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Sodium ethanesulfinate

Product Name
Sodium ethanesulfinate
CAS No.
20035-08-9
Chemical Name
Sodium ethanesulfinate
Synonyms
Nsc371084;ethanesulfinate;Sodium Ethanesulfinate;sodium 1-sulfinatoethane;ETHANE SULFINIC ACID SODIUM;ETHANE SULFINIC ACID SODIUM SALT;Ethanesulfinic acid, sodium salt (8CI,9CI)
CBNumber
CB2447829
Molecular Formula
C2H5NaO2S
Formula Weight
116.11
MOL File
20035-08-9.mol
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Sodium ethanesulfinate Property

Melting point:
292°C
Density 
1.372
storage temp. 
Inert atmosphere,Room Temperature
form 
solid
Appearance
White to light yellow Solid
InChI
InChI=1S/C2H6O2S.Na/c1-2-5(3)4;/h2H2,1H3,(H,3,4);/q;+1/p-1
InChIKey
UWIVVFQECQYHOB-UHFFFAOYSA-M
SMILES
S(CC)(=O)[O-].[Na+]
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
ALD00294
Product name
Sodium ethylsulfinate
Packaging
500MG
Price
$266
Updated
2025/07/31
TRC
Product number
B526608
Product name
sodiumethanesulfinate
Packaging
100mg
Price
$60
Updated
2021/12/16
Matrix Scientific
Product number
067067
Product name
Ethane sulfinic acid sodium salt
Purity
90%
Packaging
100g
Price
$309
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0393856
Product name
SODIUM ETHANESULFINATE
Purity
95.00%
Packaging
5MG
Price
$499.19
Updated
2021/12/16
Matrix Scientific
Product number
067067
Product name
Ethane sulfinic acid sodium salt
Purity
90%
Packaging
5g
Price
$29
Updated
2021/12/16
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Sodium ethanesulfinate Chemical Properties,Usage,Production

Uses

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

Synthesis

594-44-5

20035-08-9

The general procedure for the synthesis of sodium ethylsulfite from ethylsulfonyl chloride was as follows: sodium sulfite (53.9 g, 0.428 mol), sodium bicarbonate (65.34 g, 0.778 mol), and deionized water (325 mL) were added to a four-necked flask equipped with a stirrer at room temperature and under nitrogen protection. The reaction mixture was stirred continuously at 80 °C for 1.3 hours. Subsequently, ethanesulfonyl chloride (50.0 g, 0.389 mol) was slowly added dropwise to the reaction system and the reaction continued to be stirred at the same temperature for 4.2 hours. Upon completion of the reaction, the reaction mixture was concentrated by rotary evaporator. Anhydrous ethanol was added to the concentrated residue and concentrated again. Next, toluene was added to the residue and the concentration process was repeated to completely remove water. The resulting solid was dried under vacuum, then anhydrous ethanol (100 mL) was added and the mixture was heated to reflux. The mixture was hot filtered and the solids were washed with a small amount of ethanol. All the filtrate and washings were combined and finally concentrated by rotary evaporator to give a white solid sodium ethylsulfite (38.96 g, yield calculated based on ethylsulfonyl chloride).

References

[1] RSC Advances, 2013, vol. 3, # 35, p. 15114 - 15120
[2] Chemistry - A European Journal, 2016, vol. 22, # 50, p. 18085 - 18091
[3] Macromolecules, 2018, vol. 51, # 20, p. 8188 - 8196
[4] Chemistry - A European Journal, 2016, vol. 22, # 25, p. 8694 - 8699
[5] Journal of Medicinal Chemistry, 1989, vol. 32, # 11, p. 2436 - 2442

Sodium ethanesulfinate Preparation Products And Raw materials

Raw materials

Preparation Products

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Sodium ethanesulfinate Suppliers

Shanghai Taijilin Industrial Co., Ltd.
Tel
021-50630626 18964684208
Fax
021-50563898
Email
kate@tajilin.com
Country
China
ProdList
1291
Advantage
58
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Yancheng Yuntao Chemical Co., Ltd.
Tel
13512592619
Email
2838893166@qq.com
Country
China
ProdList
97
Advantage
58
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7811
Advantage
57
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View Lastest Price from Sodium ethanesulfinate manufacturers

Career Henan Chemical Co
Product
ETHANE SULFINIC ACID SODIUM SALT 20035-08-9
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2018-08-01