LINDANE

ChemicalBook > CAS DataBase List > LINDANE

Product Name: LINDANE
CAS No.: 319-86-8
Chemical Name: LINDANE
Synonyms: HCH;GAMMA-HCH;Δ-HCH;G-BHC;GEXANE;BENZENE HEXACHLORIDE;δ-hexachlorocyclohexane;GAMMA-BENZENE HEXACHLORIDE;d-1,2,3,4,5,6-Hexachlorocyclohexane;1ALPHA,2ALPHA,3BETA,4ALPHA,5ALPHA,6BETA-HEXACHLOROCYCLOHEXANE
CBNumber: CB2281876
Molecular Formula: C6H6Cl6
Formula Weight: 290.83
MOL File: 319-86-8.mol

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LINDANE Property

Melting point:: 113-115 °C(lit.)
Boiling point:: 373.64°C (rough estimate)
Density: 1.7152 (rough estimate)
vapor pressure: 3.52 at 25 °C (Banerjee et al., 1990)
refractive index: 1.576-1.674 (589.3 nm 20℃)
Flash point:: 11 °C
storage temp.: 2-8°C
solubility: Soluble in ethanol, benzene, and chloroform (Weast, 1986)
form: Solid
BRN: 1907334
Henry's Law Constant: (x 10^-7 atm·m³/mol): 2.5 at 20 °C (approximate - calculated from water solubility and vapor pressure)
EPA Substance Registry System: .delta.-Hexachlorocyclohexane (319-86-8)

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Safety

Hazard Codes: T,N,F,Xn
Risk Statements: 20/21-25-48/22-50/53-64-39/23/24/25-23/24/25-11-40-21-67-65-38-52/53
Safety Statements: 36/37-45-60-61-22-16-7-62
RIDADR: UN 2811 6.1/PG 1
WGK Germany: 3
RTECS: GV4900000
Hazardous Substances Data: 319-86-8(Hazardous Substances Data)
Toxicity: Acute oral LD50 for rats 1,000 mg/kg (RTECS, 1985).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H370Causes damage to organs

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 48495
Product name: δ-BHC
Purity: PESTANAL?,analyticalstandard
Packaging: 50mg
Price: $109
Updated: 2024/03/01

Sigma-Aldrich

Product number: 40103-U
Product name: δ-BHC
Purity: certifiedreferencematerial,1000?μg/mLinmethanol
Packaging: 1mL
Price: $40.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 33377
Product name: δ-HCH
Purity: PESTANAL
Packaging: 50mg
Price: $98
Updated: 2024/03/01

TRC

Product number: H290800
Product name: δ-1,2,3,4,5,6-Hexachlorocyclohexane
Packaging: 100mg
Price: $160
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0324256
Product name: D-1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE
Purity: 95.00%
Packaging: 5MG
Price: $501.2
Updated: 2021/12/16

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LINDANE Chemical Properties,Usage,Production

Chemical Properties

BHC is a white-to-brownish crystalline solid with a musty, phosgene-like odor.

Physical properties

Solid crystals or fine platelets with a faint musty-like odor

Uses

δ-1,2,3,4,5,6-Hexachlorocyclohexane is an organochloride annd is one of the isomers of hexachlorocyclohexane. aδ-1,2,3,4,5,6-Hexachlorocyclohexane is also an byproduct of insecticide Lindane (L465990) .

Uses

Insecticide.

Definition

ChEBI: Beta-hexachlorocyclohexane is the beta-isomer of hexachlorocyclohexane. It has a role as a persistent organic pollutant. It is an organochlorine pesticide and a hexachlorocyclohexane.

General Description

Slightly musty odor.

Reactivity Profile

LINDANE may be incompatible with strong oxidizing and reducing agents. Incompatible with some amines, nitrides, azo/diazo compounds, with alkali metals, and with epoxides.

Health Hazard

ACUTE/CHRONIC HAZARDS: Highly toxic. May cause irritation on contact. Hazardous decomposition products.

Potential Exposure

The major commercial usage of BHC is based upon its insecticidal properties. α-BCH is used as an Agricultural chemical, pesticide, pharmaceutical, and veterinary drug. The 7-isomer has the highest acute toxic ity, but the other isomers are not without activity. It is gen erally advantageous to purify the 7-isomer from the less active isomers. The γ-isomer acts on the nervous system of insects, principally at the level of the nerve ganglia. As a result, lindane has been used against insects in a wide range of applications including treatment of animals, buildings, humans for ectoparasites, clothes; water for mosquitoes; living plants; seeds and soils. Some applications have been abandoned due to excessive residues, e.g., stored food stuffs. By voluntary action, the principal domestic producer of technical grade BHC requested cancellation of its BHC registrations on September 1, 1976. As of July 21, 1978, all registrants of pesticide products containing BHC voluntar ily canceled their registrations or switched their former BHC products to lindane formulations.

Environmental Fate

Biological. Dehydrochlorination of δ-BHC by a Pseudomonas sp. under aerobic con ditions was reported by Sahu et al. (1992). They also reported that when deionized water containing δ-BHC was inoculated with Pseudomonas sp., the concentration of δ-BHC decreased to undetectable levels after 8 days with concomitant formation of chloride ions and δ-pentachlorocyclohexane. In four successive 7-day incubation periods, δ-BHC (5 and 10 mg/L) was recalcitrant to degradation in a settled domestic wastewater inoculum (Tabak et al., 1981).
Chemical/Physical. δ-BHC dehydrochlorinates in the presence of alkalies. The hydrol ysis half-lives at pH values of 7 and 9 are 191 days and 11 hours, respectively (Worthing and Hance, 1991).

Shipping

UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Decomposes on contact with powdered iron, aluminum, zinc, and on contact with strong bases producing trichlorobenzene.

Waste Disposal

A process has been developed for the destructive pyrolysis of benzene hexachloride @ 400 500℃ with a catalyst mixture which contains 5 10% of either cupric chloride, ferric chloride; zinc chloride; or aluminum chloride on activated carbon.

LINDANE Preparation Products And Raw materials

Raw materials

Preparation Products

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319-86-8, LINDANERelated Search:

lindane(bhcorhch-mixedisomers ORGANOCHLORINE PESTICIDE MATRIX SPIKING MIXTURE beta-Lindane alpha-lindan Carboxin LINDANE LINDANE Kilex lindane (g-Benzenehexachloride) (g-BHC) (Lindane-D6),GAMMA-1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE-D6 HEXACHLOROBENZENE <DELTA>-HCH PESTANAL. SOLVENT DEGREASER LINDANE (13C6) ALPHA-HCH SOLUTION 100 NG/MYL IN METHAN& Trichlorphon+BCH,powder (5.5%) Parathion+BCH,powder BCH+Parathion-methyl,powder PESTICIDE MIX 7

1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE, GAMMA-ISOMER

1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE [G-ISOMER]

1ALPHA,2ALPHA,3BETA,4ALPHA,5ALPHA,6BETA-HEXACHLOROCYCLOHEXANE

Cyclohexane, 1,2,3,4,5,6-hexachloro-, delta-

Cyclohexane, 1,2,3,4,5,6-hexachloro-, delta-isomer

Cyclohexane, delta,1,2,3,4,5,6-hexachloro-

cyclohexane,1,2,3,4,5,6-hexachloro-,(1alpha,2alpha,3alpha,4beta,5alpha,6

Cyclohexane,1,2,3,4,5,6-hexachloro-,(1-α,2-α,3-α,4-β,5-α,6-β)-

cyclohexane,1,2,3,4,5,6-hexachloro-,(1α,2α,3α,4β,5α,6β)-

delta-(Aeeee)-1,2,3,4,5,6-Hexachlorocyclohexane

delta-(aeeeee)-1,2,3,4,5,6-hexachlorocyclohexane

delta,1,2,3,4,5,6-Hexachlorocyclohexane

delta-1,2,3,4,5,6-hexachloro-cyclohexan

delta-1,2,3,4,5,6-hexachlorocyclohexane

BENZENE HEXACHLORIDE (GAMMA-ISOMER)

BENZENE HEXACHLORIDE

BEN-HEX(R)

BHC GAMMA ISOMER

APARASIN(R)

APHTIRIA

HCH(R)

HCH

G-BHC

GEXANE

GAMMEXANE

GAMMA-BENZENE HEXACHLORIDE

GAMMA-COL

GAMMA-1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE

GAMMA-HCH

'LGC' (1104)

ISOTOX(R)

JUCUTIN(R)

KEWLL(R)

HGI(R)

(1alpha,2alpha,3alpha,4beta,5alpha,6beta)-1,2,3,4,5,6-hexachlorocyclohexane

LOREXANE(R)

LINTOX(R)

STREUNEX(R)

TRI-6

δ-1,2,3,4,5,6-Hexachlorocyclohexane solution, δ-HCH solution

δ-1,2,3,4,5,6-Hexachlorocyclohexane solution, δ-BHC solution

delta-HCH (BHC)

δ-HCH Standard

BHC (delta isomer) 100mg [319-86-8]

DELTA-BHC, 50MG, NEAT

d-HCH

DELTA-BHC, 1X1ML, MEOH, 20UG/ML

BHC DELTA ISOMER, 100MG, NEAT

<DELTA>-HCH PESTANAL<TM>

deltaisomer)

delta-bhc (jmaf,iso)

delta-hch (bsi,iso)

δ-1,2,3,4,5,6-hexachlorocyclohexane solution

benzene hexachloride {= B.H.C.}

DELTA-HEXACHLOROBENZENE

DELTA,1,2,3,4,4,5,6-Hexachlorocyclohexane

1,2,3,4,5,6-hexachlorocyclohexane (delta isomer)

Δ-HCH