ChemicalBook > CAS DataBase List > 4-Bromobiphenyl

4-Bromobiphenyl

Product Name
4-Bromobiphenyl
CAS No.
92-66-0
Chemical Name
4-Bromobiphenyl
Synonyms
92-66-0;4-BROMO-1,1'-BIPHENYL;pbb 3;P-BROMOBIPHENYL;PBB NO 3;4-Bromodipheny;4-Brom-biphenyl;4-BROMOBIPHENYL;4-BROMODIPHENYL;P-BROMODIPHENYL
CBNumber
CB2489092
Molecular Formula
C12H9Br
Formula Weight
233.1
MOL File
92-66-0.mol
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4-Bromobiphenyl Property

Melting point:
82-86 °C(lit.)
Boiling point:
310 °C(lit.)
Density 
0.9327
refractive index 
1.6565 (estimate)
Flash point:
143 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
dioxane: soluble1g/10 mL, clear, colorless to very faintly yellow
form 
Crystalline Flakes
color 
Almost white to slightly yellow
Water Solubility 
Insoluble
BRN 
1907453
Stability:
Stable. Incompatible with oxidizing agents.
InChIKey
PKJBWOWQJHHAHG-UHFFFAOYSA-N
CAS DataBase Reference
92-66-0(CAS DataBase Reference)
NIST Chemistry Reference
1,1'-Biphenyl, 4-bromo-(92-66-0)
EPA Substance Registry System
4-Bromobiphenyl (92-66-0)
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Safety

Hazard Codes 
Xi,N,Xn
Risk Statements 
36/37/38-50/53-41-37/38-22
Safety Statements 
22-24/25-37/39-26-61-60-39
RIDADR 
UN 3152 9/PG 2
WGK Germany 
3
RTECS 
DV1750100
TSCA 
T
HazardClass 
IRRITANT
PackingGroup 
Ⅲ
HS Code 
29036990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H400Very toxic to aquatic life

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P391Collect spillage. Hazardous to the aquatic environment

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
281999
Product name
4-Bromobiphenyl
Purity
98%
Packaging
10g
Price
$29.8
Updated
2024/03/01
Sigma-Aldrich
Product number
281999
Product name
4-Bromobiphenyl
Purity
98%
Packaging
50g
Price
$143
Updated
2024/03/01
Alfa Aesar
Product number
A12638
Product name
4-Bromobiphenyl, 98+%
Packaging
10g
Price
$32.8
Updated
2023/06/20
Alfa Aesar
Product number
A12638
Product name
4-Bromobiphenyl, 98+%
Packaging
50g
Price
$124
Updated
2023/06/20
Alfa Aesar
Product number
A12638
Product name
4-Bromobiphenyl, 98+%
Packaging
250g
Price
$493
Updated
2023/06/20
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4-Bromobiphenyl Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

4-Bromobiphenyl is used as halogenated hydrocarbon and Intermediates of Liquid Crystals. It is also used in used in the synthesis of 4-biphenylthiolate.

Uses

4-Bromobiphenyl is used as a reagent in the synthesis of spirooxindole derivatives for use as AMPK activators.  It is also used as a reagent in the preparation of indenoindole derivatives as organic electroluminescent device materials.

General Description

Colorless crystals. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Bromobiphenyl may be sensitive to light, and it can react with oxidizing materials.

Fire Hazard

Combustible.

Synthesis

Into a 250 ml reactor equipped with magnetic agitation means, a condenser, a dropping funnel, and a thermometer, the following materials were introduced:
(i) 15.4 g biphenyl (0.1 M);
(ii) 100 ml solvent
at ambient temperature Then, over 10 min, the bromine was poured therein (39.2 g/0.22 M), whereupon the mixture was agitated for a varying period of time at ambient temperature. Upon completion of the reaction, the excess bromine was consumed by sodium or potassium sulfite or bisulfite. The organic phase was washed, dried and diluted to a given volume, and analyzed by CPG to give 4-Bromobiphenyl.

Purification Methods

Crystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]

4-Bromobiphenyl Preparation Products And Raw materials

Raw materials

PotassiuM iodide starch pa Biphenyl Dextrin 4-Bromoaniline

Preparation Products

1-(4'-Bromobiphenyl-4-yl)-3-phenylpropenone Bromadiolone Brodifacoum
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4-Bromobiphenyl Suppliers

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View Lastest Price from 4-Bromobiphenyl manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
4-Bromobiphenyl 92-66-0
Price
US $0.00/KG
Min. Order
10g/Bag
Purity
99.90%
Supply Ability
20TONS
Release date
2020-11-23
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
4-Bromobiphenyl 92-66-0
Price
US $200.00-95.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-24
Henan Fengda Chemical Co., Ltd
Product
4-Bromobiphenyl 92-66-0
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-23

92-66-0, 4-BromobiphenylRelated Search:

Bifendate 2,3,3',4,4',5-HEXACHLOROBIPHENYL FIREMASTER BP-6 Decabromodiphenyl oxide trans-Bifenthtin 3-BROMOBIPHENYL,1,1’-biphenyl,3-bromo-(3-bromobiphenyl 2-BROMOBIPHENYL 98.0+%,2-BROMOBIPHENYL,o-Bromobiphenyl,BROMOBIPHENYL(2-) 2,7-Dibromofluorene 4-BROMO-4'-PROPYLBIPHENYL 4-BROMO-4'-ETHYLBIPHENYL 4-Bromo-4'-bromobiphenyl,1,1’-biphenyl,,4’-dibromo-(4,4’-bromobiphenyl 4-Bromo-2-fluorobiphenyl 2-Amino-7-bromofluorene 4,4'-DIBROMOOCTAFLUOROBIPHENYL 4- hydroxyl-4’-bromobiphenyl,4'-BROMOBIPHENYL-4-OL,4-HYDROXY-4'-BROMOBIPHENYL 3,9-Dibromobenzanthrone 4-BROMO-3-NITROBIPHENYL, 95 4-AMYL-4'-BROMOBIPHENYL

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  • The broMine biphenyl
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