Physical and Chemical Properties InChI Code Toxicity Application Synthesis
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Tralkoxydim

Physical and Chemical Properties InChI Code Toxicity Application Synthesis
Product Name
Tralkoxydim
CAS No.
87820-88-0
Chemical Name
Tralkoxydim
Synonyms
TRALKOXIDYM;GRASP;pp604;ACHIEVE;Fd 4026;Achiveve;splendor;Ici-A 604;Hsdb 7016;Grasp 604
CBNumber
CB2299916
Molecular Formula
C20H27NO3
Formula Weight
329.43
MOL File
87820-88-0.mol
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Tralkoxydim Property

Melting point:
106°
Boiling point:
467.02°C (rough estimate)
Density 
1.1213 (rough estimate)
refractive index 
1.5614 (estimate)
Flash point:
>100 °C
storage temp. 
0-6°C
solubility 
soluble in dichloromethane,Toluene,Acetone
pka
4.20±0.25(Predicted)
color 
Light yellow to Yellow to Orange
Merck 
14,9564
BRN 
8577523
LogP
4.460
CAS DataBase Reference
87820-88-0(CAS DataBase Reference)
EPA Substance Registry System
Tralkoxydim (87820-88-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
RTECS 
GW7191600
HazardClass 
9
PackingGroup 
III
HS Code 
29280000
Hazardous Substances Data
87820-88-0(Hazardous Substances Data)
Toxicity
LD50 orally in male and female rats, male and female mice, male rabbit (mg/kg): 1324, 934, 1231, 1100, 519; dermally in male and female rats: >2000, >2000 mg/kg (Warner 1987)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H351Suspected of causing cancer

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
36536
Product name
Tralkoxidym
Purity
PESTANAL
Packaging
250mg
Price
$74.7
Updated
2022/05/15
TCI Chemical
Product number
T2916
Product name
Tralkoxydim
Packaging
200MG
Price
$27
Updated
2024/03/01
TCI Chemical
Product number
T2916
Product name
Tralkoxydim
Packaging
1G
Price
$87
Updated
2024/03/01
TRC
Product number
T712403
Product name
Tralkoxidym
Packaging
250mg
Price
$50
Updated
2021/12/16
Chem-Impex
Product number
39336
Product name
Tralkoxydim,95%(HPLC)
Purity
95%(HPLC)
Packaging
200MG
Price
$61.6
Updated
2021/12/16
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Tralkoxydim Chemical Properties,Usage,Production

Physical and Chemical Properties

Appearance: White tasteless crystalline solid
Melting Point: 106℃
Saturated Vapor Pressure: 4×10-7Pa (<0.013×10-3Pa 20℃)
Solubility: 4×10-7Pa (<0.013×10-3Pa 20℃) in dichloromethane at 24℃, 213g/L in methylbenzene at 24℃, 110g/L in ethyl acetate at 24℃, 89g/L in acetone at 24℃, 25g/L in methanol at 24℃, 18g/L in hexane at 24℃.
6mg/L (pH=6.5) and 5mg/L (pH=5.0) in water at 20℃

InChI Code

1S/C20H27NO3/c1-6-16(21-24-7-2)20-17(22)10-15(11-18(20)23)19-13(4)8-12(3)9-14(19)5/h8-9,15,22H,6-7,10-11H2,1-5H3

Toxicity

P.O. acute toxicity: LD50=1324mg/kg for male rats, LD50=934mg/kg for female rats,  LD50=1321mg/kg for male mice, LD50=1100mg/kg for female mice, LD50>519mg/kg for rabbits.
Non-effect dose for rats in three-month feed test is 12.5mg/kg. LD50=3020mg/kg for mallard, LD50=4430mg/kg for partridge.
Acute percutaneous toxicity: LD50>2000mg/kg for male and female rats.
Acute inhalation toxicity: LC50>3467mg/m3 for male and female rats.
It has mild irritation on eyes and skin. No allergic effect on cavy.
No teratogenesis effect has been observed yet.
LC50>7.2mg/L (96h) for rainbow trout, LC50>8.2mg/L (96h) for Cyprinus carpio var.

Application

Tralkoxydim is a kind of highly selective herbicide with inward absorption and conduction ability. It’s used on a variety of graminaceous weeds in barley and wheat fields. It is rapidly absorbed and transferred throughout all parts of the weeds after foliar spray. The weeds will soon turn pale and wither. The general dosage is 150~350g effective constituent/hm2 . 200~350g effective constituent /hm2 of tralkoxydim applied from early growth period to elongation stage will be effective on the prevention and control of wild oat weeds.

Synthesis

The product of the reaction between 2,4,6-Trimethylbenzaldehyde and acetone react with diethyl malonate to generate an intermediate. The intermediate is transformed into 3-hydroxy-5-(2',4',6'-trimethylphenyl)-cyclohexyl-2-alkenyl-1-ketone after hydrolysis, cyclization and decarboxylation. Then it reacts with propionic anhydride in the presence of sodium methanol. The product reacts with ethoxyamine hydrochloride to generate methoxyphenone.

Uses

Post-emergent herbicide.

Definition

ChEBI: Tralkoxydim is a mixture.

Agricultural Uses

Herbicide: Tralkoxydim is a post-emergent herbicide applied to actively growing weeds in wheat, barley, triticale and cereal rye to control wild oats, green foxtail, yellow foxtail, annual ryegrass and Persian darnel. Registered for use in EU countries. Registered for use in the U.S.

Trade name

ACHIEVE®; ACHIEVE®-40DG; ALPHA GRASP®; ICI-A 604®; PP 604®; SPLENDOR®

Tralkoxydim Preparation Products And Raw materials

Raw materials

Preparation Products

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Tralkoxydim Suppliers

Jiangsu Agrochem Laboratory
Tel
0519-5109160
Fax
0086-519-85108116
Email
sales@agrochemlab.com
Country
China
ProdList
180
Advantage
54
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
BEST-REAGENT
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11726
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6181
Advantage
58
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
Nanjing Sunlida Biological Technology Co., Ltd.
Tel
025-57798810
Fax
025-57019371
Email
sales@sunlidabio.com
Country
China
ProdList
3750
Advantage
55
TargetMol Chemicals Inc.
Tel
021-33632979 15002134094
Fax
021-33632979
Email
marketing@targetmol.com
Country
China
ProdList
7934
Advantage
58
ChemStrong Scientific Co.,Ltd
Tel
0755-66853366 13670046396
Fax
0755-28363542
Email
sales@chem-strong.com
Country
China
ProdList
17982
Advantage
56
Finetech Industry Limited
Tel
027-87465837 19945049750
Fax
027-8777-2287
Email
sales@finetechnology-ind.com
Country
China
ProdList
9664
Advantage
58
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View Lastest Price from Tralkoxydim manufacturers

Hebei Mojin Biotechnology Co., Ltd
Product
Tralkoxydim 87820-88-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16
Hebei Guanlang Biotechnology Co., Ltd.
Product
Tralkoxydim 87820-88-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-03-28
Career Henan Chemical Co
Product
Tralkoxydim 87820-88-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-31

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