Tin(IV) chloride Property

Melting point:

56 °C

Density 

2.040

solubility 

very soluble in H2O; soluble in ethanol

form 

lumps

color 

Light Yellow

Water Solubility 

soluble

Merck 

14,8774

Stability:

Stable, but may decompose in contact with moisture or water. Incompatible with strong acids.

InChIKey

KHMOASUYFVRATF-UHFFFAOYSA-J

CAS DataBase Reference

10026-06-9(CAS DataBase Reference)

EPA Substance Registry System

Stannane, tetrachloro-, pentahydrate (10026-06-9)

Safety

Hazard Codes 

C

Risk Statements 

34-52/53

Safety Statements 

26-36/37/39-45-7/8-61

RIDADR 

UN 2440 8/PG 3

WGK Germany 

3

RTECS 

XP8870000

HazardClass 

8

PackingGroup 

III

HS Code 

28273990

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Tin(IV) chloride Chemical Properties,Usage,Production

Physical Properties

Colorless fuming liquid; corrosive; density 2.234 g/mL; freezes at –33°C; boils at 114.15°C; critical temperature 318.75°C; critical pressure 37.98 atm; critical volume 351 cm3/mol; soluble in cold water, evolving heat; decomposed by hot water; soluble in alcohol, benzene, toluene, chloroform, acetone and kerosene.
The pentahydrate is a yellowish-white crystalline solid or small, fused lumps; faint odor of HCl; density 2.04 g/cm3; decmposes at 56°C; very soluble in water; soluble in ethanol.

Uses

Tin(IV) chloride is a mordant for dying fabrics; a stabilizer for perfume in soap; used in weighting silk; in ceramic coatings; in manufacturing blue print papers; and to produce fuchsin. Also, tin(IV) chloride is used in preparing many organotin compounds.

Preparation

Tin(IV) chloride is prepared by reacting tin or tin(II) chloride with chlorine:
Sn + 2Cl2 → SnCl4
SnCl2 + Cl2 → SnCl4

Chemical Properties

White solid. Soluble in water or alcohol.

Chemical Properties

Stannic chloride is a white to yellow powder with a faint odor of HCl.

Uses

Substitute for anhydrous stannic chloride where the presence of water is not objectionable

Uses

Tin (IV) Chloride Pentahydrate is a hydrate of Tin (IV) Chloride(T443805), which can induce slight inhibition of the catalytic activity of horse liver alcohol dehydrogenase (HLADH).

General Description

Stannic chloride pentahydrate is a white colored solid. Stannic chloride pentahydrate is soluble in water. Stannic chloride pentahydrate is toxic by ingestion, inhalation and skin absorption. Stannic chloride pentahydrate is used to make perfumes and dyes.

Air & Water Reactions

Soluble in water. Reacts with water to form Hydrochloric Acid in dense white fumes [Merck 11th ed. 1989].

Reactivity Profile

Acidic salts, such as STANNIC CHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Hazard

Toxic material

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

A poison by intraperitoneal and intravenous routes. Mutation data reported. A corrosive liquid. When heated to decomposition it emits toxic vapors of tin and Cl-.

Potential Exposure

Hydrated stannic chloride is used for fixing certain textile dyes, and for treating silk to give weight to the fabric.

Shipping

UN2440 Stannic chloride, pentahydrate, Hazard class: 8; Labels: 8-Corrosive material.

Incompatibilities

Reacts violently with water, forming corrosive hydrochloric acid and tin oxide fumes. Reacts with turpentine, alcohols, and amines, causing fire and explosion hazard. Attacks many metals; some forms of plastics, rubber, and coatings. Reacts with moist air to form hydrochloric acid and dense white fume.