Lily aldehyde
Description Chemical Properties- Product Name
- Lily aldehyde
- CAS No.
- 80-54-6
- Chemical Name
- Lily aldehyde
- Synonyms
- LILIAL;BUTYLPHENYL METHYLPROPIONAL;2-(4-TERT-BUTYLBENZYL)PROPIONALDEHYDE;LYSMERAL;Lillial;synthetic convallaria aldehyde;4-(1,1-Dimethylethyl)-methylbenzenepropanal;Propanal, alpha-methyl-beta-(p-tert.-butylphenyl)-;Lilyal;lilyall
- CBNumber
- CB2492379
- Molecular Formula
- C14H20O
- Formula Weight
- 204.31
- MOL File
- 80-54-6.mol
Lily aldehyde Property
- Melting point:
- 106-109 °C
- Boiling point:
- 150°C 10mm
- Density
- 0.946 g/mL at 20 °C(lit.)
- vapor pressure
- 0.25Pa at 20℃
- refractive index
- n20/D 1.505
- Flash point:
- 100°C
- storage temp.
- 2-8°C
- solubility
- Chloroform (Sparingly), Ethyl Acetate (Slightly)
- form
- Liquid
- color
- Colorless to Light yellow
- Odor
- at 100.00 %. floral muguet watery green powdery cumin
- Odor Type
- floral
- Water Solubility
- 33mg/L at 20℃
- BRN
- 880140
- InChIKey
- SDQFDHOLCGWZPU-UHFFFAOYSA-N
- LogP
- 4.2 at 24℃
- CAS DataBase Reference
- 80-54-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Lilial(80-54-6)
- EPA Substance Registry System
- Benzenepropanal, 4-(1,1-dimethylethyl)-.alpha.-methyl- (80-54-6)
Safety
- Hazard Codes
- Xn,N
- Risk Statements
- 22-38-51/53-62-43
- Safety Statements
- 60-61-36/37
- RIDADR
- UN 3082 9/PG 3
- WGK Germany
- 2
- RTECS
- MW4895000
- F
- 10
- HS Code
- 29121900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H317May cause an allergic skin reaction
H361Suspected of damaging fertility or the unborn child
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- CRM40184
- Product name
- Lilial solution
- Purity
- certified reference material, 2000?μg/mL in methanol, ampule of 1?mL
- Packaging
- 1mL
- Price
- $116
- Updated
- 2024/03/01
- Product number
- 43884
- Product name
- 2-(4-tert-Butylbenzyl)propionaldehyde
- Purity
- analytical standard
- Packaging
- 10mg
- Price
- $69.1
- Updated
- 2024/03/01
- Product number
- B1145
- Product name
- 3-(4-tert-Butylphenyl)isobutyraldehyde
- Purity
- >96.0%(GC)
- Packaging
- 25mL
- Price
- $29
- Updated
- 2024/03/01
- Product number
- B1145
- Product name
- 3-(4-tert-Butylphenyl)isobutyraldehyde
- Purity
- >96.0%(GC)
- Packaging
- 100mL
- Price
- $73
- Updated
- 2024/03/01
- Product number
- B1145
- Product name
- 3-(4-tert-Butylphenyl)isobutyraldehyde
- Purity
- >96.0%(GC)
- Packaging
- 500mL
- Price
- $217
- Updated
- 2024/03/01
Lily aldehyde Chemical Properties,Usage,Production
Description
Lily aldehyde (also known as lysmeral or Lilial) is a chemical compound commonly used as a perfume in cosmetic preparations and laundry powders1-3. It is fresh light green floral lily muguet lindenblossom aldehyde. Lilial is used in a wide variety of compositions where it confers a particularly recommended for floral notes such as muguet, linden-blossom and cyclamen2.
Chemical Properties
Lilial is a colorless to pale yellow liquid, as yet has not been found in nature. It has a higher stability than the homologous cyclamenaldehyde and therefore is used as scent in soaps.
Lilial is a widely used fragrance compound found naturally in the essential oil of chamomile and is used synthetically in a variety of beauty products, including perfumes, shampoos, deodorants, tanning lotions and hairstyling products, primarily for its Lily of the Valley aroma.
Chemical Properties
Lily aldehyde is a homolog of
cyclamenaldehyde. The racemic compound is a colorless to slightly yellow liquid
with a mild-floral odor, reminiscent of cyclamen and lily of the valley.
The aldehyde is prepared by the same routes as cyclamenaldehyde.
Other routes start from ??-methylcinnamaldehyde. ??-Methylcinnamaldehyde
(from benzaldehyde and propionaldehyde) is hydrogenated to ??-methyldihydrocinnamic
alcohol.The alcohol is alkylated with tert-butyl chloride or isobutene to
4-tert-butyl-??-methyldihydrocinnamic alcohol, which is subsequently dehydrogenated to the desired aldehyde.
4-tert-Butyl-??-methyldihydrocinnamaldehyde is more stable than cyclamenaldehyde
and is a popular component of flower compositions, particularly lily of the
valley and linden types, because of its mild, pleasant, blossomfragrance. It is used
in a wide range of perfume types, but especially in soap and detergent perfumes.
Uses
In addition to its applications in the perfume and aroma industry, lilial is used mainly for the synthesis of substituted 3-(4-tert-butylphenyl)-2-methylpropylamines, a new class of substances with fungicidal properties. These compounds are effective against mildew in barley and wheat.
Uses
2-(4-tert-Butylbenzyl)propionaldehyde may be used as a reference standard for the determination of 2-(4-tert-butylbenzyl)propionaldehyde in:
- Human urine samples by ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) equipped with electrospray ionization (ESI) source and multiple reaction monitoring (MRM) mode of detection.
- Deodorants and air fresheners by sonication extraction coupled with gas chromatography-mass spectrometry (GC-MS).
- Scented consumer products by GC-MS as well as GC in combination with olfactometry.
Production Methods
Lily aldehyde is produced industrially almost solely by aldol condensation of 4-tert-butylbenzaldehyde and propionaldehyde to give 4-tert-butyl-α-methylcinnamaldehyde, which can be hydrogenated selectively on noble metal catalysts such as Pd, Rh, Pd – Pr2O3 on Al2O3, or on modified cobalt catalysts. The aldol condensation and the hydrogenation can be carried out in one step in the presence of a hydrogenation catalyst.
The Friedel – Crafts reaction of 4-tertbutylbenzene with methacrolein or methacrolein diacetate proceeds in an analogous manner to the preparation of cyclamenaldehyde.
Further possibilities are the Rh-catalyzed hydroformylation of 1-(4-tert-butylphenyl)-1- methoxypropene and subsequent partial hydrogenation, the palladium salt catalyzed reaction of 4-tert-butylphenylhalide with methallylalcohol, and the dehydrogenation of 3-(4-tert-butylphenyl)-2-methylpropanol on silver catalysts.
General Description
2-(4-tert-Butylbenzyl)propionaldehyde is categorized under the synthetic fragrance class of compounds widely utilized in consumer products such as perfumes, after shave lotions, cosmetics, etc.
Flammability and Explosibility
Non flammable
Trade name
Lilestralis Pure (Innospec), Lysmeral® Extra (BASF).
Contact allergens
Lilial? is a synthetic compound listed as a fragrance allergen. Its presence is indicated on cosmetics within the EU.
Lily aldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Lily aldehyde manufacturers
- Product
- Lily aldehyde 80-54-6
- Price
- US $120.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-04-25
- Product
- Lily aldehyde 80-54-6
- Price
- US $80.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-04-25
- Product
- Lily aldehyde 80-54-6
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-22