(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

Reaction

Product Name: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
CAS No.: 494227-35-9
Chemical Name: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
Synonyms: MANDYPHOS SL-M002-1;(R)-(S)-NMe2-Pcy2-Mandyphos;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLA;(R,R)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc;(R,R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(SP,SμP)-1,1μ-Bis(dicyclohexylphosphino)-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(SP,S′P)-1,1′-Bis(dicyclohexylphosphino)-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis(dicyclohexylphosphino)ferrocene;(1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene;(SP,S'P)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene
CBNumber: CB2677457
Molecular Formula: C52H72FeN2P2
Formula Weight: 842.95
MOL File: 494227-35-9.mol

More

Less

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Property

alpha: +54.6° (c 1.0, CHCl3)
form: solid
color: orange-red
Stability:: store cold
CAS DataBase Reference: 494227-35-9

More

Less

Safety

WGK Germany: 3
HS Code: 29319090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Strem Chemicals

Product number: 26-0240
Product name: (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging: 100mg
Price: $96
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0240
Product name: (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging: 500mg
Price: $355
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0240
Product name: (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging: 2g
Price: $1207
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0240
Product name: (S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene, min. 97%
Packaging: 10g
Price: $4824
Updated: 2024/03/01

AK Scientific

Product number: 7420AJ
Product name: (alphaR,alphaR)-2,2'-Bis(alpha-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(dicyclohexylphosphino)ferrocene
Packaging: 10g
Price: $4902
Updated: 2021/12/16

More

Less

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Chemical Properties,Usage,Production

Reaction

Ligand for a copper-catalyzed domino conjugated reduction/aldol reaction of methyl acrylate with various alkyl aryl ketones. Ligand for gold catalyzed Phenol synthesis from furyldialkyne
Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [(η6-benzylamine)Cr(CO)3]

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Suppliers

China 34 Germany 2 Switzerland 1 United States 4 Global 41

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

Sinocompound Catalysts Co., Ltd.

Tel: 0512-67216630 18962121273
Fax: 0512-56316689
Email: sales@sinocompound.com
Country: China
ProdList: 278
Advantage: 64

Shaanxi Rock New Materials Co., Ltd.

Tel: 0917-8888777, 3380777,18691786767; 15619786767
Email: xuya@bjrock.com
Country: China
ProdList: 310
Advantage: 62

Xinxiang Runyu Material Co., Ltd.

Tel: 166-166-37336996 15690792173
Fax: 0373-7759608
Email: chenxi.song@runvmat.com
Country: China
ProdList: 294
Advantage: 55

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Zhengzhou HQ Material Co., Ltd.

Tel: 0371-67759225 13526468238
Fax: +86-37155919558
Email: sales@hqmat.com
Country: China
ProdList: 814
Advantage: 55

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

Tel: 0371-65511006 18625597674
Email: sales@kingorgchem.com
Country: China
ProdList: 953
Advantage: 55

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2603
Advantage: 58

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 10007
Advantage: 58

More

Less

View Lastest Price from (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE manufacturers

Career Henan Chemical Co

Product: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 494227-35-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kgs
Release date: 2020-01-10

494227-35-9, (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENERelated Search:

(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE Ferrocene (R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE 1,1'-DIMETHYLFERROCENE 1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE N,N-Dimethylaminomethylferrocene 1,1'-DIETHYLFERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

MANDYPHOS SL-M002-1

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLA

(S,S)-(+)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

(<alpha>R,<alpha>R)-1,1#-Bis[<alpha>-(dimethylamino)benzyl]-(S,S)-2,2#-bis(dicyc

(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene,min.97%

(r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis(dicyclohexylphosphino)ferrocene (acc to cas)

(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis(dicyclohexylphosphino)ferrocene

(SP,SμP)-1,1μ-Bis(dicyclohexylphosphino)-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene

Mandyphos SL-M002-1, (1R,1μRμ)-1,1μ-Bis(dicyclohexylphosphino)-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)

(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino) ferrocene, min. 97%

(1R,1′R′)-1,1′-Bis(dicyclohexylphosphino)-2,2′-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)

(R)-(S)-NMe2-Pcy2-Mandyphos

(αR,αR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1′-bis(dicyclohexyphosphino)ferrocene

(aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(dicyclohexylphosphino)ferrocene

(aR,aR)-2,2'-Bis(a-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(dicyclohexylphosphino)-ferrocene

(1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene

(SP,S'P)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene >=97%

(S,S)Fc-1,1’-Bis(dicyclohexylphosphino)-2,2’-bis[(R,R)C-(N,Ndimethylamino)phenylmethyl]ferrocene

(SP,S'P)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene

(SP,S′P)-1,1′-Bis(dicyclohexylphosphino)-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene

(1R,1'R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene

(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene

(R,R)-1,1'-Bis(dicyclohexylphosphino)-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene

(S,S)-(+)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(dicyclohexylphosphino)ferrocene,97%

494227-35-9

C54H74FeN2P2

C52H74FeN2P2

Privileged Ligands

Solvias Ligands

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Chiral Phosphine

Ferrocene Series

Mandyphos Series