Hexafluoropropylene oxide Property

Melting point:

-129°C

Boiling point:

−42 °C(lit.)

Density 

1.67±0.1 g/cm3(Predicted)

vapor pressure 

680.85kPa at 25℃

Water Solubility 

16.3μg/L at 22.7℃

InChI

InChI=1S/C3F6O/c4-1(2(5,6)7)3(8,9)10-1

InChIKey

PGFXOWRDDHCDTE-UHFFFAOYSA-N

SMILES

O1C(F)(C(F)(F)F)C1(F)F

LogP

1.72 at 25℃

CAS DataBase Reference

428-59-1(CAS DataBase Reference)

NIST Chemistry Reference

Oxirane, trifluoro(trifluoromethyl)-(428-59-1)

EPA Substance Registry System

Oxirane, 2,2,3-trifluoro-3-(trifluoromethyl)- (428-59-1)

Safety

Hazard Codes 

Xi

Risk Statements 

36/37/38-44

Safety Statements 

7-26-37/39-38

RIDADR 

UN 1956 2.2

WGK Germany 

3

Hazard Note 

Irritant

HazardClass 

2.2

Hazardous Substances Data

428-59-1(Hazardous Substances Data)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P234Keep only in original container.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P390Absorb spillage to prevent material damage.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

Hexafluoropropylene oxide Chemical Properties,Usage,Production

Uses

Hexafluoropropylene oxide is an important intermediate of organic fluorine material.HFPO is mainly used in the manufacture of high-quality fluorinated compounds.It is the main component of perfluor-vinyl ether(PPVE,PSVE,PFVE,PMVE) and the monomer of fluorinated surfactants and fluorinated ether oil.

General Description

Hexafluoropropylene oxide is a colorless odorless gas. Hexafluoropropylene oxide is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Its vapors are heavier than air. Hexafluoropropylene oxide can cause asphyxiation by the displacement of air. Exposure of the container to prolonged heat or fire may cause Hexafluoropropylene oxide to rupture violently and rocket.

Reactivity Profile

Hexafluoropropylene oxide is a chlorinated epoxide. Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.

Fire Hazard

Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.

Flammability and Explosibility

Non flammable