5-Bromo-2-methoxy-4-methylpyridine

Product Name: 5-Bromo-2-methoxy-4-methylpyridine
CAS No.: 164513-39-7
Chemical Name: 5-Bromo-2-methoxy-4-methylpyridine
Synonyms: 5-Bromo-2-methoxy-4-methyL;2-METHOXY-5-BROMO-4-PICOLINE;5-BROMO-2-METHOXY-4-PICOLINE;5-BROMO-2-METHOXY-4-METHYLPYRIDIN;2-METHOXY-5-BROMO-4-METHYLPYRIDINE;5-BROMO-2-METHOXY-4-METHYLPYRIDINE;Pyridine, 5-bromo-2-methoxy-4-methyl-;5-Bromo-2-methoxy-4-methylpyridine >5-BROMO-2-METHOXY-4-METHYLPYRIDINE, 96+%;5-BROMO-2-METHOXY-4-METHYLPYRIDINE ISO 9001：2015 REACH
CBNumber: CB2411116
Molecular Formula: C7H8BrNO
Formula Weight: 202.05
MOL File: 164513-39-7.mol

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5-Bromo-2-methoxy-4-methylpyridine Property

Melting point:: 33-37 °C(lit.)
Boiling point:: 229.6±35.0 °C(Predicted)
Density: 1.45g/ml
Flash point:: 225 °F
storage temp.: 0-10°C
pka: 1.70±0.18(Predicted)
form: powder to crystal
color: White to Almost white
InChI: 1S/C7H8BrNO/c1-5-3-7(10-2)9-4-6(5)8/h3-4H,1-2H3
InChIKey: HTBPXLJKMNBQMS-UHFFFAOYSA-N
SMILES: COc1cc(C)c(Br)cn1
CAS DataBase Reference: 164513-39-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29339900
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 588873
Product name: 5-Bromo-2-methoxy-4-methylpyridine
Purity: ≥96%
Packaging: 5g
Price: $462
Updated: 2023/06/20

Sigma-Aldrich

Product number: 588873
Product name: 5-Bromo-2-methoxy-4-methylpyridine
Purity: ≥96%
Packaging: 1g
Price: $93.4
Updated: 2022/05/15

TCI Chemical

Product number: B4067
Product name: 5-Bromo-2-methoxy-4-methylpyridine
Purity: >98.0%(GC)
Packaging: 1g
Price: $25
Updated: 2026/03/19

TCI Chemical

Product number: B4067
Product name: 5-Bromo-2-methoxy-4-methylpyridine
Purity: >98.0%(GC)
Packaging: 5g
Price: $79
Updated: 2026/03/19

TRC

Product number: B684770
Product name: 5-Bromo-2-methoxy-4-methylpyridine
Packaging: 25g
Price: $360
Updated: 2021/12/16

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5-Bromo-2-methoxy-4-methylpyridine Chemical Properties,Usage,Production

Synthesis

Sodium acetate (3.54g. 43.23mmol) was added to a solution of 2-methoxy-4-methylpyridine (5.0g.3gmmol) in EtOAc (25mL). Br2 (1 .52mL, 58mmol) was added drop-wise to over 20 mm at 0°C. The RM was stirred at 50°C for 18 h. The total reaction mass was cooled, and after diluting it with water, the pH was adjusted to 8 with aq. NaOH. The organic layer was separated, and aq. Layer extracted with EtOAc (250mL x 3). The combined extract was washed with water (300 mL), brine (200 mL), dried (Na2SO4) and concentrated under reduced pressure to get a crude compound. The crude compound was purified by CC(silica gel 100-200mesh, 0-5 per cent EtOAc in PE) to obtain 5-bromo-2-methoxy-4-methylpyridine (2.82g. 40 per cent) as liquid.

References

[1] Patent: US2016/176882, 2016, A1. Location in patent: Paragraph 0355; 0356
[2] Patent: WO2017/221100, 2017, A1. Location in patent: Paragraph 00166

5-Bromo-2-methoxy-4-methylpyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Bromo-2-methoxy-4-methylpyridine Suppliers

Americas 1 Canada 1 China 182 Europe 1 France 1 Germany 2 India 11 Japan 1 Switzerland 1 United Kingdom 4 United States 22 Global 227

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View Lastest Price from 5-Bromo-2-methoxy-4-methylpyridine manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 5-Bromo-2-methoxy-4-methylpyridine 164513-39-7
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-29

Henan Fengda Chemical Co., Ltd

Product: 5-Bromo-2-methoxy-4-methylpyridine 164513-39-7
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-30

Dideu Industries Group Limited

Product: 5-BROMO-2-METHOXY-4-METHYLPYRIDINE 164513-39-7
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons min
Release date: 2021-08-18

164513-39-7, 5-Bromo-2-methoxy-4-methylpyridineRelated Search:

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5-BROMO-2-METHOXY-4-METHYLPYRIDINE, 96+%

2-METHOXY-5-BROMO-4-PICOLINE

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5-BROMO-2-METHOXY-4-METHYLPYRIDIN

5-Bromo-2-methoxy-4-methylpyridine &gt

5-Bromo-2-methoxy-4-methyL

Pyridine, 5-bromo-2-methoxy-4-methyl-

5-BROMO-2-METHOXY-4-METHYLPYRIDINE ISO 9001：2015 REACH

164513-39-7

Building Blocks

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Halogenated Heterocycles

Heterocyclic Building Blocks

Isoquinolines ,Quinolines ,Quinazolines ,Quinaldines

Pyridine Series

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Heterocyclic Compounds

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Boronic Acid

C7 and C8Heterocyclic Building Blocks

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