyms
Dimethyl cyanocarbonimidodithioate;DIMETHYL N-CYANODITHIOIMINOCARBONATE;DIMETHYL CYANODITHIOIMINOCARBONATE;N-Cyano-S;AKOS 91434;N-Cyanoimido-S;N-Cyanoimido-S,S-dim;α-mercaptoacetic aci;DIMETHYL-N-CYANOTHIOCARBONATE;DIMETHYL CARBODITHIOCYANAMATE
CBNumber
CB2234726
Molecular Formula
C4H6N2S2
Formula Weight
146.23
MOL File
10191-60-3.mol
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N-Cyanoimido-S,S-dimethyl-dithiocarbonate Property

Melting point:
45-50 °C (lit.)
Boiling point:
229.6±23.0 °C(Predicted)
Density 
1.298 (estimate)
refractive index 
1.5000 (estimate)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Slightly soluble in methanol.
form 
solid
pka
-5.10±0.50(Predicted)
Appearance
White to off-white Solid
BRN 
635998
InChI
InChI=1S/C4H6N2S2/c1-7-4(8-2)6-3-5/h1-2H3
InChIKey
IULFXBLVJIPESI-UHFFFAOYSA-N
SMILES
C(=N/C#N)(/SC)\SC
CAS DataBase Reference
10191-60-3(CAS DataBase Reference)
NIST Chemistry Reference
N-Cyano-s,s'-dimethyldithioimido carbonate(10191-60-3)
EPA Substance Registry System
Carbonimidodithioic acid, cyano-, dimethyl ester (10191-60-3)
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Safety

Hazard Codes 
C,T
Risk Statements 
22-34-23/24/25-36/37
Safety Statements 
26-36/37/39-45-38-28A-7/9
RIDADR 
UN 1759 8/PG 2
WGK Germany 
3
F 
13-19
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
249637
Product name
Dimethyl N-cyanodithioiminocarbonate
Purity
90%
Packaging
50g
Price
$164
Updated
2025/07/31
Sigma-Aldrich
Product number
249637
Product name
Dimethyl N-cyanodithioiminocarbonate
Purity
90%
Packaging
250g
Price
$873
Updated
2023/06/20
TCI Chemical
Product number
D1798
Product name
S,S'-Dimethyl N-Cyanodithioiminocarbonate
Purity
>98.0%(N)
Packaging
25g
Price
$46
Updated
2025/07/31
TCI Chemical
Product number
D1798
Product name
S,S'-Dimethyl N-Cyanodithioiminocarbonate
Purity
>98.0%(N)
Packaging
250g
Price
$180
Updated
2025/07/31
Usbiological
Product number
269249
Product name
N-Cyanoimido-S,S-dimethyl-dithiocarbonate
Packaging
25g
Price
$319
Updated
2021/12/16
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N-Cyanoimido-S,S-dimethyl-dithiocarbonate Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline powder

Uses

Dimethyl cyanodithioiminocarbonate has been used in the synthesis of 4-methylthiopyrazolo[1,5-a]-1,3,5-triazines, methylsulfanylpyrimidines, cyanoguanidines and N-aryl-6-methylsulfanyl-4-oxopyrimidine-5-carbonitriles. It has been also used in the synthesis of methylsulfanyl derivatives of azoloazines and azoloazoles.

Synthesis

75-15-0

420-04-2

74-88-4

10191-60-3

Dimethyl N-cyanoimido-S,S-dithiocarbonate was synthesized according to the method reported in the literature. The procedure was as follows: cyanamide (0.02 mol, 50% aqueous solution) was dissolved in 80 mL of water, followed by addition of potassium hydroxide (0.04 mol) and stirred for 45 min at room temperature. Carbon disulfide was then added and the reaction mixture was heated to 40°C. After complete dissolution of carbon disulfide (about 2 hours), iodomethane (0.04 mole) was added and stirred overnight at room temperature. After completion of the reaction, the precipitate was collected by filtration, the solid product was washed with water, dried under vacuum at room temperature to constant weight and finally purified by recrystallization from ethanol. The resulting product was dimethyl cyanodithioiminocarbonate (1c) in 71% yield with a melting point of 58-60°C. Infrared spectra (FT-IR, ν/cm?1): 1678, 2176. nuclear magnetic resonance hydrogen spectra (1H NMR, 300 MHz, DMSO-d6) δ: 2.90 (s, 6H, 2×SCH3). NMR carbon spectra (13C NMR, 75 MHz, CDCl3) δ: 18.8, 115.3, 186.8.

References

[1] Tetrahedron, 2008, vol. 64, # 39, p. 9309 - 9314
[2] Phosphorus, Sulfur and Silicon and the Related Elements, 2016, vol. 191, # 5, p. 759 - 764
[3] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988, p. 2309 - 2314
[4] Synthetic Communications, 2004, vol. 34, # 5, p. 805 - 815
[5] Synthetic Communications, 2006, vol. 36, # 6, p. 743 - 753

N-Cyanoimido-S,S-dimethyl-dithiocarbonate Preparation Products And Raw materials

Raw materials

Calcium cyanamide Potassium hydroxide Carbon disulfide Methanol Diisopropyl ether Isopropyl alcohol Cyanamide Dimethyl sulfate

Preparation Products

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N-Cyanoimido-S,S-dimethyl-dithiocarbonate Suppliers

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View Lastest Price from N-Cyanoimido-S,S-dimethyl-dithiocarbonate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
N-Cyanoimido-S,S-dimethyl-dithiocarbonate 10191-60-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-31
Hebei Chuanghai Biotechnology Co., Ltd
Product
N-Cyanoimido-S,S-dimethyl-dithiocarbonate 10191-60-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-29
Career Henan Chemical Co
Product
N-Cyanoimido-S,S-dimethyl-dithiocarbonate 10191-60-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
25kg
Release date
2019-07-11

10191-60-3, N-Cyanoimido-S,S-dimethyl-dithiocarbonateRelated Search:

ALTRENOGEST Dimethyl disulfide N,N-Dimethylformamide ISOMETHIOZIN ETHANE Dimethyl phthalate Dimethyl sulfate Dimethyl sulfoxide Glycine Dacthal Dimethyl fumarate Dimethyl ether Dimethyl carbonate Cimetidine 4,4'-Diphenylmethane diisocyanate Methylene Blue Dimethoxymethane ETHYL 2-CYANOACRYLATE

  • s,s-dimethyl cyanoimidodithiocarbonate
  • S,S'-DIMETHYL N-CYANODITHIOIMINOCARBONATE
  • N-CYANO-S,S'-DIMETHYLDITHIOIMIDOCARBONATE
  • N-CYANO-S,S-DIMETHYLDITHIOIMIDOCARBONATE
  • N-CYANOIMIDO-S,S-DIMETHYL-DITHIOCARBONATE
  • (Cyanoimino)bis(methylthio)methane
  • Carbonimidodithioic acid, cyano-, dimethyl ester
  • Carbonimidodithioicacid,cyano-,dimethylester
  • cyano-carbonimidodithioicacidimethylester
  • Cyanodithioimidocarbonic acid, dimethyl ester
  • Cyanoiminodithiocarbonicdimethylester
  • Dimethyl cyanimidodithiocarbonate
  • Dimethyl cyanocarbonimidodithioate
  • Dimethyl cyanodithioimidocarbonate
  • Dimethyl N-cyanoimidodithiocarbonate
  • Dimethylcyaniminodithiocarbonate
  • dimethylcyanocarbonimidodithioate
  • Dimethylcyanoimidothiocarbonate
  • Imidocarbonic acid, cyanodithio-, dimethyl ester
  • n-cyanoimido-s,s-dimethyl-dithiocarbonate,remainderwater
  • S,S-Dimethyl (N-cyanoimido)dithiocarbonate
  • S,S-Dimethyl cyaniminodithiocarbamate
  • N-CYANOIMIDO-S,S-DIMETHLDITHIOCARBONATE
  • DIMETHYL N-CYANODITHIOMINOCARBONATE
  • DIMETHYL-N-CYANOTHIOCARBONATE
  • S,S-DIMETHYL-N-CYANODITHIOIMINO CARBONATE [DIMETHYL-N-CYANOTHIOCARBONATE]CIMETIDINE
  • Dimethyl cyanocarbonodithioimidoate
  • Dimethyl cyanodithioiminocarbonate, 90+%, remainder water
  • Dimethyl cyanodithioiminocarbonate, 90+%
  • Bis(methylthio)(cyanoimino)methane
  • N-[Bis(methylthio)methylene]cyanamide
  • N-Cyanoimidodithiocarbonic acid dimethyl ester
  • N-Cyanoimidodithiocarbonic acid S,S-dimethyl ester
  • N-Cyanoimido-S,S-dimethyl-dithiocarbonate,ca.90%,remainder water
  • Dimethyl cyanodithioiminocarbonate ,98%
  • N-Cyano-S
  • S'-diMethyldithioiMidocarbonate
  • Dimethyl N-cyanocarbonodithioimidate
  • N-Cyanoimido-S,S-dim
  • DiMethyl CyanocarboniMinodithioate
  • Dimethyl N-Cyanodithioimino- Carbonate (CCITM)
  • N-N-Cyanoimido-S,S-dimethyl-dithiocarbonate
  • DIMETHYL N-CYANODITHIOIMINOCARBONATE
  • DIMETHYL CYANODITHIOIMINOCARBONATE
  • DIMETHYL CYANO IMIDO DITHIO CARBONATE
  • DIMETHYL CYANOIMINODITHIOCARBONATE
  • DIMETHYL CARBODITHIOCYANAMATE
  • [[BIS(METHYLTHIO)METHYLENE]AMINO](NITRILO)METHANE
  • AKOS 91434
  • Cyanoimidodithiocarbonic Acid S,S-Dimethyl Ester
  • DIMETHYL N-CYANODITHIOIMINOCARBONATE, 90 %
  • Dimethyl cyanodithioiminocarbonate, tech.
  • N-Cyanoimido-S,S-dimethyl-dithiocarbonate, remainder water, ca. 90%
  • DiMethyl cyanocarboniMido-dithionate
  • CarboniMidodithioic acid,N-cyano-,diMethyl ester
  • FREE SAMPLE NCV DIMETHYL N-CYANODITHIOIMINOCARBONATE
  • dimethyl n-cyanodithiocarbonimidate
  • Dimethyl <i>N</i>-cyanodithioiminocarbonate