4-Bromophenol

Product Name: 4-Bromophenol
CAS No.: 106-41-2
Chemical Name: 4-Bromophenol
Synonyms: P-BROMOPHENOL;Para Bromo Phenol;4-Bromphenol;Phenol, 4-bromo-;p-Bromphenol;4-BROMOPHENOL;BROMOPHENOL-4;P-Bromophenlo;4-bromo-pheno;p-bromo-pheno
CBNumber: CB7181317
Molecular Formula: C6H5BrO
Formula Weight: 173.01
MOL File: 106-41-2.mol

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4-Bromophenol Property

Melting point:: 61-64 °C (lit.)
Boiling point:: 235-236 °C (lit.)
Density: 1.84
refractive index: 1.5085 (estimate)
Flash point:: 235-238°C
storage temp.: room temp
solubility: 14g/l
form: Crystalline Solid
pka: 9.37(at 25℃)
color: Pinkish-brown
Water Solubility: It is insoluble in water. It is soluble in 5%ethanol.
λmax: 282nm(EtOH)(lit.)
Merck: 14,1428
BRN: 1680024
CAS DataBase Reference: 106-41-2(CAS DataBase Reference)
NIST Chemistry Reference: 4-Bromophenol(106-41-2)
EPA Substance Registry System: Phenol, 4-bromo- (106-41-2)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38-20/21/22
Safety Statements: 26-37/39-36
RIDADR: 2811
WGK Germany: 2
RTECS: SJ7960000
F: 8-10-23
Hazard Note: Irritant
TSCA: Yes
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29081000
Hazardous Substances Data: 106-41-2(Hazardous Substances Data)
Toxicity: mouse,LD50,intraperitoneal,411mg/kg (411mg/kg),Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 44(12), Pg. 19, 1979.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: B75808
Product name: 4-Bromophenol
Purity: 99%
Packaging: 5g
Price: $37.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: B75808
Product name: 4-Bromophenol
Purity: 99%
Packaging: 100g
Price: $76.3
Updated: 2024/03/01

TCI Chemical

Product number: B0787
Product name: 4-Bromophenol
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $19
Updated: 2024/03/01

TCI Chemical

Product number: B0787
Product name: 4-Bromophenol
Purity: >98.0%(GC)(T)
Packaging: 100g
Price: $33
Updated: 2024/03/01

Alfa Aesar

Product number: A14873
Product name: 4-Bromophenol, 99%
Packaging: 100g
Price: $61.8
Updated: 2024/03/01

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4-Bromophenol Chemical Properties,Usage,Production

Chemical Properties

4-Bromophenol is a pinkish-brown crystalline solid. four-sided biconical crystal precipitated from ether or chloroform. The melting point is 66.4 ℃, and a small amount of water can reduce the melting point a lot. Soluble in water, chloroform, easily soluble in ethanol, ether and glacial acetic acid, soluble in 7 parts of water.

Uses

4-Bromophenol is used as an intermediate in medicine grade. It is also used as a phenol that is used in Stille reactions. It is used in the intermediate of organic synthesis, flame retardant and pharmaceutical industry.

Application

4-Bromophenol is a phenolic derivative that It can used as a reagent in Stille reactions or Intermediates of Liquid Crystals.

Preparation

4-Bromophenol is synthesized by bromination of phenol. The bromine and carbon disulfide solution was added to the phenolic carbon disulfide solution, and the addition was started below 5°C, and the addition was completed under stirring for 2 hours. Phenol and bromine are approximately equimolar ingredients. Distill the reactant to remove carbon disulfide, and then conduct fractional distillation under reduced pressure to collect fractions at 145-150°C (3.32-3.99kPa) to obtain the product. Yield 80-84%.

Definition

ChEBI: 4-bromophenol is a bromophenol containing only hydroxy and bromo substituents that are para to one another. It has a role as a mouse metabolite, a persistent organic pollutant, a human xenobiotic metabolite, a rat metabolite, a human urinary metabolite and a marine metabolite.

Synthesis Reference(s)

Tetrahedron, 45, p. 7869, 1989 DOI: 10.1016/S0040-4020(01)85800-2
The Journal of Organic Chemistry, 23, p. 280, 1958 DOI: 10.1021/jo01096a033

Purification Methods

Crystallise the phenol from CHCl3, CCl4, pet ether (b 40-60o), or water and dry it at 70o under vacuum for 2hours. [Beilstein 6 IV 1043.]

4-Bromophenol Preparation Products And Raw materials

Raw materials

Carbon disulfide Government regulation

Preparation Products

1-BENZOFURAN-5-CARBONITRILE BENZOFURAN-5-BORONIC ACID 5-BROMO-2(3H)-BENZOXAZOLONE 4-Bromoanisole 6-Bromo-2,3-dihydro-4H-chromen-4-one 1-Benzofuran-5-carbaldehyde N-[2-(4-Bromophenoxy)ethyl]pyrrolidine 4-Benzyloxybenzeneboronic acid 4-ISOBUTOXYPHENYLBORONIC ACID 4-Bromo-2-nitrophenol 5-BROMO-2-BENZOXAZOLINONE 97 4-Hydroxyphenylboronic acid 6-BROMO-2H-1,4-BENZOXAZIN-3(4H)-ONE 4-Bromo-2-chlorophenol Tamoxifen citrate O,O-Di(4-bromophenyl)thiophosphoryl chloride 2-Amino-4-bromophenol 5-Bromo-1-benzofuran 3-(4-BROMOPHENOXY)PROPANOIC ACID 6-bromo-3,4-dihydro-2H-chromen-4-ol

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4-Bromophenol Suppliers

Americas 1 Belgium 3 Canada 4 China 339 Cyprus 1 Europe 3 France 2 Germany 13 India 79 Israel 1 Japan 11 Norway 1 Slovakia 1 South Korea 3 Switzerland 2 The Netherlands 2 Ukraine 2 United Kingdom 23 United States 68 Global 559

JINGJIANG MALONG CHEMICAL MANUFACTURING CO., LTD.

Tel: 0523-84580141 13961024239
Email: 13961024239@139.com
Country: China
ProdList: 1
Advantage: 58

Jiangsu Mingchem Corporation

Tel: 0519-85170101
Fax: 0519-85170505
Email: sales@mingchem.com
Country: China
ProdList: 607
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Shanghai Taijilin Industrial Co., Ltd.

Tel: 021-021-50630626 18964684208
Fax: 021-50563898
Email: kate@tajilin.com
Country: China
ProdList: 1212
Advantage: 58

Hubei Hongfuda Biotechnology Co., Ltd.

Tel: 19107255884
Email: 2013537414@qq.com
Country: China
ProdList: 501
Advantage: 58

Shanghai Matyang New Material Technology Co., LTD

Tel: 18051161798
Email: dongnijj@foxmail.com
Country: China
ProdList: 19
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Nantong Xiaochang Pharmaceutical Trading Co., Ltd.

Tel: 0513-82104991 18912868322
Fax: QQ1907456386
Email: sales10@btcpharm.com
Country: China
ProdList: 1356
Advantage: 58

Huaian Jiamu Biotechnology Co., Ltd.

Tel: 0517-83187139 18205232085
Email: cai@jiamu-bio.com
Country: China
ProdList: 980
Advantage: 58

Shanghai Boyle Chemical Co., Ltd.

Tel
Fax: 86-21-57758967
Email: sales@boylechem.com
Country: China
ProdList: 2923
Advantage: 55

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3576
Advantage: 66

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View Lastest Price from 4-Bromophenol manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: 4-Bromophenol 106-41-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-07-04

Hebei Guanlang Biotechnology Co., Ltd.

Product: 4-Bromophenol 106-41-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-02-25

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-Bromophenol 106-41-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

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TIANFU-CHEM CAS:106-41-2 4-Bromophenol

106-41-2

BrC6H4OH

Organic Building Blocks

Phenols

Oxygen Compounds

ARYL HALIDE

Building Blocks

Building Blocks for Liquid Crystals

Phenols (Building Blocks for Liquid Crystals)

intermediates

alcohol| alkyl bromide

Bromo

Halogenated

Volatiles/ Semivolatiles

Building Blocks for Liquid Crystals

Functional Materials