5-IODO-2-METHOXYTOLUENE

Product Name: 5-IODO-2-METHOXYTOLUENE
CAS No.: 75581-11-2
Chemical Name: 5-IODO-2-METHOXYTOLUENE
Synonyms: 5-IODO-2-METHYLANISOLE;4-IODO-2-METHYLANISOLE;5-IODO-2-METHOXYTOLUENE;4-Iodo-1-Methoxy-2-Methylbenzene;Benzene, 4-iodo-1-methoxy-2-methyl-
CBNumber: CB2370299
Molecular Formula: C8H9IO
Formula Weight: 248.06
MOL File: 75581-11-2.mol

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5-IODO-2-METHOXYTOLUENE Property

Melting point:: 75-76 °C(Solv: acetic acid (64-19-7))
Boiling point:: 247.7±28.0 °C(Predicted)
Density: 1.634±0.06 g/cm3(Predicted)
storage temp.: 2-8°C(protect from light)
Appearance: Off-white to gray Solid

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: I737063
Product name: 4-Iodo-2-methylanisole
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: I737063
Product name: 4-Iodo-2-methylanisole
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 007383
Product name: 4-Iodo-2-methylanisole
Purity: 97%
Packaging: 5g
Price: $52
Updated: 2021/12/16

Activate Scientific

Product number: AS145178
Product name: 5-Iodo-2-methylanisole
Purity: 98%
Packaging: 250mg
Price: $140
Updated: 2021/12/16

Matrix Scientific

Product number: 007383
Product name: 4-Iodo-2-methylanisole
Purity: 97%
Packaging: 25g
Price: $205
Updated: 2021/12/16

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5-IODO-2-METHOXYTOLUENE Chemical Properties,Usage,Production

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 4081, 1996 DOI: 10.1016/0040-4039(96)00738-1

Synthesis

578-58-5

75581-11-2

The general procedure for the synthesis of 4-iodo-2-methylanisole from 2-methylanisole is as follows: to a stirred solution of 2-methylanisole (1 mmol) in dichloromethane (CH2Cl2) or 1,2-dichloroethane ((CH2Cl)2) (0.1 M), triphenylphosphorane-gold bis(trifluoromethylsulfonyl)imide (Ph3PAuNTf2) (0.025 mmol , 19 mg; if toluene-coordinated Ph3PAuNTf2 complex was used, the ratio was 2:1), followed by the addition of N-iodosuccinimide (NIS) (1.1 mmol, 248 mg). The reaction mixture was stirred at room temperature or reacted under reflux conditions until complete conversion of the feedstock was confirmed by thin layer chromatography (TLC) monitoring. Upon completion of the reaction, the solvent was evaporated under reduced pressure and the resulting crude product was purified by fast column chromatography using different ratios of hexane and ethyl acetate (EtOAc) as eluents to finally obtain pure 4-iodo-2-methylanisole.

References

[1] Synthetic Communications, 2003, vol. 33, # 8, p. 1319 - 1323
[2] Chemistry Letters, 1988, # 5, p. 795 - 798
[3] Synlett, 2014, vol. 25, # 3, p. 399 - 402
[4] Tetrahedron Letters, 1996, vol. 37, # 23, p. 4081 - 4084
[5] Journal of Organic Chemistry, 2006, vol. 71, # 11, p. 4349 - 4352

5-IODO-2-METHOXYTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-IODO-2-METHOXYTOLUENE Suppliers

China 55 India 3 United Kingdom 5 United States 5 Global 68

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View Lastest Price from 5-IODO-2-METHOXYTOLUENE manufacturers

Career Henan Chemical Co

Product: 5-IODO-2-METHOXYTOLUENE 75581-11-2
Price: US $6.60/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg -1000kg
Release date: 2020-01-02

75581-11-2, 5-IODO-2-METHOXYTOLUENERelated Search:

clioxanide ROSE BENGAL 5-IODO-2,3-DIHYDROBENZO[B]FURAN ERYTHROSIN B ERYTHROSIN B ROSE BENGAL 5-AMINOERYTHROSIN ERYTHROSIN B ISOTHIOCYANATE, ISOMER II BENZAMIDE, N-[(1-ETHYL-2-PYRROLIDINYL)METHYL]-2-HYDROXY-3-IODO-6-METHOXY- ETHYL 6-IODO-4-OXO-4H-CHROMENE-2-CARBOXYLATE ROSE BENGAL LACTONE epidepride TRIIODOFLUORESCEIN 3-IODO-4-METHOXYTOLUENE 4-IODO-2-METHOXYTOLUENE Hydroxy[(3',6'-dihydroxy-2',7'-diiodospiro[3H-2,1-benzoxathiole-3,9'-[9H]xanthene]-1,1-dioxide)-4'-yl]mercury(II) salt METHYL 5-IODO-2-[(4-METHYLBENZOYL)OXY]BENZENECARBOXYLATE 2,3-DIMETHOXY-5-IODOBENZALDEHYDE

5-IODO-2-METHOXYTOLUENE

4-IODO-2-METHYLANISOLE

5-IODO-2-METHYLANISOLE

4-Iodo-1-Methoxy-2-Methylbenzene

Benzene, 4-iodo-1-methoxy-2-methyl-

75581-11-2

C8H9OI

Aromatic Ethers

Anisoles, Alkyloxy Compounds & Phenylacetates

Iodine Compounds