3-Amino-4-chlorobenzotrifluoride

Product Name: 3-Amino-4-chlorobenzotrifluoride
CAS No.: 121-50-6
Chemical Name: 3-Amino-4-chlorobenzotrifluoride
Synonyms: 2-CHLORO-5-(TRIFLUOROMETHYL)ANILINE;Fast Orange RD Salt;Fast Orange Salt RD;6-CHLORO-ALPHA,ALPHA,ALPHA-TRIFLUORO-M-TOLUIDINE;usafma-13;C.I. 37050;USAF ma-13;orangesaltnrd;2-Chloro-5-(tr;Orange Salt NRD
CBNumber: CB2430564
Molecular Formula: C7H5ClF3N
Formula Weight: 195.57
MOL File: 121-50-6.mol

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3-Amino-4-chlorobenzotrifluoride Property

Melting point:: 10 °C
Boiling point:: 82-83 °C (9 mmHg)
Density: 1.428 g/mL at 25 °C(lit.)
vapor pressure: 0.15 hPa
refractive index: n20/D 1.499(lit.)
Flash point:: 75 °C
storage temp.: Store below +30°C.
solubility: 11g/l
pka: 1.43±0.10(Predicted)
form: clear liquid
Colour Index: 37050
color: Colorless to Yellow to Green
Specific Gravity: 1.428
Water Solubility: 11 g/L (60 ºC)
BRN: 879910
CAS DataBase Reference: 121-50-6(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, 2-chloro-5-(trifluoromethyl)-(121-50-6)
EPA Substance Registry System: Benzenamine, 2-chloro-5-(trifluoromethyl)- (121-50-6)

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Safety

Hazard Codes: Xn,Xi,N
Risk Statements: 20/21/22-51/53-36/37/38
Safety Statements: 36/37-60-57-36/37/39-26-36
RIDADR: UN 2810 6.1/PG 3
WGK Germany: 2
RTECS: XU5775000
Autoignition Temperature: ≥560°C
Hazard Note: Irritant
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29214300

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.41772
Product name: 3-Amino-4-chlorobenzotrifluoride
Purity: for synthesis
Packaging: 50mL
Price: $112
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.41772
Product name: 3-Amino-4-chlorobenzotrifluoride
Packaging: 8417720050
Price: $104
Updated: 2021/12/16

TCI Chemical

Product number: A0948
Product name: 3-Amino-4-chlorobenzotrifluoride
Purity: >98.0%(GC)
Packaging: 25g
Price: $48
Updated: 2025/07/31

TCI Chemical

Product number: A0948
Product name: 3-Amino-4-chlorobenzotrifluoride
Purity: >98.0%(GC)
Packaging: 500g
Price: $373
Updated: 2025/07/31

TRC

Product number: C351435
Product name: 2-Chloro-5-trifluoromethylaniline
Packaging: 500mg
Price: $45
Updated: 2021/12/16

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3-Amino-4-chlorobenzotrifluoride Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLORLESS TO LIGHT YELLOW LIQUID

Uses

2-Chloro-5-trifluoromethylaniline

Synthesis

328-84-7

39885-50-2

121-50-6

Example 1: N-methylpyrrolidone (1050 mL) was added to an autoclave with 102 g of anhydrous activated potassium fluoride followed by 377 g of 3,4-dichlorobenzotrifluoride. At ambient temperature, 158 g of ammonia was vented from a pressure tank into the reactor. The reaction mixture was heated to 245-250 °C over a period of 2 h, at which time the reactor pressure reached 30-32 kg/cm2. excess ammonia gas was continued to be passed from the pressure tank to maintain the reactor pressure at 38-40 kg/cm2 at a liquid temperature of 245-250 °C. The reaction was maintained at this temperature and pressure condition for 8 h. The reaction was completed with the addition of 377 g of potassium fluoride, followed by the addition of 377 g of 3,4-dichlorobenzotrifluoride. Upon completion of the reaction, the mixture was cooled to ambient temperature and the unreacted ammonia gas was drained and recovered. The reaction mixture was filtered and the products were separated by fractional distillation to give 2-chloro-4-trifluoromethylaniline (77% yield) and 2-chloro-5-trifluoromethylaniline (13% yield) based on 3,4-dichlorobenzotrifluoride consumption calculations.

References

[1] Patent: WO2011/107998, 2011, A1. Location in patent: Page/Page column 17
[2] Patent: US2013/30190, 2013, A1. Location in patent: Paragraph 0060

3-Amino-4-chlorobenzotrifluoride Preparation Products And Raw materials

Raw materials

Preparation Products

2-CHLORO-5-(TRIFLUOROMETHYL)PHENYL ISOCYANATE

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3-Amino-4-chlorobenzotrifluoride Suppliers

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View Lastest Price from 3-Amino-4-chlorobenzotrifluoride manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 3-Amino-4-chlorobenzotrifluoride 121-50-6
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

Hebei Chuanghai Biotechnology Co., Ltd

Product: 3-Amino-4-chlorobenzotrifluoride 121-50-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2024-11-29

Shaanxi Dideu Medichem Co. Ltd

Product: 3-Amino-4-chlorobenzotrifluoride 121-50-6
Price: US $0.00-0.00/KG
Min. Order: 50mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-08

121-50-6, 3-Amino-4-chlorobenzotrifluorideRelated Search:

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3-Amino-4-chorobenzotrifluoride

6-Chloro-alpha,alpha,alpha-trifluoro-m-toluidine 3-Amino-4-chlorobenzotrifluoride C.I. 37050

3-Amino-4-chlorobenzotrifluoride for synthesis

2-Chloro-5-(trifluoromethyl)aniline >=98.0% (GC)

4-chloro-3-aminotrifluorotoluene

3-Amino-4-chlorobenzotrifluoride, 6-Chloro-α,α,α-trifluoro-m-toluidine

Azoene Fast Orange RD

3-Amino-4-chlorobenzotrifluoride ,97%

C.I.Azoic Diazo Component 49

TIMTEC-BB SBB003593

LABOTEST-BB LT00053884

FAST ORANGE RD OIL

C.I. 37050

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5-Chloro-2-(trifluoromethyl)benzenamine

3-AMINO-4-CHLOROBENZOTRIFLUORIDE 99%

1-AMINO-2-CHLORO-5-(TRIFLUORMETHYL)-BENZENE

3-Amino-4-chlorobenzotrifluoride98%

6-Chlor-.alpha,alpha,alpha-trifluor-m-toluidin

AKOS BBS-00000946

6-CHLORO-A,A,A-TRIFLUORO-M-TOLUIDINE

6-chloro-alpha,alpha,alpha-trifluoro-m-toluidin

Azoene Fast Orange RD Salt

azoenefastorangerdsalt

Benzenamine,2-chloro-5-(trifluoromethyl)-

Daito Orange Salt RD

daitoorangesaltrd

Diazo Fast Orange RD

diazofastorangerd

Fast Orange RD Salt

Fast Orange Salt RD

Fast Orange Salt RDA

Fast Orange Salt RDN

fastorangerdsalt

fastorangesaltrd

fastorangesaltrda

fastorangesaltrdn

Hiltosal Fast Orange RD Salt

hiltosalfastorangerdsalt

m-Toluidine, 6-chloro-alpha,alpha,alpha-trifluoro-

Orange Salt NRD

orangesaltnrd

Sanyo Fast Orange Salt RD

sanyofastorangesaltrd