Carbonyltris(triphenylphosphine)rhodium(I) hydride

Product Name: Carbonyltris(triphenylphosphine)rhodium(I) hydride
CAS No.: 17185-29-4
Chemical Name: Carbonyltris(triphenylphosphine)rhodium(I) hydride
Synonyms: HRh(CO)(PPh3)3;(betab-5-23)-rhodiu;Carbonyltris(triphen;HRh(CO)(PPh3)3 - RODRIDO;Carbonyltris(triphenylphosphine)rhodium;Carbonylhydridotris(triphenylphosphine);TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &;Carbonyltris(triphenylphosphine)rhodiuM(I);Carbonylhydrotris(triphenylphosphin)rhodium;Carbonyl triphenylphosphine rhodiuM hydride
CBNumber: CB2322445
Molecular Formula: 3C18H15P.CO.HRh
Formula Weight: 918.8
MOL File: 17185-29-4.mol

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Carbonyltris(triphenylphosphine)rhodium(I) hydride Property

Melting point:: 150 °C (dec.) (lit.)
Density: 1.33
vapor pressure: 0Pa at 25℃
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
solubility: Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands
form: crystal
color: light yellow
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Merck: 14,9758
Exposure limits: ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
InChIKey: CEKFIOLKXHVOKA-UHFFFAOYSA-N
CAS DataBase Reference: 17185-29-4(CAS DataBase Reference)
NIST Chemistry Reference: carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4)
EPA Substance Registry System: Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4)

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Safety

Hazard Codes: T
Risk Statements: 23/24/25
Safety Statements: 36/37/39-45-36/37
RIDADR: UN 2811 6.1/PG 2
WGK Germany: 1
F: 10-23
TSCA: Yes
HazardClass: 4.3
PackingGroup: III
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 225665
Product name: Tris(triphenylphosphine)rhodium(I) carbonyl hydride
Purity: 97%
Packaging: 500mg
Price: $251
Updated: 2024/03/01

Sigma-Aldrich

Product number: 225665
Product name: Tris(triphenylphosphine)rhodium(I) carbonyl hydride
Purity: 97%
Packaging: 5g
Price: $1760
Updated: 2024/03/01

TCI Chemical

Product number: C1383
Product name: Carbonylhydridotris(triphenylphosphine)rhodium(I)
Packaging: 1g
Price: $396
Updated: 2024/03/01

TCI Chemical

Product number: C1383
Product name: Carbonylhydridotris(triphenylphosphine)rhodium(I)
Packaging: 5g
Price: $1189
Updated: 2024/03/01

Alfa Aesar

Product number: 010016
Product name: Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min
Packaging: 0.1g
Price: $47.2
Updated: 2023/06/20

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Carbonyltris(triphenylphosphine)rhodium(I) hydride Chemical Properties,Usage,Production

Chemical Properties

Carbonylhydrido-tris(triphenylphosphine)rhodium(I), carbonyl-tris(triphenylphosphine)rhodium(I) hydride, forms yellow crystals that are stable in air, mp 172 – 174℃ in a closed nitrogen-filled capillary. It is readily soluble in benzene, chloroform, and dichloromethane. In solution, one phosphine ligand is readily lost by dissociation to give a 16-electron complex that is an active catalyst for the hydrogenation of alkenes and for hydroformylation.

Uses

Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation

Uses

Carbonylhydrido-tris(triphenylphosphine)rhodium(I) is used in industry for the hydroformylation of alkenes by the low pressure oxo (LPO) process developed by Union Carbide, Davy Power Gas, and Johnson Matthey. The reaction takes place rapidly at 25℃ giving a product in which the ratio of n- to iso-aldehydes is very favorable (ca. 20 : 1), a much higher ratio than can be obtained with cobalt catalysts.

Production Methods

Carbonyltris(triphenylphosphine)rhodium(I) hydride is obtained by the reaction of a solution of RhCl3.3 H2O in alcoholic alkali with aqueous formaldehyde (the carbon monoxide source) and an excess of triphenyl phosphine. The commercial product is a microcrystalline powder with a purity of 97 % (Degussa).

Carbonyltris(triphenylphosphine)rhodium(I) hydride Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonyltris(triphenylphosphine)rhodium(I) hydride Suppliers

Americas 1 Belgium 2 Brazil 1 China 164 Czech Republic 1 Europe 1 France 1 Germany 6 India 8 Japan 4 Singapore 1 Switzerland 2 United Kingdom 7 United States 34 Global 233

Shandong Boyi Biotechnology Co. LTD

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Alfa Aesar

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Chemsky（shanghai）International Co.,Ltd.

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View Lastest Price from Carbonyltris(triphenylphosphine)rhodium(I) hydride manufacturers

Longyan Tianhua Biological Technology Co., Ltd

Product: Carbonyltris(triphenylphosphine)rhodium(I) hydride 17185-29-4
Price: US $30.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-18

Career Henan Chemical Co

Product: Carbonyltris(triphenylphosphine)rhodium(I) hydride 17185-29-4
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-02-13

17185-29-4, Carbonyltris(triphenylphosphine)rhodium(I) hydrideRelated Search:

Terphenyl, hydrogenated Lithium Triethylborohydride Sodium triacetoxyborohydride Tris(triphenylphosphine)rhodiu Sodium hydride Tributyltin Hydride Triphenylphosphine Rhodium Ruthenium dioxide Iridium(IV) chloride Tris(triphenylphosphine)ruthenium(II) chloride Chloroiridic acid Hydridotetrakis(triphenylphosphine)rhodium(I) Rhodium triiodide Ruthenium tetroxide Dipotassium hexachloroiridate Cyclopentadienyl manganese tricarbonyl Carbonyltris(triphenylphosphine)rhodium(I) hydride

HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I)

CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)

CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE

CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE

TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE

(betab-5-23)-rhodiu

carbonylhydrotris(triphenylphosphine)rhodium

TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &

Carbonylhydridotris(triphenylphosphine)rhodium(I).99.9%

CARBONYLHYDIDOTRIS (TRIPHENYLPHOSPHINE) RHODIUM(I)

Hydridocarbonyltris(triphenylphosphine)rhodium(I),98%

Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-

tris(triphenylphosphine)rhodium carbonyl hydride

Carbonyltris(triphenylphosphine)rhodium

Carbonylhydrotris(triphenylphosphin)rhodium

Carbonylhydridotris tris (triphenylphosphine) rhodiuM (I)

Rhodium monocarbonyl hydrogen tris(triphenylphosphine)

trans-Carbonyl(hydrido)tris(triphenylphosphine)rhodium

Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min

Carbonylhydridotris(triphenylphosphine)

CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRI

Efficient hydroformylation catalyst. Unstable in solution in presence of air.

rhodium(I) tris(triphenylphosphine) carbonyl hydride

Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2%

Carbonyl hydridotris(triphenylphosphine) rhodium

Hydridocarbonyltris(triphenylphosphine)rhodium

Tris(triphenylphosphine)carbonylrhodium hydride

Carbonyltris(triphenylphosphine)rhodium(I) hydride, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), Rhodium(I) tris(triphenylphosphine) carbonyl hydride

Carbonyltris(triphenylphosphine)rhodium(I)hydride,97%

Carbonylhydridotris(triphenylphosphine)rhodium/ 98+%

Tris(triphenylphosphine)rhodium(I) carbonyl hydride,Carbonyltris(triphenylphosphine)rhodium(I) hydride, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), Rhodium(I) tris(triphenylphosphine) carbony

Carbonyltris(triphen

Tris(triphenylphosphine)rhodium(I) carbonyl hydride ,98%

Carbonyl triphenylphosphine rhodiuM hydride

Carbonyltris(triphenylphosphine)rhodiuM(I)

Carbonyltris(triphenylphosphine)rhodium(I) Hydride Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride

Tris(triphenylphosphine)rhodium(Ⅰ) carbonyl hydride

RHODIUM(I) HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)

Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2% min

Carbonylhydridotris(triphenylphosphane)rhodium(I) “RODRIDO”

Carbonyltris(triphenylphosphine)rhodium(I) hydride ISO 9001：2015 REACH

HRh(CO)(PPh3)3 - RODRIDO

Carbonylhydridotris(triphenylphosphine)rhodium(I)[RhH(CO)(PPh3)3

HRh(CO)(PPh3)3

Trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]

17185-29-4

C6H53P3RhCOH

C55H46O1P3Rh1

RhHCOPPh33

RhHCOPC6H533

C55H46OP3Rh

C54H46P3Rh

3C18H15PCOHRh

Transition Metal Compounds

Catalysts for Organic Synthesis

Rh (Rhodium) Compounds

Classes of Metal Compounds

Homogeneous Catalysts