ChemicalBook > CAS DataBase List > 3-Methylthiophene

3-Methylthiophene

Product Name
3-Methylthiophene
CAS No.
616-44-4
Chemical Name
3-Methylthiophene
Synonyms
Thiophene, 3-methyl-;3MT;4-Methylthiophene;beta-methylthiophene;3-Thiotolene;β-Methylthiophene;3-methyl-thiophen;3-METHYLTHIOPHENE;Methyl-3-thiophene;3-Methyl[b]thiophene
CBNumber
CB2664882
Molecular Formula
C5H6S
Formula Weight
98.17
MOL File
616-44-4.mol
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3-Methylthiophene Property

Melting point:
-69 °C (lit.)
Boiling point:
114 °C/738 mmHg (lit.)
Density 
1.016 g/mL at 25 °C (lit.)
vapor pressure 
42.4 mm Hg ( 37.7 °C)
refractive index 
n20/D 1.519(lit.)
Flash point:
52 °F
storage temp. 
Flammables area
solubility 
0.40g/l
form 
Liquid
color 
Clear colorless to light yellow
Specific Gravity
1.016
Water Solubility 
insoluble
BRN 
1300
Stability:
Volatile
InChIKey
QENGPZGAWFQWCZ-UHFFFAOYSA-N
LogP
2.340
CAS DataBase Reference
616-44-4(CAS DataBase Reference)
NIST Chemistry Reference
Thiophene, 3-methyl-(616-44-4)
EPA Substance Registry System
Thiophene, 3-methyl- (616-44-4)
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Safety

Hazard Codes 
F,Xn,Xi
Risk Statements 
11-20/22-36/37/38-37
Safety Statements 
7-16-29-33-36-37/39-26-7/9
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
RTECS 
XM9800000
8-10-13-23
Hazard Note 
Flammable/Harmful
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
M84402
Product name
3-Methylthiophene
Purity
98%
Packaging
25g
Price
$44.6
Updated
2024/03/01
TCI Chemical
Product number
M0440
Product name
3-Methylthiophene
Purity
>98.0%(GC)
Packaging
25g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
M0440
Product name
3-Methylthiophene
Purity
>98.0%(GC)
Packaging
500g
Price
$389
Updated
2024/03/01
Alfa Aesar
Product number
A13394
Product name
3-Methylthiophene, 98+%
Packaging
25g
Price
$36.65
Updated
2024/03/01
Alfa Aesar
Product number
A13394
Product name
3-Methylthiophene, 98+%
Packaging
100g
Price
$102.65
Updated
2024/03/01
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3-Methylthiophene Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

A thiophene derivative used as an electropolymerization monomer in conducting polymer research.

Uses

Conducting polymer precursor.1

Uses

Thiophene, 2-methyIthiopheney and 3-methylthiophene act as inhibitors for the polymerization of trichloroethylene in a solvent used for the degreasing of iron and aluminum, said polymerization being catalyzed by contact of the solvent with the metals. Bonz, in 1885, reported the formation of a dichloroethylthiophene from chlorination of 2-ethylthiophene in the cold. Is Opolski studied the chlorination of 2- and 3-methylthiophenes, 2-ethyl- and 2-butylthiophene and reported constants for the monochloro derivatives. Voerman has chlorinated 3-methylthiophene in the side chain with phosphorus trichloride in the sunlight, but concurrent ring chlorination predominates. 3-Methylthiophene gives a unique reaction with alkyl- or arylsodium in which the substitution takes place exclusively in the 5-position rather than in the expected 2-position.

Uses

3-Methylthiophene is found in coffee and coffee products. it is a maillard product, present in roast coffee aroma.
3-Methylthiophene is a member of thiophenes. Conducting polymer precursor. Copolymerization of 3-alkylthiophene and 3-methylthiophene is a promising approach to provide a polymer which has both solution processible property and high electrical conductivity.

Definition

ChEBI: 3-Methylthiophene is a member of thiophenes.

Purification Methods

Dry it with Na2SO4, then distil it from sodium. [Beilstein 17 III/IV 277, 17/1 V 331.]

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View Lastest Price from 3-Methylthiophene manufacturers

Hebei Duling International Trade Co. LTD
Product
3-Methylthiophene 616-44-4
Price
US $30.00/kg
Min. Order
14kg
Purity
99%
Supply Ability
20 tons
Release date
2023-03-17
Hebei Yanxi Chemical Co., Ltd.
Product
3-Methylthiophene 616-44-4
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-09-21
Hebei Guanlang Biotechnology Co., Ltd.
Product
3-Methylthiophene 616-44-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-10-09

616-44-4, 3-MethylthiopheneRelated Search:


  • 3-Methylthiophene, 99+%
  • Thiophene, 3-methyl-
  • 3-Methylthiophene,98%
  • 3-Methyl[b]thiophene
  • 4-Methylthiophene
  • β-Methylthiophene
  • 3-Methylthiophene, 99+% 50ML
  • 3MT
  • 3-METHYLTHIOPHENE
  • 3-methyl-thiophen
  • 3-Thiotolene
  • beta-methylthiophene
  • Methyl-3-thiophene
  • 3-Methylthiophene&gt
  • 3-Methylthiophene USP/EP/BP
  • 3-Methylthiophene, ≥ 98.0%
  • 616-44-4
  • 614-44-4
  • 616-44-1
  • 616444
  • C5H6S
  • Thiophenes
  • Heterocyclic Building Blocks
  • Reagents for Conducting Polymer Research
  • 3-Alkylthiophenes (for Conduting Polymer Research)
  • Building Blocks
  • Building Blocks
  • Heterocyclic Building Blocks
  • 3-Alkylthiophenes (for Conduting Polymer Research)
  • Functional Materials
  • Reagents for Conducting Polymer Research
  • Thiophen
  • C4 to C6
  • Building Blocks
  • Chemical Synthesis
  • Heterocyclic Building Blocks
  • Aromatics
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Sulfur & Selenium Compounds
  • Heterocycles
  • Thiophene&Benzothiophene
  • Heterocyclic Compounds
  • Thiophens
  • Thiophenes