ChemicalBook > CAS DataBase List > 1,2-Epoxyhexane

1,2-Epoxyhexane

Product Name
1,2-Epoxyhexane
CAS No.
1436-34-6
Chemical Name
1,2-Epoxyhexane
Synonyms
BUTYLOXIRAN;BUTYLOXIRANE;HEXYLENEOXIDE;2-Butyloxirane;1,2-EPOXYHEXAN;1-HEXENE OXIDE;Epoxy-n-hexane;Hexene epoxide;n-butyloxirane;1,2-EPOXYHEXANE
CBNumber
CB2236083
Molecular Formula
C6H12O
Formula Weight
100.16
MOL File
1436-34-6.mol
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1,2-Epoxyhexane Property

Melting point:
94°C
Boiling point:
118-120 °C(lit.)
Density 
0.833 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.406
Flash point:
60 °F
storage temp. 
2-8°C
solubility 
Difficult to mix.
form 
Liquid
Specific Gravity
0.831
color 
Clear colorless
BRN 
102568
InChI
InChI=1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3
InChIKey
WHNBDXQTMPYBAT-UHFFFAOYSA-N
SMILES
O1CC1CCCC
LogP
1.950
CAS DataBase Reference
1436-34-6(CAS DataBase Reference)
EPA Substance Registry System
Oxirane, butyl- (1436-34-6)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-22-36/37/38
Safety Statements 
26
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
RTECS 
MO3630000
F 
10-21
HazardClass 
3
PackingGroup 
III
HS Code 
29109000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
377171
Product name
1,2-Epoxyhexane
Purity
97%
Packaging
25g
Price
$67.7
Updated
2024/03/01
Sigma-Aldrich
Product number
377171
Product name
1,2-Epoxyhexane
Purity
97%
Packaging
100g
Price
$235
Updated
2024/03/01
TCI Chemical
Product number
E0445
Product name
1,2-Epoxyhexane
Purity
>96.0%(GC)
Packaging
25mL
Price
$58
Updated
2024/03/01
Alfa Aesar
Product number
L07609
Product name
1,2-Epoxyhexane, 96%
Packaging
25g
Price
$58.4
Updated
2024/03/01
Alfa Aesar
Product number
L07609
Product name
1,2-Epoxyhexane, 96%
Packaging
100g
Price
$171
Updated
2024/03/01
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1,2-Epoxyhexane Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

1,2-Epoxyhexane is used as chemical reagent, organic intermediates, fine chemicals, pharmaceutical research and development.

Application

1,2-Epoxyhexane could used as a passivating agent for core–shell aluminum nanoparticles with very high active aluminum content[1].

Synthesis

A method for preparing 1,2-epoxyhexane using a fixed-bed microchannel reaction device is as follows: dissolve 1-hexene in a solvent to prepare a 1-hexene solution, and then dissolve an oxidizing reagent in the solvent to prepare an oxidizing reagent solution. Add the solid catalyst into the fixed-bed microchannel reaction device. Pump the 1-hexene and oxidizing reagent solution configured above into the fixed-bed microchannel reaction device respectively, maintain the reaction residence time for 8-25 minutes, and the upper organic phase enters the continuous centrifuge. The product is obtained after continuous water washing.

storage

Keep container tightly closed. Store away from oxidizing agents.

Purification Methods

Purify it by fractional distillation through a 2ft helices-packed column at atmospheric pressure in a N2 atmosphere. [Pasto & Cumbo J Org Chem 30 1271 1965, Howarth et al. J Chem Soc 2433 1927, 13C NMR Davies & Witham J Chem Soc Perkin Trans 2 861 1975, Beilstein 17/1 V 103.]

References

[1] Paul A. Jelliss . “The use of 1,2-epoxyhexane as a passivating agent for core–shell aluminum nanoparticles with very high active aluminum content.” Solid State Sciences 23 (2013): Pages 8-12.

1,2-Epoxyhexane Preparation Products And Raw materials

Raw materials

1-Hexene 3-Chloroperoxybenzoic acid Peroxyacetic acid Diethyl ether Dichloromethane

Preparation Products

gamma-Octanoic lactone
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1,2-Epoxyhexane Suppliers

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Wuhan Huahan Dingcheng New Material Technology Co., Ltd
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View Lastest Price from 1,2-Epoxyhexane manufacturers

Henan Fengda Chemical Co., Ltd
Product
1,2-EPOXYHEXANE 1436-34-6
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26

1436-34-6, 1,2-EpoxyhexaneRelated Search:

6-BROMO-1,2-EPOXYHEXANE,1-Bromo-5,6-epoxyhexane HEXAMETHYLENE OXIDE 4,4,5,5,6,6,6-HEPTAFLUORO-1,2-EPOXYHEXANE S-1,2-EPOXYHEXANE (2S,3S)-2,3-Epoxyhexane-1-ol 1H,1H,2H-NONAFLUORO-1,2-EPOXYHEXANE (R)-(+)-1,2-EPOXYHEXANE (2R,3R)-1-[(tert-Butyldimethylsilyl)oxy]-2,3-epoxyhexane (2R,3R)-1-(Benzyloxy)-2,3-epoxyhexane 3,3,4,4,5,5,6,6,6-Nonafluoro-1,2-epoxyhexane (R)-(-)-2-METHYL 1,2-EPOXYHEXANE 6H-PERFLUORO-1,2-EPOXYHEXANE (2S,3S)-1-Acetoxy-2,3-epoxyhexane (2R,3R)-1-Acetoxy-2,3-epoxyhexane (2S,3S)-1-(Benzyloxy)-2,3-epoxyhexane 3,4-Epoxyhexane (2S,3S)-1-[(tert-Butyldimethylsilyl)oxy]-2,3-epoxyhexane

  • BUTYLOXIRAN
  • BUTYLOXIRANE
  • 1-HEXENE OXIDE
  • 1,2-HEXYLENE OXIDE
  • 1,2-EPOXYHEXAN
  • 1,2-EPOXYHEXANE
  • 1,2-Hexene oxide
  • 1,2-hexeneoxide
  • 1-Hexene epoxide
  • 1-hexeneepoxide
  • 2-Butyloxirane
  • 2-butyl-oxirane
  • Epoxy-n-hexane
  • Hexane, 1,2-epoxy-
  • Hexene 1,2-oxide
  • 1,2-EPOXYHEXANE 96+%
  • 1,2-Hexane oxide
  • Hexene epoxide
  • n-butyloxirane
  • HEXYLENEOXIDE
  • 1,2-Epoxyhexane, GC 97%
  • 1,2-Epoxyhexane, 97% 25ML
  • 1,2-Epoxyhexane, 1-Hexene oxide
  • 1-Hexene oxide, Butyloxirane
  • 1,2-Epoxyhexane,97%
  • 1,2-Epoxyhexane&gt
  • Oxirane, 2-butyl-
  • 1,2-EPOXYHEXANE ISO 9001：2015 REACH
  • 1436-34-6
  • Simple 3-Membered Ring Compounds
  • Oxiranes
  • Epoxides
  • Organic Building Blocks
  • Oxygen Compounds
  • Building Blocks
  • Oxiranes
  • Simple 3-Membered Ring Compounds