ChemicalBook > CAS DataBase List > Carbonyltris(triphenylphosphine)rhodium(I) hydride

Carbonyltris(triphenylphosphine)rhodium(I) hydride

Product Name
Carbonyltris(triphenylphosphine)rhodium(I) hydride
CAS No.
17185-29-4
Chemical Name
Carbonyltris(triphenylphosphine)rhodium(I) hydride
Synonyms
HRh(CO)(PPh3)3;(betab-5-23)-rhodiu;Carbonyltris(triphen;HRh(CO)(PPh3)3 - RODRIDO;Carbonyltris(triphenylphosphine)rhodium;Carbonylhydridotris(triphenylphosphine);TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &;Carbonyltris(triphenylphosphine)rhodiuM(I);Carbonylhydrotris(triphenylphosphin)rhodium;Carbonyl triphenylphosphine rhodiuM hydride
CBNumber
CB2322445
Molecular Formula
3C18H15P.CO.HRh
Formula Weight
918.8
MOL File
17185-29-4.mol
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Carbonyltris(triphenylphosphine)rhodium(I) hydride Property

Melting point:
150 °C (dec.) (lit.)
Density 
1.33
vapor pressure 
0Pa at 25℃
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands
form 
crystal
color 
light yellow
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Merck 
14,9758
Exposure limits
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
InChIKey
CEKFIOLKXHVOKA-UHFFFAOYSA-N
CAS DataBase Reference
17185-29-4(CAS DataBase Reference)
NIST Chemistry Reference
carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4)
EPA Substance Registry System
Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4)
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Safety

Hazard Codes 
T
Risk Statements 
23/24/25
Safety Statements 
36/37/39-45-36/37
RIDADR 
UN 2811 6.1/PG 2
WGK Germany 
1
F 
10-23
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
III
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
225665
Product name
Tris(triphenylphosphine)rhodium(I) carbonyl hydride
Purity
97%
Packaging
500mg
Price
$251
Updated
2024/03/01
Sigma-Aldrich
Product number
225665
Product name
Tris(triphenylphosphine)rhodium(I) carbonyl hydride
Purity
97%
Packaging
5g
Price
$1760
Updated
2024/03/01
TCI Chemical
Product number
C1383
Product name
Carbonylhydridotris(triphenylphosphine)rhodium(I)
Packaging
1g
Price
$396
Updated
2024/03/01
TCI Chemical
Product number
C1383
Product name
Carbonylhydridotris(triphenylphosphine)rhodium(I)
Packaging
5g
Price
$1189
Updated
2024/03/01
Alfa Aesar
Product number
010016
Product name
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min
Packaging
0.1g
Price
$47.2
Updated
2023/06/20
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Carbonyltris(triphenylphosphine)rhodium(I) hydride Chemical Properties,Usage,Production

Chemical Properties

Carbonylhydrido-tris(triphenylphosphine)rhodium(I), carbonyl-tris(triphenylphosphine)rhodium(I) hydride, forms yellow crystals that are stable in air, mp 172 – 174℃ in a closed nitrogen-filled capillary. It is readily soluble in benzene, chloroform, and dichloromethane. In solution, one phosphine ligand is readily lost by dissociation to give a 16-electron complex that is an active catalyst for the hydrogenation of alkenes and for hydroformylation.

Uses

Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation

Uses

Carbonylhydrido-tris(triphenylphosphine)rhodium(I) is used in industry for the hydroformylation of alkenes by the low pressure oxo (LPO) process developed by Union Carbide, Davy Power Gas, and Johnson Matthey. The reaction takes place rapidly at 25℃ giving a product in which the ratio of n- to iso-aldehydes is very favorable (ca. 20 : 1), a much higher ratio than can be obtained with cobalt catalysts.

Production Methods

Carbonyltris(triphenylphosphine)rhodium(I) hydride is obtained by the reaction of a solution of RhCl3.3 H2O in alcoholic alkali with aqueous formaldehyde (the carbon monoxide source) and an excess of triphenyl phosphine. The commercial product is a microcrystalline powder with a purity of 97 % (Degussa).

Carbonyltris(triphenylphosphine)rhodium(I) hydride Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonyltris(triphenylphosphine)rhodium(I) hydride Suppliers

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View Lastest Price from Carbonyltris(triphenylphosphine)rhodium(I) hydride manufacturers

Longyan Tianhua Biological Technology Co., Ltd
Product
Carbonyltris(triphenylphosphine)rhodium(I) hydride 17185-29-4
Price
US $30.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-18
Career Henan Chemical Co
Product
Carbonyltris(triphenylphosphine)rhodium(I) hydride 17185-29-4
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-02-13

17185-29-4, Carbonyltris(triphenylphosphine)rhodium(I) hydrideRelated Search:

Terphenyl, hydrogenated Lithium Triethylborohydride Sodium triacetoxyborohydride Tris(triphenylphosphine)rhodiu Sodium hydride Tributyltin Hydride Triphenylphosphine Rhodium Ruthenium dioxide Iridium(IV) chloride Tris(triphenylphosphine)ruthenium(II) chloride Chloroiridic acid Hydridotetrakis(triphenylphosphine)rhodium(I) Rhodium triiodide Ruthenium tetroxide Dipotassium hexachloroiridate Cyclopentadienyl manganese tricarbonyl Carbonyltris(triphenylphosphine)rhodium(I) hydride

  • HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I)
  • CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
  • CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE
  • CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE
  • TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE
  • (betab-5-23)-rhodiu
  • carbonylhydrotris(triphenylphosphine)rhodium
  • TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &
  • Carbonylhydridotris(triphenylphosphine)rhodium(I).99.9%
  • CARBONYLHYDIDOTRIS (TRIPHENYLPHOSPHINE) RHODIUM(I)
  • Hydridocarbonyltris(triphenylphosphine)rhodium(I),98%
  • Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-
  • tris(triphenylphosphine)rhodium carbonyl hydride
  • Carbonyltris(triphenylphosphine)rhodium
  • Carbonylhydrotris(triphenylphosphin)rhodium
  • Carbonylhydridotris tris (triphenylphosphine) rhodiuM (I)
  • Rhodium monocarbonyl hydrogen tris(triphenylphosphine)
  • trans-Carbonyl(hydrido)tris(triphenylphosphine)rhodium
  • Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min
  • Carbonylhydridotris(triphenylphosphine)
  • CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRI
  • Efficient hydroformylation catalyst. Unstable in solution in presence of air.
  • rhodium(I) tris(triphenylphosphine) carbonyl hydride
  • Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2%
  • Carbonyl hydridotris(triphenylphosphine) rhodium
  • Hydridocarbonyltris(triphenylphosphine)rhodium
  • Tris(triphenylphosphine)carbonylrhodium hydride
  • Carbonyltris(triphenylphosphine)rhodium(I) hydride, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), Rhodium(I) tris(triphenylphosphine) carbonyl hydride
  • Carbonyltris(triphenylphosphine)rhodium(I)hydride,97%
  • Carbonylhydridotris(triphenylphosphine)rhodium/ 98+%
  • Tris(triphenylphosphine)rhodium(I) carbonyl hydride,Carbonyltris(triphenylphosphine)rhodium(I) hydride, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), Rhodium(I) tris(triphenylphosphine) carbony
  • Carbonyltris(triphen
  • Tris(triphenylphosphine)rhodium(I) carbonyl hydride ,98%
  • Carbonyl triphenylphosphine rhodiuM hydride
  • Carbonyltris(triphenylphosphine)rhodiuM(I)
  • Carbonyltris(triphenylphosphine)rhodium(I) Hydride Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride
  • Tris(triphenylphosphine)rhodium(Ⅰ) carbonyl hydride
  • RHODIUM(I) HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)
  • Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2% min
  • Carbonylhydridotris(triphenylphosphane)rhodium(I) “RODRIDO”
  • Carbonyltris(triphenylphosphine)rhodium(I) hydride ISO 9001：2015 REACH
  • HRh(CO)(PPh3)3 - RODRIDO
  • Carbonylhydridotris(triphenylphosphine)rhodium(I)[RhH(CO)(PPh3)3
  • HRh(CO)(PPh3)3
  • 17185-29-4
  • C6H53P3RhCOH
  • C55H46O1P3Rh1
  • RhHCOPPh33
  • RhHCOPC6H533
  • C55H46OP3Rh
  • C54H46P3Rh
  • 3C18H15PCOHRh
  • Transition Metal Compounds
  • Catalysts for Organic Synthesis
  • Rh (Rhodium) Compounds
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes