ChemicalBook > CAS DataBase List > PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE

PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE

Product Name
PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE
CAS No.
138687-69-1
Chemical Name
PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE
Synonyms
FDPP;Perfluorophenyl diphenylphosphinate;Pentafluorophenyl diphenyl phosphate;PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE;perfluorophenyl diphenylphosphinate(FDPP);Diphenylphosphinic acid pentafluorophenyl ester;1-diphenylphosphoryloxy-2,3,4,5,6-pentafluorobenzene;Phosphinic acid, P,P-diphenyl-, 2,3,4,5,6-pentafluorophenyl ester;PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE Diphenylphosphinic acid pentafluorophenyl ester
CBNumber
CB2397032
Molecular Formula
C18H10F5O2P
Formula Weight
384.24
MOL File
138687-69-1.mol
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PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE Property

Melting point:
47-50 °C (lit.)
Boiling point:
413.1±55.0 °C(Predicted)
Density 
1.45
storage temp. 
Sealed in dry,Room Temperature
InChIKey
OOWSDKUFKGVADH-UHFFFAOYSA-N
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
418080
Product name
Pentafluorophenyl diphenylphosphinate
Packaging
1g
Price
$50.1
Updated
2024/03/01
Sigma-Aldrich
Product number
418080
Product name
Pentafluorophenyl diphenylphosphinate
Packaging
5g
Price
$89.4
Updated
2024/03/01
TCI Chemical
Product number
P2726
Product name
Pentafluorophenyl Diphenylphosphinate
Packaging
1G
Price
$35
Updated
2024/03/01
TCI Chemical
Product number
P2726
Product name
Pentafluorophenyl Diphenylphosphinate
Packaging
5G
Price
$117
Updated
2024/03/01
TRC
Product number
P227345
Product name
Pentafluorophenyl diphenylphosphinate
Packaging
1g
Price
$90
Updated
2021/12/16
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PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE Chemical Properties,Usage,Production

Chemical Properties

White to yellow solid

Uses

Pentafluorophenyl Diphenylphosphinate is a reagent used as carboxyl activating group and a coupling agent in variety of amide bond formations.

Uses

FDPP can be used as a coupling reagent in the:

  • Synthesis of peptides by solid-phase and solution-phase reactions.
  • Preparation of macrocyclic peptide cyclotheonamide B as a thrombin inhibitor.
  • Cyclooligomerization of N-methylated-L-valine thiazole amino acid to obtain its cyclic tetramers.
  • Macrocyclization of an intermediate for the total synthesis of ziziphine N , and for the macrolactamization of precursor in synthesizing cryptophycin D.

General Description

Pentafluorophenyl diphenylphosphinate (FDPP) is a reagent, used as a coupling agent in the amide bond forming reactions without racemization. It can also be employed in the synthesis of dipeptides with high yields and good optical purity. FDPP can be prepared from diphenylphosphinic chloride and pentafluorophenol in the presence of imidazole.

PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE Preparation Products And Raw materials

Raw materials

Preparation Products

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PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE Suppliers

China 111 India 3 Japan 1 South Korea 1 Switzerland 2 United States 11 Global 129
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View Lastest Price from PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Pentafluorophenyldiphenylphosphinate 138687-69-1
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16
Huida Pharmaceutical Technology (Shanghai) Co., Ltd.
Product
PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE 138687-69-1
Price
US $0.00-0.00/kg
Min. Order
0.1kg
Purity
98%+
Supply Ability
1000kg
Release date
2023-02-28
Henan Aochuang Chemical Co.,Ltd.
Product
PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE 138687-69-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-26

138687-69-1, PENTAFLUOROPHENYL DIPHENYLPHOSPHINATERelated Search:

2,3,4,5,6-PENTAFLUOROPHENYL 2-PROPANESULFONATE 2,3,4,5,6-PENTAFLUOROPHENYL 4-NITROBENZENESULFONATE 2,3,4,5,6-PENTAFLUOROPHENYLACETONITRILE METHYL PENTAFLUOROPHENYL CARBONATE PENTAFLUOROPHENYL METHACRYLATE dimesitylammonium pentafluorobenzenesulfonate ETHYL PENTAFLUOROPROPIONATE Pentafluorophenyl formate EZ-LINK (TM) PFP-BIOTIN, 50 MG Triphenyl phosphate TETRAETHYLENEGLYCOL MONOMETHYL ETHER pfpat 2,3,4,5,6-PENTAFLUOROBENZENEBORONIC ACID METHYL METHYLPHENYLPHOSPHINATE Diphenylmethoxyphosphine DIMETHYLPHOSPHINIC ACID Phenylphosphinic acid Diphenylphosphinic acid

  • PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE
  • Perfluorophenyl diphenylphosphinate
  • 1-diphenylphosphoryloxy-2,3,4,5,6-pentafluorobenzene
  • Diphenylphosphinic acid pentafluorophenyl ester
  • perfluorophenyl diphenylphosphinate(FDPP)
  • Phosphinic acid, P,P-diphenyl-, 2,3,4,5,6-pentafluorophenyl ester
  • FDPP
  • PENTAFLUOROPHENYL DIPHENYLPHOSPHINATE Diphenylphosphinic acid pentafluorophenyl ester
  • Pentafluorophenyl diphenyl phosphate
  • 138687-69-1
  • C6H52POOC6F5
  • C18H10F5O2P
  • Building Blocks
  • Phosphonates/Phosphinates
  • Phosphorus Compounds
  • Organic Building Blocks
  • Organic Building Blocks
  • Phosphonates/Phosphinates
  • Phosphorus Compounds