ChemicalBook > CAS DataBase List > 2-Bromo-4-methylphenol

2-Bromo-4-methylphenol

Product Name
2-Bromo-4-methylphenol
CAS No.
6627-55-0
Chemical Name
2-Bromo-4-methylphenol
Synonyms
AKOS BBB/368;2-bromo-p-cres;2-bromo-p-creso;2-BROMO-P-CRESOL;2-Bromo-4-cresol;p-Cresol, 2-bromo-;2-Bromo-p-cresol >2-Bromo-p-methylphenol;2-BROMO-4-METHYLPHENOL;4-Methyl-2-bromophenol
CBNumber
CB2703260
Molecular Formula
C7H7BrO
Formula Weight
187.03
MOL File
6627-55-0.mol
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2-Bromo-4-methylphenol Property

Melting point:
54-55 °C
Boiling point:
245-247 °C
Density 
1.554±0.06 g/cm3 | Condition: Temp: 20 °C Press: 760 Torr
refractive index 
n20/D 1.578(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Chloroform, Methanol
pka
8.73±0.18(Predicted)
form 
powder to lump to clear liquid
color 
White or Colorless to Light yellow
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C7H7BrO/c1-5-2-3-7(9)6(8)4-5/h2-4,9H,1H3
InChIKey
MTIDYGLTAOZOGU-UHFFFAOYSA-N
SMILES
C1(O)=CC=C(C)C=C1Br
CAS DataBase Reference
6627-55-0(CAS DataBase Reference)
NIST Chemistry Reference
Phenol, 2-bromo-4-methyl-(6627-55-0)
EPA Substance Registry System
Phenol, 2-bromo-4-methyl- (6627-55-0)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-21/22
Safety Statements 
26-37/39-36/37/39-24/25
WGK Germany 
3
RTECS 
GO6868200
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29071990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B72809
Product name
2-Bromo-4-methylphenol
Purity
96%
Packaging
5g
Price
$60
Updated
2025/07/31
Sigma-Aldrich
Product number
B72809
Product name
2-Bromo-4-methylphenol
Purity
96%
Packaging
25g
Price
$229
Updated
2023/06/20
TCI Chemical
Product number
B0808
Product name
2-Bromo-p-cresol
Purity
>98.0%(GC)
Packaging
25g
Price
$95
Updated
2025/07/31
TCI Chemical
Product number
B0808
Product name
2-Bromo-p-cresol
Purity
>98.0%(GC)
Packaging
500g
Price
$1134
Updated
2025/07/31
TRC
Product number
B686105
Product name
2-Bromo-4-methylphenol
Packaging
250g
Price
$305
Updated
2021/12/16
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2-Bromo-4-methylphenol Chemical Properties,Usage,Production

Chemical Properties

clear colourless to pale yellow liquid

Uses

It is applied as a compound responsible for iodine off-flavor in wines.

Synthesis

25458-49-5

6627-55-0

General procedure for the synthesis of 2-bromo-4-methylphenol from 4-(methoxymethoxy)toluene: To a 10 mL round-bottomed flask equipped with a magnetic stirring bar were added 4-(methoxymethoxy)toluene (0.1 mmol), carbon tetrabromide (33 mg, 0.1 mmol), anhydrous acetonitrile (1 mL), and tris(2,2'-bipyridine) ruthenium (II) dichloride (3.8 mg, 0.005 mmol). The reaction mixture was irradiated at room temperature using a blue LED (1 W) and air was continuously passed until the complete disappearance of the feedstock was shown by thin layer chromatography (TLC) monitoring. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was purified by fast column chromatography to afford the target product 2-bromo-4-methylphenol.

References

[1] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 622 - 627

2-Bromo-4-methylphenol Preparation Products And Raw materials

Raw materials

dilute sulphuric acid 2-Bromo-4-methylaniline p-Cresol

Preparation Products

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2-Bromo-4-methylphenol Suppliers

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View Lastest Price from 2-Bromo-4-methylphenol manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2-Bromo-4-methylphenol 6627-55-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-31
Henan Aochuang Chemical Co.,Ltd.
Product
2-Bromo-4-methylphenol 6627-55-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-08
Hebei Yanxi Chemical Co., Ltd.
Product
2-Bromo-4-methylphenol 6627-55-0
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-10-08

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