4-ETHYNYLBENZALDEHYDE
- Product Name
- 4-ETHYNYLBENZALDEHYDE
- CAS No.
- 63697-96-1
- Chemical Name
- 4-ETHYNYLBENZALDEHYDE
- Synonyms
- DK850;Zinc02548316;CHEMBRDG-BB 4003406;4-ethynylbezaldehyde;4-ETHYNYLBENZALDEHYDE;Benzaldehyde,4-ethynyl-;4-Ethynylbenzaldehyde >4-ETHYNYLBENZALDEHYDE,95%;4-Ethynylbenzaldehyde 97%;Benzaldehyde, 4-ethynyl- (9CI)
- CBNumber
- CB2493912
- Molecular Formula
- C9H6O
- Formula Weight
- 130.14
- MOL File
- 63697-96-1.mol
4-ETHYNYLBENZALDEHYDE Property
- Melting point:
- 89-93 °C (lit.)
- Boiling point:
- 223.8±23.0 °C(Predicted)
- Density
- 1.07±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- form
- Powder or Crystalline Powder
- color
- White to orange to brown
- λmax
- 297nm(CH3CN)(lit.)
- InChI
- InChI=1S/C9H6O/c1-2-8-3-5-9(7-10)6-4-8/h1,3-7H
- InChIKey
- BGMHQBQFJYJLBP-UHFFFAOYSA-N
- SMILES
- C(=O)C1=CC=C(C#C)C=C1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 597430
- Product name
- 4-Ethynylbenzaldehyde
- Purity
- 97%
- Packaging
- 1g
- Price
- $147
- Updated
- 2025/07/31
- Product number
- 597430
- Product name
- 4-Ethynylbenzaldehyde
- Purity
- 97%
- Packaging
- 5g
- Price
- $399.7
- Updated
- 2025/07/31
- Product number
- E0987
- Product name
- 4-Ethynylbenzaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $73
- Updated
- 2025/07/31
- Product number
- E932580
- Product name
- 4-Ethynylbenzaldehyde
- Packaging
- 250mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- OR01516
- Product name
- 4-Ethynylbenzaldehyde
- Purity
- 97%
- Packaging
- 1g
- Price
- $56
- Updated
- 2021/12/16
4-ETHYNYLBENZALDEHYDE Chemical Properties,Usage,Production
Uses
4-?Ethynylbenzaldehyde is commonly used in solar cells as the acceptor unit.
Synthesis Reference(s)
The Journal of Organic Chemistry, 46, p. 2280, 1981 DOI: 10.1021/jo00324a015
Synthesis
77123-57-0
63697-96-1
General procedure for the synthesis of 4-ethynylbenzaldehyde from 4-trimethylsilylethynylbenzaldehyde: Compound 4 (727 mg, 3.6 mmol) was dissolved in 15 mL of anhydrous THF, followed by the addition of 2 mL of aqueous KOH (298 mg, 4 mmol). The reaction mixture was stirred at room temperature for 2 hours. Upon completion of the reaction, the THF solvent was removed by rotary evaporator. The reaction mixture was extracted with ethyl acetate (EA) and washed three times with saturated NaCl solution. The combined organic phases were dried with anhydrous Na2SO4, filtered and concentrated. Finally, purification by column chromatography (eluent was petroleum ether and dichloromethane, 1:1, v/v) gave 450 mg of compound 5 as a light yellow solid in 97% yield.
References
[1] Journal of the American Chemical Society, 2009, vol. 131, # 2, p. 634 - 643
[2] Chemical Communications, 2011, vol. 47, # 4, p. 1282 - 1284
[3] Journal of Materials Chemistry A, 2013, vol. 1, # 34, p. 10008 - 10015
[4] ChemPhysChem, 2016, p. 2066 - 2078
[5] Journal of the American Chemical Society, 2016, vol. 138, # 51, p. 16703 - 16710
4-ETHYNYLBENZALDEHYDE Preparation Products And Raw materials
Raw materials
Preparation Products
4-ETHYNYLBENZALDEHYDE Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
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- Europe
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View Lastest Price from 4-ETHYNYLBENZALDEHYDE manufacturers
- Product
- 4-ETHYNYLBENZALDEHYDE 63697-96-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-07