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Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate

Product Name
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
CAS No.
147531-11-1
Chemical Name
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
Synonyms
Diphenyl(trifluoromethyl);diphenyl(trifluoromethyl)sulfanium;sulfonium trifluoromethanesulfonate;diphenyl-(trifluoroMethyl)-sulfoniuM;(S)-(trifluoroMethyl)diphenylsulfoniuM triflate;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat;diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate;diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate;Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate
CBNumber
CB22470708
Molecular Formula
C13H10F3S.CF3O3S
Formula Weight
404.35
MOL File
147531-11-1.mol
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Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Property

Melting point:
84-85 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
D492063
Product name
Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
D492063
Product name
Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Packaging
500mg
Price
$220
Updated
2021/12/16
ChemScene
Product number
CS-0049606
Product name
Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Purity
>97.0%
Packaging
5g
Price
$409
Updated
2021/12/16
Apolloscientific
Product number
PC905034
Product name
Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Purity
98%
Packaging
250mg
Price
$77
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK1415797
Product name
Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate
Purity
99%
Packaging
100mg
Price
$120
Updated
2021/12/16
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Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Chemical Properties,Usage,Production

Uses

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate can be used as a raw material for organic synthesis with styrene derivatives to synthesise 2-arylazo pyridine at low temperature[1].

Synthesis

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate is synthesised using phenyl trifluoromethyl sulfoxide as a raw material by chemical reaction. The specific synthesis steps are as follows:
Trifluoromethyl sulfoxide (0.4 g, 2.1 mmol) and then benzene (4.9 g, 64 mmol) are introduced, under an inert atmosphere and at approximately 0° C. (lower limit below which benzene crystallizes), into a Schlenck tube purged beforehand with argon. Five equivalents of triflic anhydride (2.82 g, 10 mmol) are gradually added. The mixture is stirred for 1 h at 0° C. and then for 24 h at ambient temperature. The medium is evaporated and the residue is purified by chromatography with the CH3CN/CH2Cl2 (1/4) mixture as eluent. White crystals (Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate), having a melting point of 69-70° C., are obtained with a yield of 40%.

References

[1] J. MATSUO. A Convenient Method for the Synthesis of 2-Arylaziridines from Styrene Derivatives via 2-Arylethenyl(diphenyl)sulfonium Salts[J]. Chemistry Letters, 2003. DOI:10.1246/CL.2003.392.

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Suppliers

China 84 India 1 United States 9 Global 94
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate 147531-11-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-09

147531-11-1, Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonateRelated Search:

2-CYANOPROP-2-ENOIC ACID (4-bromophenyl)diphenylphosphine diphenyl(2,2,2-trifluoroethyl)sulfanium trifluoromethanesulfonate (perfluoroethyl)diphenylsulfonium trifluoromethanesulfonate Mesityl(2,2,2-trifluoroethyl)iodonium trifluoromethanesulfonate (difluoromethyl)(2,4-dimethylphenyl)(phenyl)sulfonium tetrafluoroborate Iodonium, (1,1,2,2,3,3,4,4,4-nonafluorobutyl)phenyl-,1,1,1-trifluoromethanesulfonate (2,2-difluoroethyl)diphenylsulfonium trifluoromethanesulfonate 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate (Difluoromethyl)bis(2,5-dimethylphenyl)sulfonium Tetrafluoroborate 1-TrifluoroMethyl-1,2-benziodoxol-3(1H)-one (PERFLUORO-N-HEXYL)PHENYLIODONIUM TRIFLUOROMETHANESULFONATE

  • diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate
  • diphenyl-(trifluoroMethyl)-sulfoniuM
  • Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate
  • (S)-(trifluoroMethyl)diphenylsulfoniuM triflate
  • diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate
  • diphenyl(trifluoromethyl)sulfanium
  • Diphenyl(trifluoromethyl)
  • sulfonium trifluoromethanesulfonate
  • Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat
  • Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot
  • Sulfonium, diphenyl(trifluoromethyl)-, 1,1,1-trifluoromethanesulfonate (1:1)
  • 147531-11-1
  • C14H10F6O3S2