2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER

Product Name: 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER
CAS No.: 832735-54-3
Chemical Name: 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER
Synonyms: 2-Benzyloxy-5-pyridineboronic acid pinacol ester;2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER;6-benzoxypyridine-3-borate frequency alcohol ester;6-(Benzyloxy)pyridine-3-boronic acid pinacol ester;2-BENZYLOXY-5-(4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXABOROLAN-2-YL)PYRIDINE;Pyridine, 2-(phenylmethoxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
CBNumber: CB2380762
Molecular Formula: C18H22BNO3
Formula Weight: 311.18
MOL File: 832735-54-3.mol

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2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Property

Melting point:: 138-142°C
Boiling point:: 429.6±35.0 °C(Predicted)
Density: 1.11±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
form: solid
pka: 3.91±0.24(Predicted)
color: Yellow
InChI: 1S/C18H22BNO3/c1-17(2)18(3,4)23-19(22-17)15-10-11-16(20-12-15)21-13-14-8-6-5-7-9-14/h5-12H,13H2,1-4H3
InChIKey: MXNLRVZITPPZHT-UHFFFAOYSA-N
SMILES: CC1(C)OB(OC1(C)C)c2ccc(OCc3ccccc3)nc2
CAS DataBase Reference: 832735-54-3

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
HS Code: 2933399990
Storage Class: 11 - Combustible Solids
Hazard Classifications: Aquatic Chronic 4

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 715484
Product name: 2-Benzyloxy-5-pyridineboronic acid pinacol ester
Purity: 97%
Packaging: 1g
Price: $252
Updated: 2023/06/20

TRC

Product number: B288883
Product name: 6-Benzyloxypyridine-3-boronicacid,pinacolester
Packaging: 500mg
Price: $65
Updated: 2021/12/16

TRC

Product number: B288883
Product name: 6-Benzyloxypyridine-3-boronicacid,pinacolester
Packaging: 100mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB33104
Product name: 2-Benzyloxy-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-pyridine
Packaging: 250mg
Price: $45
Updated: 2021/12/16

Ark Pharm

Product number: P000663198
Product name: 2-(Benzyloxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
Purity: 95+%
Packaging: 1g
Price: $61
Updated: 2021/12/16

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2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Chemical Properties,Usage,Production

Synthesis

83664-33-9

73183-34-3

832735-54-3

General procedure: to a 50 mL solution of 1,4-dioxane was added sequentially 2-benzyloxy-5-bromopyridine (3.76 g, 14.2 mmol, 1.0 eq.), pinacol ester of bis(boronic acid) (4.34 g, 17.1 mmol, 1.2 eq.), potassium acetate (3.48 g, 35.5 mmol, 2.5 eq.), and [1,1'-bis(diphenylphosphino) ferrocene]palladium dichloride (1.16 g, 1.4 mmol, 0.1 eq.). The reaction mixture was heated to 100 °C under nitrogen protection and refluxed overnight. After completion of the reaction, the reaction mixture was concentrated and dried, and the residue was purified by column chromatography (eluent: petroleum ether/dichloromethane=2:1) to afford 6-benzyloxypyridine-3-boronic acid pinacol ester (2.63 g, 59.5% yield).

References

[1] Patent: CN106588937, 2017, A. Location in patent: Paragraph 0197

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Suppliers

China 65 France 2 Germany 2 India 1 United Kingdom 3 United States 22 Global 95

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View Lastest Price from 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER manufacturers

Career Henan Chemical Co

Product: 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER 832735-54-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-30

832735-54-3, 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTERRelated Search:

Phenylboronic acid Propylthiouracil [2-(BENZYLOXY)PYRIMIDIN-5-YL]BORONIC ACID 2-BENZYLOXYPYRIDIN-3-YLBORONIC ACID 2-Benzyloxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 2-(Benzyloxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrimidine 2-Benzyloxy-pyridine-5-boronic acid 6-HYDROXY-3-PYRIDINEBORONIC ACID (6-ETHOXYPYRIDIN-3-YL)BORONIC ACID 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER 2-ETHOXY-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE 2-METHOXYPYRIDINE-5-BORONIC ACID PINACOL ESTER 3-Pyridylboronic acid 2-BENZYLOXYPYRIDINE-3-BORONIC ACID PINACOL ESTER 2-Methoxy-5-pyridineboronic acid 2-HYDROXY-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE

2-Benzyloxy-5-pyridineboronic acid pinacol ester

2-BENZYLOXY-5-(4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXABOROLAN-2-YL)PYRIDINE

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER

6-(Benzyloxy)pyridine-3-boronic acid pinacol ester

Pyridine, 2-(phenylmethoxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

6-benzoxypyridine-3-borate frequency alcohol ester

832735-54-3

C18H22BNO3

Heterocyclic Compounds