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METHYL 2-CHLORO-5-IODONICOTINATE

Product Name
METHYL 2-CHLORO-5-IODONICOTINATE
CAS No.
78686-83-6
Chemical Name
METHYL 2-CHLORO-5-IODONICOTINATE
Synonyms
METHYL 2-CHLORO-5-IODONICOTINATE;2-Chloro-5-iodoicotinic acid methyl ester;2-Chloro-5-iodo-nicotinic acid methyl ester;Methyl 2-chloro-5-iodopyridine-3-carboxylate;Methyl 2-chloro-5-iodo-3-pyridinecarboxylate;3-Pyridinecarboxylic acid, 2-chloro-5-iodo-, methyl ester
CBNumber
CB2314628
Molecular Formula
C7H5ClINO2
Formula Weight
297.48
MOL File
78686-83-6.mol
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METHYL 2-CHLORO-5-IODONICOTINATE Property

Melting point:
70-73°
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Solid
color 
White
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Safety

HazardClass 
IRRITANT
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
M295605
Product name
Methyl2-chloro-5-iodonicotinate
Packaging
100mg
Price
$45
Updated
2021/12/16
Usbiological
Product number
454902
Product name
Methyl 2-chloro-5-iodonicotinate
Packaging
100mg
Price
$312
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
Y14746
Product name
Methyl2-chloro-5-iodonicotinate
Purity
98%
Packaging
1g
Price
$50
Updated
2021/12/16
Matrix Scientific
Product number
046002
Product name
Methyl 2-chloro-5-iodonicotinate
Purity
>95%
Packaging
500mg
Price
$77
Updated
2021/12/16
AK Scientific
Product number
2322AC
Product name
Methyl2-chloro-5-iodonicotinate
Packaging
100mg
Price
$84
Updated
2021/12/16
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METHYL 2-CHLORO-5-IODONICOTINATE Chemical Properties,Usage,Production

Synthesis

116387-40-7

78686-83-6

Step 2 of Scheme 13: Methyl 5-iodo-2-hydroxynicotinate (4.75 g, 17.1 mmol) was dissolved in trichlorophosphorus (50 mL) and heated to reflux for 24 hours. After completion of the reaction, the solvent was removed by rotary evaporator. The crude product was neutralized with saturated sodium bicarbonate solution and subsequently extracted with ether. The organic phase was dried over anhydrous magnesium sulfate, filtered and concentrated by rotary evaporator. The crude product was purified by silica gel column chromatography to afford 4.3 g (85% yield) of methyl 2-chloro-5-iodonicotinate using a hexane solution of 5% ethyl acetate as eluent. The physical and chemical properties of this compound have been documented in Journal of Organic Chemistry, 1989, vol. 54.

References

[1] Patent: US2005/203081, 2005, A1. Location in patent: Page/Page column 13; 33
[2] Journal of Medicinal Chemistry, 1993, vol. 36, # 18, p. 2676 - 2688
[3] Patent: US5250548, 1993, A
[4] Patent: WO2008/76425, 2008, A1. Location in patent: Page/Page column 54
[5] Patent: WO2008/130600, 2008, A2. Location in patent: Page/Page column 46

METHYL 2-CHLORO-5-IODONICOTINATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2-CHLORO-5-IODONICOTINATE Suppliers

A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from METHYL 2-CHLORO-5-IODONICOTINATE manufacturers

Career Henan Chemica Co
Product
METHYL 2-CHLORO-5-IODONICOTINATE 78686-83-6
Price
US $1.00/KG
Min. Order
1KG
Purity
MIn98%HPLC/LC
Supply Ability
100KGS
Release date
2020-10-29

78686-83-6, METHYL 2-CHLORO-5-IODONICOTINATERelated Search:


  • METHYL 2-CHLORO-5-IODONICOTINATE
  • Methyl 2-chloro-5-iodopyridine-3-carboxylate
  • 2-Chloro-5-iodo-nicotinic acid methyl ester
  • 2-Chloro-5-iodoicotinic acid methyl ester
  • 3-Pyridinecarboxylic acid, 2-chloro-5-iodo-, methyl ester
  • Methyl 2-chloro-5-iodo-3-pyridinecarboxylate
  • 78686-83-6