ChemicalBook > CAS DataBase List > 2,4-DIAMINOFLUOROBENZENE

2,4-DIAMINOFLUOROBENZENE

Product Name
2,4-DIAMINOFLUOROBENZENE
CAS No.
6264-67-1
Chemical Name
2,4-DIAMINOFLUOROBENZENE
Synonyms
5-AMINO-2-FLUOROANILINE;2,4-DIAMINOFLUOROBENZENE;1,3-DIAMINO-4-FLUOROBENZENE;4-Fluoro-1,3-benzenediamine;4-Fluoro-1,3-diaminobenzene;4-FLUORO-BENZENE-1,3-DIAMINE;4-FLUORO-1,3-PHENYLENEDIAMINE;1,3-BenzenediaMine, 4-fluoro-;1,2-DiaMino-4-difluorobenzene;(5-amino-2-fluoro-phenyl)amine
CBNumber
CB2431420
Molecular Formula
C6H7FN2
Formula Weight
126.13
MOL File
6264-67-1.mol
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2,4-DIAMINOFLUOROBENZENE Property

Melting point:
34-37 °C(lit.)
Boiling point:
152-153 °C(lit.)
Density 
1.284±0.06 g/cm3(Predicted)
Flash point:
221 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
4.65±0.10(Predicted)
form 
Powder
color 
Black
CAS DataBase Reference
6264-67-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
2921599090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
541532
Product name
4-Fluoro-1,3-diaminobenzene
Purity
95%
Packaging
25g
Price
$928
Updated
2022/05/15
TCI Chemical
Product number
F0794
Product name
4-Fluoro-1,3-phenylenediamine
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$234
Updated
2025/07/31
TRC
Product number
F598128
Product name
4-Fluorobenzene-1,3-diamine
Packaging
500mg
Price
$110
Updated
2021/12/16
AK Scientific
Product number
Z4961
Product name
4-Fluorobenzene-1,3-diamine
Packaging
1g
Price
$87
Updated
2021/12/16
Matrix Scientific
Product number
126756
Product name
4-Fluorobenzene-1,3-diamine
Purity
>95%
Packaging
5g
Price
$288
Updated
2021/12/16
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2,4-DIAMINOFLUOROBENZENE Chemical Properties,Usage,Production

Synthesis

364-76-1

6264-67-1

In Example 1, equimolar 4-fluoro-3-nitroaniline was substituted for m-nitroacetophenone as a raw material, and the reaction conditions were set at 80°C and 4.0 MPa for 48 hours. The rest of the operation steps were kept consistent with Example 1, and 4-fluoro-1,3-diaminobenzene was finally obtained in 94% yield. The specific operation was as follows: 16.44 mg (0.04 mmol) of silver 4,4'-dimethoxy-2,2'-bipyridine, 11.22 mg (0.1 mmol) of potassium tert-butoxide and 1 mL of 1,4-dioxane were added to an autoclave. After thorough stirring, 165.15 mg (1 mmol) of m-nitroacetophenone was added and the mixture was stirred continuously at 80 °C for 8 hours. Upon completion of the reaction, the organic phase was separated by extraction of the reaction solution using water and dichloromethane. The organic phase was subsequently dried with anhydrous Na2SO4 and purified by filtration, rotary evaporation and chromatographic separation to afford 3-acetanilide as a yellow solid in 96% yield.

References

[1] Patent: CN106748834, 2017, A. Location in patent: Paragraph 0016; 0069; 0072
[2] Patent: US4552882, 1985, A

2,4-DIAMINOFLUOROBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4-DIAMINOFLUOROBENZENE Suppliers

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View Lastest Price from 2,4-DIAMINOFLUOROBENZENE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2,4-DIAMINOFLUOROBENZENE 6264-67-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-25
Shaanxi Dideu New Materials Co. Ltd
Product
4-Fluorobenzene-1,3-diamine 6264-67-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2024-11-19
Career Henan Chemical Co
Product
2,4-DIAMINOFLUOROBENZENE 6264-67-1
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02

6264-67-1, 2,4-DIAMINOFLUOROBENZENERelated Search:


  • 5-AMINO-2-FLUOROANILINE
  • 4-FLUORO-BENZENE-1,3-DIAMINE
  • 4-FLUORO-1,3-PHENYLENEDIAMINE
  • 4-Fluoro-1,3-benzenediamine
  • 2,4-DIAMINOFLUOROBENZENE
  • 4-Fluoro-1,3-diaminobenzene, 95%
  • 1,3-DIAMINO-4-FLUOROBENZENE
  • 1,2-DiaMino-4-difluorobenzene
  • 1,3-BenzenediaMine, 4-fluoro-
  • 1,3-DiaMino-4-fluorobenzene[2,4-DiaMinofluorobenzene]
  • (5-amino-2-fluoro-phenyl)amine
  • 4-Fluoro-1,3-phenylenediamine&gt
  • 4-Fluoro-1,3-diaminobenzene
  • 6264-67-1
  • FC6H3NH22
  • Polyamines
  • Building Blocks
  • Organic Building Blocks
  • Nitrogen Compounds
  • Anilines, Aromatic Amines and Nitro Compounds