ChemicalBook > CAS DataBase List > Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate

Product Name: Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
CAS No.: 147531-11-1
Chemical Name: Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
Synonyms: Diphenyl(trifluoromethyl);diphenyl(trifluoromethyl)sulfanium;sulfonium trifluoromethanesulfonate;diphenyl-(trifluoroMethyl)-sulfoniuM;(S)-(trifluoroMethyl)diphenylsulfoniuM triflate;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat;diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate;diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate;Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate
CBNumber: CB22470708
Molecular Formula: C13H10F3S.CF3O3S
Formula Weight: 404.35
MOL File: 147531-11-1.mol

Less

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Property

Melting point:: 84-85 °C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: Light brown to brown Solid
InChI: InChI=1S/C13H10F3S.CHF3O3S/c14-13(15,16)17(11-7-3-1-4-8-11)12-9-5-2-6-10-12;2-1(3,4)8(5,6)7/h1-10H;(H,5,6,7)/q+1;/p-1
InChIKey: YHEBUXDOUNWVNZ-UHFFFAOYSA-M
SMILES: C(F)(F)(F)S(=O)(=O)[O-].C1=CC=CC([S+](C(F)(F)F)C2C=CC=CC=2)=C1

Less

Safety

Risk Statements: 36/37/38
Safety Statements: 26-36
HS Code: 29339900

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P501Dispose of contents/container to..…

Less

N-Bromosuccinimide Price

TRC

Product number: D492063
Product name: Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: D492063
Product name: Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Packaging: 500mg
Price: $220
Updated: 2021/12/16

ChemScene

Product number: CS-0049606
Product name: Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Purity: >97.0%
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Apolloscientific

Product number: PC905034
Product name: Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Purity: 98%
Packaging: 250mg
Price: $77
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK1415797
Product name: Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Purity: 99%
Packaging: 100mg
Price: $120
Updated: 2021/12/16

Less

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Chemical Properties,Usage,Production

Uses

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate can be used as a raw material for organic synthesis with styrene derivatives to synthesise 2-arylazo pyridine at low temperature^[1].

Synthesis

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate is synthesised using phenyl trifluoromethyl sulfoxide as a raw material by chemical reaction. The specific synthesis steps are as follows:
Trifluoromethyl sulfoxide (0.4 g, 2.1 mmol) and then benzene (4.9 g, 64 mmol) are introduced, under an inert atmosphere and at approximately 0° C. (lower limit below which benzene crystallizes), into a Schlenck tube purged beforehand with argon. Five equivalents of triflic anhydride (2.82 g, 10 mmol) are gradually added. The mixture is stirred for 1 h at 0° C. and then for 24 h at ambient temperature. The medium is evaporated and the residue is purified by chromatography with the CH3CN/CH2Cl2 (1/4) mixture as eluent. White crystals (Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate), having a melting point of 69-70° C., are obtained with a yield of 40%.

References

[1] J. MATSUO. A Convenient Method for the Synthesis of 2-Arylaziridines from Styrene Derivatives via 2-Arylethenyl(diphenyl)sulfonium Salts[J]. Chemistry Letters, 2003. DOI:10.1246/CL.2003.392.

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

Less

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Suppliers

China 92 India 1 United States 10 Global 103

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Xi 'an billiton biological technology co., LTD

Tel: 029-88764766 18191268030
Email: wang.yali@xatuochao.com
Country: China
ProdList: 287
Advantage: 58

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

Tongchuang Pharma(Suzhou). Co., Ltd.

Tel: 0512-63263366 18912765016
Fax: 0512-6326 3366
Email: tongtf110@sina.com
Country: China
ProdList: 993
Advantage: 62

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9510
Advantage: 58

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 150-2103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9342
Advantage: 55

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Country: China
ProdList: 2930
Advantage: 58

SHANG FLUORO

Tel: 021-65170832 15601903708
Email: qinba_1@163.com
Country: China
ProdList: 399
Advantage: 60

JW & Y Pharmlab Co., Ltd.

Tel: 021-64340559 13651849907;
Fax: 021- 64345308
Email: xinyu_shi@jwypharmlab.com.cn
Country: China
ProdList: 12000
Advantage: 58

SPIRO PHARMA

Tel
Fax: -
Email: eric_feng1954@126.com
Country: China
ProdList: 9248
Advantage: 55

Taizhou Ruixin Chemical Co., Ltd.

Tel: 0576-89085261 15867635987
Fax: 0576-89085262
Email: jasonhu09@163.com
Country: China
ProdList: 442
Advantage: 50

AgileBioChem Co., Ltd.

Tel: 18055517827
Email: sales@agilebiochem.com
Country: China
ProdList: 1003
Advantage: 50

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Cangzhou Enke Pharma-tech Co., Ltd.

Tel: 0317-5296180 15533709196
Fax: 0317-5106596
Email: sale@enkepharma.com
Country: China
ProdList: 2267
Advantage: 55

Zhengzhou Acme Chemical Co., Ltd.

Tel: 0371-0371-55629727 13323845623
Fax: 037155629727
Email: 2885676761@qq.com
Country: China
ProdList: 10110
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 021-021-52271985 17721149837
Fax: +86 (21) 52271987
Email: sales@9dingchem.com
Country: China
ProdList: 19800
Advantage: 60

Aikon International Limited

Tel: 025-66113011 13155353615
Fax: (7)02557626880
Email: qzhang@aikonchem.com
Country: China
ProdList: 15394
Advantage: 58

3A Chemicals

Tel: 400-668-9898
Fax: 010-51582189
Email: service@3achem.com
Country: China
ProdList: 20557
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Xi 'an fuchen biotechnology co., LTD

Tel: 13679166801
Email: infoxafuture@126.com
Country: China
ProdList: 194
Advantage: 58

Hangzhou Fuze Pharmaceutical Technology Co., Ltd.

Tel: 0572-0571-82870240 13586109179
Email: 47302108@qq.com
Country: China
ProdList: 221
Advantage: 58

Allfluoro pharmaceutical co. ltd.

Tel: +86-400-0216110 +86-15958047586
Fax: 0086-21-33275002
Email: sales@allfluoro.com
Country: China
ProdList: 11385
Advantage: 58

CR Corporation Limited

Tel: +8613062833949
Email: fred.wen@crcorporation.cn
Country: China
ProdList: 8645
Advantage: 58

ANHUI WITOP BIOTECH CO., LTD

Tel: +8615255079626
Email: eric@witopchemical.com
Country: China
ProdList: 23541
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

Labnetwork lnc.

Tel: +86-27-50766799 +8618062016861
Email: contact@labnetwork.com
Country: China
ProdList: 19987
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: +86-0571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52846
Advantage: 58

Career Henan Chemica Co

Tel: +86-0371-86658258 +8613203830695
Fax: 0371-86658258
Email: laboratory@coreychem.com
Country: China
ProdList: 30229
Advantage: 58

HUNAN CHEMFISH SCIENTIFIC CO.,LTD

Tel: +86-0731-85567275 13298656710
Fax: QQ:3554193828
Email: sales05@chemfish.com
Country: China
ProdList: 7448
Advantage: 58

Shanghai Pleikon Chemical Technology Co., Ltd

Tel: 021-021-54321516 17717324060
Email: 2719672468@qq.com
Country: China
ProdList: 1880
Advantage: 58

Weihai Zhaochuan Biotechnology Co., Ltd.

Tel: 13863193635
Fax: 0631-5295078
Email: 53702483@qq.com
Country: China
ProdList: 404
Advantage: 58

Chongqing Chemdad Co., Ltd

Tel: +86-023-6139-8061 +86-86-13650506873
Email: sales@chemdad.com
Country: China
ProdList: 39927
Advantage: 58

Shanghai Minhan Pharmaceutical Technology Co., Ltd.

Tel: 17612188245
Fax: QQ 2816925681
Email: 2816925681@qq.com
Country: China
ProdList: 2989
Advantage: 58

CONIER CHEM AND PHARMA LIMITED

Tel: +8618523575427
Email: sales@conier.com
Country: China
ProdList: 49975
Advantage: 58

Shanghai Kaiwei Chemical Technology Co., Ltd.

Tel: 021-58461859 15821823057
Email: service@aiviche.com
Country: China
ProdList: 49312
Advantage: 58

Fuxin Pharmaceutical

Tel: +86-021-021-50872116 +8613122107989
Email: contact@fuxinpharm.com
Country: China
ProdList: 10000
Advantage: 58

Guangzhou Yuheng Pharmaceutical Technology Co., Ltd

Tel: +8613580539051
Email: joe@yuhengpharm.com
Country: CHINA
ProdList: 21142
Advantage: 58

Henan Weitesi Chemical Technology Co. LTD

Tel: 0371-0371-55135753 18003832934
Fax: QQ：2853979818
Email: 2853979818@qq.com
Country: China
ProdList: 9991
Advantage: 58

Chunchuang (Wuhan) Technology Co., Ltd

Tel: 15727060112
Email: yutianchun2007@126.com
Country: China
ProdList: 9814
Advantage: 58

Energy Chemical

Tel: 021-58432009 400-005-6266
Fax: 021-58436166
Email: marketing1@energy-chemical.com
Country: China
ProdList: 44894
Advantage: 58

Shandong Territorial sea Biological Technology Co., LTD

Tel: 15092083467
Email: 18660263263@163.com
Country: China
ProdList: 2810
Advantage: 58

LEWOO PHARMATECH (SHANGHAI) CO.,LTD

Tel: 15800805830
Fax: 021 67898603
Email: miao@lewoopharma.com.cn
Country: China
ProdList: 932
Advantage: 58

Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Tel: 021-51816796-820 13611835272
Fax: 021-5161 3951
Email: sales2@sunwaypharm.com
Country: China
ProdList: 44119
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 40000
Advantage: 58

JinOu Biomedical (Nanjing) Co., Ltd.

Tel: 13000000000
Fax: jinoupharma@163
Email: jinoupharma@163.com
Country: China
ProdList: 11721
Advantage: 58

PharmaBlock Sciences (Nanjing), Inc.

Tel: 4000255188
Fax: 025 86918232
Email: sales_china@pharmablock.com
Country: China
ProdList: 10000
Advantage: 58

Shaanxi Yudingzhuo Medical Technology Co., Ltd.

Tel: 18992018580 18165105898
Fax: QQ:1617857088
Email: 13608210612@163.com
Country: China
ProdList: 2984
Advantage: 58

Tianjin Yankai Scientific Co. Ltd.

Tel: 18500985499
Email: yankaisale@qq.com
Country: China
ProdList: 481
Advantage: 58

Haixin (Wuhan) biomedical Co., Ltd

Tel: 15527257315
Fax: QQ:597963209
Email: hulun12343@163.com
Country: China
ProdList: 328
Advantage: 58

Less

View Lastest Price from Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate 147531-11-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

147531-11-1, Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonateRelated Search:

2-CYANOPROP-2-ENOIC ACID (4-bromophenyl)diphenylphosphine diphenyl(2,2,2-trifluoroethyl)sulfanium trifluoromethanesulfonate (perfluoroethyl)diphenylsulfonium trifluoromethanesulfonate Mesityl(2,2,2-trifluoroethyl)iodonium trifluoromethanesulfonate (difluoromethyl)(2,4-dimethylphenyl)(phenyl)sulfonium tetrafluoroborate Iodonium, (1,1,2,2,3,3,4,4,4-nonafluorobutyl)phenyl-,1,1,1-trifluoromethanesulfonate (2,2-difluoroethyl)diphenylsulfonium trifluoromethanesulfonate 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate (Difluoromethyl)bis(2,5-dimethylphenyl)sulfonium Tetrafluoroborate 1-TrifluoroMethyl-1,2-benziodoxol-3(1H)-one (PERFLUORO-N-HEXYL)PHENYLIODONIUM TRIFLUOROMETHANESULFONATE

diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate

diphenyl-(trifluoroMethyl)-sulfoniuM

Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate

(S)-(trifluoroMethyl)diphenylsulfoniuM triflate

diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate

diphenyl(trifluoromethyl)sulfanium

Diphenyl(trifluoromethyl)

sulfonium trifluoromethanesulfonate

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot

Sulfonium, diphenyl(trifluoromethyl)-, 1,1,1-trifluoromethanesulfonate (1:1)

147531-11-1

147531-11-2

C14H10F6O3S2

C13H10F3SCF3O3S