TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE

Product Name: TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
CAS No.: 13406-29-6
Chemical Name: TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
Synonyms: tris[4-(trifluoromethyl)phenyl]phosphane;Tris(4-(trifluoromethyl);4,4',4''-phosphoryltrimorpholine;TRIS(P-TRIFLUOROMETHYLPHENYL)BENZENE;TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE;TRIS(P-TRIFLUOROMETHYLPHENYL)PHOSPHINE;Tri (4-trifluoromethylphenyl) phosphine;Potassium tetrakis(trifluoromethyl)borate;Tris(4-trifluoromethylphenyl)phosphine,99%;Tris(p-trifluoromethylphenyl)phosphine,97%
CBNumber: CB2328492
Molecular Formula: C21H12F9P
Formula Weight: 466.28
MOL File: 13406-29-6.mol

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TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Property

Melting point:: 70-75 °C
Boiling point:: 382.8±42.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: Liquid
color: Clear
Water Solubility: Insoluble in water.
InChI: InChI=1S/C21H12F9P/c22-19(23,24)13-1-7-16(8-2-13)31(17-9-3-14(4-10-17)20(25,26)27)18-11-5-15(6-12-18)21(28,29)30/h1-12H
InChIKey: PXYCJKZSCDFXLR-UHFFFAOYSA-N
SMILES: P(C1=CC=C(C(F)(F)F)C=C1)(C1=CC=C(C(F)(F)F)C=C1)C1=CC=C(C(F)(F)F)C=C1
CAS DataBase Reference: 13406-29-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
TSCA: No
HazardClass: IRRITANT
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 666629
Product name: Tris(4-trifluoromethylphenyl)phosphine
Purity: 97%
Packaging: 1g
Price: $137.7
Updated: 2025/07/31

Sigma-Aldrich

Product number: 666629
Product name: Tris(4-trifluoromethylphenyl)phosphine
Purity: 97%
Packaging: 5g
Price: $341.12
Updated: 2025/07/31

TCI Chemical

Product number: T4115
Product name: Tris[4-(trifluoromethyl)phenyl]phosphine
Purity: min. 98.0 %
Packaging: 1G
Price: $119
Updated: 2025/07/31

Strem Chemicals

Product number: 15-8010
Product name: Tris(p-trifluoromethylphenyl)phosphine, min. 97%
Packaging: 1g
Price: $137
Updated: 2024/03/01

Strem Chemicals

Product number: 15-8010
Product name: Tris(p-trifluoromethylphenyl)phosphine, min. 97%
Packaging: 5g
Price: $544
Updated: 2024/03/01

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TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Tris[4-(trifluoromethyl)phenyl]phosphine is a raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Synthesis

13406-27-4

13406-29-6

GENERAL METHODS: Triphenylphosphine oxide or its sulfide (1 mmol), anhydrous hexane (1 mL) and 1c (1 mmol) were sequentially added to Schlenk tubes under nitrogen atmosphere protection. The reaction was carried out at room temperature for 10 min and the progress of the reaction was monitored by thin layer chromatography (TLC). Upon completion of the reaction, the reaction mixture was filtered through a silica gel pad and washed several times with ethyl acetate. Subsequently, the ethyl acetate was removed by evaporation and the residue was purified by fast column chromatography on silica gel, using pure cyclohexane as eluent, to afford the target product tris(4-trifluorotoluene)phosphine. The product yield was determined by gas chromatography (GC) without further purification.

References

[1] Journal of Organic Chemistry, 2008, vol. 73, # 4, p. 1524 - 1531
[2] Russian Journal of General Chemistry, 2015, vol. 85, # 5, p. 1156 - 1160
[3] Zh. Obshch. Khim.,
[4] Advanced Synthesis and Catalysis, 2016, vol. 358, # 1, p. 26 - 29

TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Suppliers

Belgium 1 China 118 France 1 Germany 3 India 4 Japan 1 Norway 1 Russia 1 Switzerland 2 Ukraine 1 United Kingdom 9 United States 19 Global 161

Wuhan Pengo Technology.,Ltd.

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Energy Chemical

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China DongFan Chemical Co.,LTD

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Shandong Xiya Chemical Co., Ltd

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View Lastest Price from TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE 13406-29-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-26

Shaanxi Dideu Medichem Co. Ltd

Product: Tris[4-(trifluoromethyl)phenyl]phosphine 13406-29-6
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

Career Henan Chemical Co

Product: TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE 13406-29-6
Price: US $1.00/KG
Min. Order: 1G
Purity: 99%
Supply Ability: 1MT
Release date: 2018-08-09

13406-29-6, TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINERelated Search:

Tris(4-bromophenyl)amine Tris(4-fluorophenyl)phosphine Tris(4-isocyanatophenyl) thiophosphate TRIS(4-CHLOROPHENYL)PHOSPHINE TRIS(4-FORMYLPHENYL)AMINE [Tris(para-trifluoromethylphenyl)phosphine]gold(I) chloride CHLOROTRIS(PARA-TRIFLUOROMETHYLPHENYL)PHOSPHINE GOLD(I) TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium DIPHENYL(P-TOLYL)PHOSPHINE TRI-P-TOLYLPHOSPHINE (4-TRIFLUOROMETHYLPHENYL)PHOSPHINE BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE 4-TOLYLPHOSPHINE DI-P-TOLYLPHOSPHINE

TRIS(P-TRIFLUOROMETHYLPHENYL)BENZENE

TRIS(P-TRIFLUOROMETHYLPHENYL)PHOSPHINE

TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE

Phosphine, tris(alpha,alpha,alpha-trifluoro-p-tolyl)-

Trisptrifluoromethylphenylphosphineminpaleyellowpowder

Tris(p-trifluoromethylphenyl)phosphine,min.97%

Tris[4-(trifluoromethyl)phenyl]phosphine 98%

Tris[4-(trifluoromethyl)phenyl]phosphine98%

Tris(p-trifluoromethylphenyl)phosphine, min. 97%

tris[4-(trifluoromethyl)phenyl]phosphane

Potassium tetrakis(trifluoromethyl)borate

Tris(4-trifluoromethylphenyl)phosphine,99%

Tris(4-(trifluoromethyl)

Tris[4-(trifluoromethyl)phenyl]phosphine 95+%

Phosphine, tris[4-(trifluoromethyl)phenyl]-

Tri (4-trifluoromethylphenyl) phosphine

4,4',4''-phosphoryltrimorpholine

Tris(p-trifluoromethylphenyl)phosphine,97%

13406-29-6

CF3C6H43P

pCF3C6H43P

C21H21F9P

C21H12F9P

Catalysis and Inorganic Chemistry

Phosphorus Compounds

Phosphine Ligands

Achiral Phosphine

Aryl Phosphine

Ligand

organophosphorus ligand