BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE

Product Name: BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE
CAS No.: 97-24-5
Chemical Name: BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE
Synonyms: d25;D 25;cr305;Novex;Oksid;CR 305;Ph 549;HL 1050;Ovitrol;Meflorin
CBNumber: CB2255547
Molecular Formula: C12H8Cl2O2S
Formula Weight: 287.16
MOL File: 97-24-5.mol

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BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE Property

Melting point:: 175°C
Boiling point:: 416.7±45.0 °C(Predicted)
Density: 1.4186 (estimate)
storage temp.: Sealed in dry,Room Temperature
form: powder to crystal
pka: 7.91±0.48(Predicted)
color: White to Orange to Green
Merck: 14,4004
Stability:: Stable. Incompatible with strong oxidizing agents.
LogP: 4.400 (est)
CAS DataBase Reference: 97-24-5(CAS DataBase Reference)
EPA Substance Registry System: Fenticlor (97-24-5)

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
RTECS: SN0350000
HS Code: 2930.90.2900
HazardClass: IRRITANT
Toxicity: LDLo intraperitoneal in mouse: 250mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: S751847
Product name: 2,2'-THIOBIS(4-CHLOROPHENOL)
Purity: Aldrich
Packaging: 50mg
Price: $179
Updated: 2024/03/01

TCI Chemical

Product number: B0850
Product name: Bis(2-hydroxy-5-chlorophenyl) Sulfide
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $138
Updated: 2024/03/01

TRC

Product number: B591808
Product name: Bis(2-hydroxy-5-chlorophenyl) Sulfide
Packaging: 500mg
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB33497
Product name: Bis(2-hydroxy-5-chlorophenyl) sulfide
Packaging: 5G
Price: $63
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB33497
Product name: Bis(2-hydroxy-5-chlorophenyl) sulfide
Packaging: 10g
Price: $105
Updated: 2021/12/16

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BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE Chemical Properties,Usage,Production

Chemical Properties

white to pale yellow powder

Originator

Fenticlor,Shanghai Lansheng

Uses

Fungicide; especially used against Monosporium apiospermum: Reifferscheid, Seeliger, Dtsch. Med. Wochenschr. 80, 1841, 1850 (1955).

Uses

Fentichlor is a fungicide especially used against Monosporium apiospermum; topical antifungal and antibacterial agent in hairdressings, antifungal creams, and ointments; thermoplastic resin.

Definition

ChEBI: An aryl sulfide having two 5-chloro-2-hydroxyphenyl groups attached to sulfur; an antiinfective drug mostly used in veterinary medicine.

Preparation

Fenticlor is produced (1) by the reaction of 4-chlorophenol with sulfur dichloride in the presence of AlCl3 or (2) by chlorination of 2,2'-thiobisphenol with chlorine in glacial acetic acid or with SO2Cl2 in dichlorobenzene. It shows a tendency to discoloration. Fenticlor has a broad range of antimicrobial action; it is, e.g., effective against bacteria, fungi, yeasts, and algae. Fenticlor is therefore used as a preservative for aqueous functional fluids and to control algae and slime in process water circulation systems.

Manufacturing Process

1 mol bis(2-hydroxy-phenyl)-sulfide, prepared from sulfuryl chloride and phenol, in about 2500 ml glacial acetic acid was dissolved and heated for boiling. 2-3 mol gaseous chlorine was passed through that solution and on cooling bis(2-oxy-5-chlorphenyl)sulfide was fallen. It was recrystallized from acetic acid or light petroleum. MP: 175°C. A residue was dropped from filtrate with water as the white crystals, which melted at the same temperature.
Fenticlor may be also prepared by adding sulfuryl chloride to the solution of bis(2-hydroxy-phenyl)sulfide in dichlorobenzene

Therapeutic Function

Antifungal

General Description

White to cream-colored solid or pale yellow powder. White crystalline solid melting from 175.8-186.8°C. Odorless and insolbule in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials may generate heat and toxic or flammable gases.

Hazard

Toxic by ingestion.

Fire Hazard

Flash point data are not available for BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE, but BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE is probably combustible.

BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE Suppliers

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View Lastest Price from BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE manufacturers

Career Henan Chemical Co

Product: BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE 97-24-5
Price: US $5.50/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 1kg-100kg
Release date: 2020-01-10

Nanjing jinheyou Trading Co., Ltd.

Product: BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE 97-24-5
Price: US $0.00/g
Min. Order: 1g
Purity: 99.8%min
Supply Ability: 20kg/month
Release date: 2019-11-04

97-24-5, BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDERelated Search:

Dichlorophen 2,2'-thiobis[4-chloro-6-nitrophenol] 2,2'-THIOBIS(4,6-DICHLOROPHENOL) DISODIUM SALT Bithionol 4-CHLORO-2-((5-CHLORO-2-[(2-CHLOROACETYL)OXY]PHENYL)THIO)PHENYL 2-CHLOROACETATE PHENOL,2,2'-SULFONYLBIS[3,4,6-TRICHLORO]- 6,6'-thiobis[4-chloro-o-cresol] 4-CHLORO-2-[(5-CHLORO-2-HYDROXYPHENYL)SULFONYL]PHENOL A 9387 4-CHLORO-2-((5-CHLORO-2-[(2,6-DICHLOROBENZOYL)OXY]PHENYL)THIO)PHENYL 2,6-DICHLOROBENZOATE 4-CHLORO-2-((5-CHLORO-2-[(2,6-DICHLOROBENZOYL)OXY]PHENYL)SULFONYL)PHENYL 2,6-DICHLOROBENZOATE BITHIONOL SULFOXIDE BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE

TIMTEC-BB SBB001172

2,2'-DIHYDROXY-5,5'-DICHLORODIPHENYL SULFIDE

2,2'-THIOBIS(4-CHLOROPHENOL)

BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE

BIS(5-CHLORO-2-HYDROXYPHENYL) SULFIDE

FENTICHLOR

FENTICLOR

CHLORHYDROSULFIDE

CHLOROHYDROSULFIDE

2,2’-thiobis(4-chloro-pheno

2,2'-Dihydroxy-5,5'-dichlorophenyl sulfide

5,5'-Dichloro-2,2'-dihydroxydiphenyl sulfide

2,2'-Dihydroxy-5,5'-dichlorodiphenyl s

D 25 (VAN)

Fenticlor (USAN)

Phentichlorum

S 7 (VAN)

WLN: QR DG BSR BQ EG

component of Banish

CR 305

cr305

D 25

D 25-Antimykotikum

4,4'-dichloro-2,2'-thiodiphenol

d25

HL 1050

Meflorin

Novex

NSC-4112

Oksid

Ovitrol

Ph 549

S 7 (antimycotic)

Bis(2-hydroxy-5-chlorophenyl)sulphide

Phenol, 2,2-thiobis4-chloro-

22DIHYDROXY55DICHLORODIPHENYLSULPHIDE

4-chloro-2-[(5-chloro-2-hydroxy-phenyl)thio]phenol

2,2'-Sulfanediylbis(4-chlorophenol)

BIS(2-HYDROXY-5-CHLO

2,2'-Dihydroxy-5,5'-dichlorodiphenyl Sulfide Bis(5-chloro-2-hydroxyphenyl) Sulfide 2,2'-Thiobis(4-chlorophenol)

Bis(2-hydroxy-5-chlorophenyl) Sulfide &gt

97-24-5

Reagent for High-Performance Polymer Research

Diphenyl Sulfides (for High-Performance Polymer Research)

Functional Materials

Reagent for High-Performance Polymer Research