4-Hydroxyphenylboronic acid

Product Name: 4-Hydroxyphenylboronic acid
CAS No.: 71597-85-8
Chemical Name: 4-Hydroxyphenylboronic acid
Synonyms: ACF2;AKOS BRN-0188;4-BORONOPHENOL;RARECHEM AH PB 0222;4-Hydroxybenzeneboronic;4-DIHYDROXYBORANYL-PHENOL;4-Hydroxyphenylboronicaci;4-HYDROXYPHENYLBORONIC ACID;4-HYDROXYBENZENEBORONIC ACID;(P-HYDROXYPHENYL)BORONIC ACID
CBNumber: CB5691083
Molecular Formula: C6H7BO3
Formula Weight: 137.93
MOL File: 71597-85-8.mol

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4-Hydroxyphenylboronic acid Property

Melting point:: >230 °C (lit.)
Boiling point:: 351.4±44.0 °C(Predicted)
Density: 1.32±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Acetonitrile, DMSO, Methanol
form: Powder
pka: 9.09±0.10(Predicted)
color: Off-white to light brown
Water Solubility: 25 g/L
BRN: 2963491
InChIKey: COIQUVGFTILYGA-UHFFFAOYSA-N
CAS DataBase Reference: 71597-85-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,C
Risk Statements: 36/37/38-34
Safety Statements: 26-36-37/39-45-36/37/39-27
WGK Germany: 3
TSCA: No
HS Code: 2931 90 00
HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.43854
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥97% (acidimetric)
Packaging: 1g
Price: $80.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.43854
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥97% (acidimetric)
Packaging: 5G
Price: $287
Updated: 2024/03/01

Sigma-Aldrich

Product number: 523976
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥95.0%
Packaging: 1g
Price: $62.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 523976
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥95.0%
Packaging: 5g
Price: $134
Updated: 2024/03/01

TCI Chemical

Product number: H1228
Product name: 4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $44
Updated: 2024/03/01

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4-Hydroxyphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

off-white to light brown powder

Uses

4-Hydroxybenzeneboronic acid is used for Suzuki-Miyaura coupling and Stille coupling and potential for introducing different alkyl groups, palladium-catalyzed aminocarbonylation and cross-coupling reactions, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles. It is also used in preparation of rod-like dendronized polymers.

Uses

4-Hydroxyphenylboronic acid can be used as a reactant in:

Suzuki-Miyaura coupling and Stille coupling reactions.
Palladium-catalyzed aminocarbonylation and cross-coupling reactions.
Suzuki reaction for preparation of bio-supported palladium nanoparticles as phosphine-free catalysts.
Cu₂O-catalyzed aerobic oxidative cross-coupling of tetrazoles.

It can also be used to prepare/promote:

PDK1 inhibitory activity (cancer cell growth, survival, and tumorigenesis inhibitor).
Rod-like dendronized polymers containing G4 and G5 ester dendrons via macromonomer approach by living ROMP.
Estrone-derived cyclopamine analogs as Sonic Hedgehog signaling inhibitors for anti-cancer chemotherapeutics.
Enzymatic inhibitors for the treatment of Gram-negative bacterial infections.
Oligoarenes by Suzuki-Miyaura palladium-catalyzed cross-coupling.

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 6705, 1996 DOI: 10.1016/S0040-4039(96)01468-2

4-Hydroxyphenylboronic acid Preparation Products And Raw materials

Raw materials

Tetrahydrofuran 4-Bromophenol Triisopropyl borate n-Butyllithium

Preparation Products

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4-Hydroxyphenylboronic acid Suppliers

Americas 1 Belgium 1 Canada 1 China 335 Europe 3 France 1 Germany 10 India 12 Japan 2 Jordan 1 Russia 1 Switzerland 1 Ukraine 1 United Kingdom 12 United States 41 Global 423

AllyChem Co., Ltd.

Tel: 0411-62313318 13942603642
Fax: 0411-87549748
Email: info@allychem.com
Country: China
ProdList: 928
Advantage: 65

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TAIYUAN RHF CO.,LTD.

Tel: +86 351 7031519
Fax: +86 351 7031519
Email: sales@RHFChem.com
Country: China
ProdList: 2338
Advantage: 56

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 2963
Advantage: 65

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View Lastest Price from 4-Hydroxyphenylboronic acid manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: (4-hydroxyphenyl)boronic acid 71597-85-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 1000KG/month
Release date: 2021-11-02

Henan Fengda Chemical Co., Ltd

Product: 4-Hydroxyphenylboronic acid 71597-85-8
Price: US $34.00-1.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-08

Hebei Xinsheng New Material Technology Co., LTD.

Product: 4-Hydroxyphenylboronic acid 71597-85-8
Price: US $35.00-25.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 Ton
Release date: 2023-10-30

71597-85-8, 4-Hydroxyphenylboronic acidRelated Search:

Triclosan Phenylboronic acid 4-Methoxyphenol 3-Hydroxybenzoic acid 4-Carboxyphenylboronic acid 4-Hydroxybenzaldehyde 2-Hydroxyphenylacetic acid 4-Hydroxybenzoic acid 4-Aminophenylboronic acid 4-Cyanophenol Methylparaben 3-Carboxyphenylboronic acid 1,4-Benzodioxane-6-boronic acid 4-Trifluoromethoxyphenylboronic acid 4-(N-OCTYLOXY)BENZENEBORONIC ACID 3-Hydroxyphenylboronic acid Carboxy styrene-butadiene latex 2,4-Dimethoxybenzeneboronic acid

RARECHEM AH PB 0222

(P-HYDROXYPHENYL)BORONIC ACID

BORONIC ACID, (4-HYDROXYPHENYL)-

4-Boronophenol~4-Hydroxyphenylboronic acid

4-Hydroxybenzeneboronic

4-BORONOPHENOL

4-HYDROXYPHENYLBORONIC ACID

4-HYDROXYBENZENEBORONIC ACID

AKOS BRN-0188

4-DIHYDROXYBORANYL-PHENOL

4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)

4-Hydroxybenzeneboronic acid 97%

4-Hydroxyphenylboronic acid,97%

4-Hydroxyphenylboronic acid ,98%

4-Hydroxyphenylboronic acid, 97% 1GR

4-Hydroxyphenylboronic acid, 97% 5GR

Boronic acid, B-(4-hydroxyphenyl)-

BORONIC ACID, B-(4-HYDROXYPHENYL)-;

4-Hydroxyphenylboronic acid (contains Anhydride)

p-hydroxy-benzeneboronic acid

4-Hydroxyphenylboronic acid >=95.0%

4-Hydroxyphenylboronicaci

ACF2

B-(4-Hydroxyphenyl)boronic acid

71597-85-8

71579-85-8

C5H7BO2

C6H7BO3

C6H7O3B

BORONIC ACID

Boronic Acids and Derivatives

Boronic Acids

Aryl

Organometallic Reagents

OLED materials,pharm chemical,electronic

Boronate Ester

Potassium Trifluoroborate

Boronic Acids

Boronic Acid

Boronic Acids

Boronic Acids and Derivatives

Organic acids

B (Classes of Boron Compounds)

Alcohols and Derivatives

Boron, Nitrile, Thio,& TM-Cpds

Aryl

Organoborons

blocks

BoronicAcids

bc0001