4-Hydroxyphenylboronic acid

Product Name: 4-Hydroxyphenylboronic acid
CAS No.: 71597-85-8
Chemical Name: 4-Hydroxyphenylboronic acid
Synonyms: ACF2;AKOS BRN-0188;4-BORONOPHENOL;RARECHEM AH PB 0222;4-Hydroxybenzeneboronic;4-DIHYDROXYBORANYL-PHENOL;4-Hydroxyphenylboronicaci;4-HYDROXYPHENYLBORONIC ACID;4-HYDROXYBENZENEBORONIC ACID;(P-HYDROXYPHENYL)BORONIC ACID
CBNumber: CB5691083
Molecular Formula: C6H7BO3
Formula Weight: 137.93
MOL File: 71597-85-8.mol

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4-Hydroxyphenylboronic acid Property

Melting point:: >230 °C (lit.)
Boiling point:: 351.4±44.0 °C(Predicted)
Density: 1.32±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: Powder
pka: 9.09±0.10(Predicted)
color: Off-white to light brown
Water Solubility: 25 g/L
BRN: 2963491
InChIKey: COIQUVGFTILYGA-UHFFFAOYSA-N
CAS DataBase Reference: 71597-85-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,C
Risk Statements: 36/37/38-34
Safety Statements: 26-36-37/39-45-36/37/39-27
WGK Germany: 3
TSCA: No
HS Code: 2931 90 00
HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.43854
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥97% (acidimetric)
Packaging: 1g
Price: $75.7
Updated: 2023/01/07

Sigma-Aldrich

Product number: 8.43854
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥97% (acidimetric)
Packaging: 5G
Price: $271
Updated: 2023/01/07

Sigma-Aldrich

Product number: 523976
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥95.0%
Packaging: 1g
Price: $59.8
Updated: 2023/01/07

Sigma-Aldrich

Product number: 523976
Product name: 4-Hydroxyphenylboronic acid
Purity: ≥95.0%
Packaging: 5g
Price: $129
Updated: 2023/01/07

TCI Chemical

Product number: H1228
Product name: 4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $42
Updated: 2023/01/07

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4-Hydroxyphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

off-white to light brown powder

Uses

suzuki reaction

Uses

4-Hydroxybenzeneboronic acid is used for Suzuki-Miyaura coupling and Stille coupling and potential for introducing different alkyl groups, palladium-catalyzed aminocarbonylation and cross-coupling reactions, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles. It is also used in preparation of rod-like dendronized polymers.

Uses

4-Hydroxyphenylboronic acid can be used as a reactant in:

Suzuki-Miyaura coupling and Stille coupling reactions.
Palladium-catalyzed aminocarbonylation and cross-coupling reactions.
Suzuki reaction for preparation of bio-supported palladium nanoparticles as phosphine-free catalysts.
Cu₂O-catalyzed aerobic oxidative cross-coupling of tetrazoles.

It can also be used to prepare/promote:

PDK1 inhibitory activity (cancer cell growth, survival, and tumorigenesis inhibitor).
Rod-like dendronized polymers containing G4 and G5 ester dendrons via macromonomer approach by living ROMP.
Estrone-derived cyclopamine analogs as Sonic Hedgehog signaling inhibitors for anti-cancer chemotherapeutics.
Enzymatic inhibitors for the treatment of Gram-negative bacterial infections.
Oligoarenes by Suzuki-Miyaura palladium-catalyzed cross-coupling.

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 6705, 1996 DOI: 10.1016/S0040-4039(96)01468-2

4-Hydroxyphenylboronic acid Preparation Products And Raw materials

Raw materials

Tetrahydrofuran 4-Bromophenol Triisopropyl borate n-Butyllithium

Preparation Products

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4-Hydroxyphenylboronic acid Suppliers

Americas 1 Belgium 1 Canada 1 China 321 Europe 3 France 1 Germany 10 India 8 Japan 2 Jordan 1 Russia 1 Switzerland 1 Ukraine 1 United Kingdom 12 United States 39 Global 403

AllyChem Co., Ltd.

Tel: 041187549848 13889470786
Fax: 0411-87549748
Email: sales@allychem.com
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J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
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PharmaBlock Sciences (Nanjing),Inc.

Tel: 400-0255188 13770978108
Fax: 86-025-86918232
Email: sales@pharmablock.com
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Meryer (Shanghai) Chemical Technology Co., Ltd.

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Fax: 86-21-61259102
Email: market03@meryer.com
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INTATRADE GmbH

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Email: sales@intatrade.de
Country: Germany
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Alfa Aesar

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TAIYUAN RHF CO.,LTD.

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TCI (Shanghai) Development Co., Ltd.

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ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 qq:2355568890
Fax: 0086-21-50182339
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BeiJing Hwrk Chemicals Limted

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View Lastest Price from 4-Hydroxyphenylboronic acid manufacturers

Henan DaKen Chemical CO.,LTD.

Product: (4-hydroxyphenyl)boronic acid 71597-85-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 1000KG/month
Release date: 2021-11-02

LY Global chemicals co.,ltd .

Product: 4-Hydroxyphenylboronic acid 71597-85-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%Min
Supply Ability: 1000kg
Release date: 2023-03-12

Baoji Guokang Healthchem co.,ltd

Product: 4-Hydroxyphenylboronic acid 71597-85-8
Price: US $750.00/ASSAYS
Min. Order: 10g
Purity: 99%
Supply Ability: 10tons
Release date: 2021-06-07

71597-85-8, 4-Hydroxyphenylboronic acidRelated Search:

1,4-Benzodioxane-6-boronic acid 4-Trifluoromethoxyphenylboronic acid 4-(N-OCTYLOXY)BENZENEBORONIC ACID 4-Hydroxybenzoic acid 4-Aminophenylboronic acid 4-Cyanophenol Methylparaben 3-Carboxyphenylboronic acid 3-Hydroxyphenylboronic acid 2-Hydroxyphenylacetic acid Carboxy styrene-butadiene latex 4-Hydroxyphenylboronic acid Triclosan Phenylboronic acid 4-Methoxyphenol 3-Hydroxybenzoic acid p-Carboxylphenylacetic acid 4-Carboxyphenylboronic acid

RARECHEM AH PB 0222

(P-HYDROXYPHENYL)BORONIC ACID

BORONIC ACID, (4-HYDROXYPHENYL)-

4-Boronophenol~4-Hydroxyphenylboronic acid

4-Hydroxybenzeneboronic

4-BORONOPHENOL

4-HYDROXYPHENYLBORONIC ACID

4-HYDROXYBENZENEBORONIC ACID

AKOS BRN-0188

4-DIHYDROXYBORANYL-PHENOL

4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)

4-Hydroxybenzeneboronic acid 97%

4-Hydroxyphenylboronic acid,97%

4-Hydroxyphenylboronic acid ,98%

4-Hydroxyphenylboronic acid, 97% 1GR

4-Hydroxyphenylboronic acid, 97% 5GR

Boronic acid, B-(4-hydroxyphenyl)-

BORONIC ACID, B-(4-HYDROXYPHENYL)-;

4-Hydroxyphenylboronic acid (contains Anhydride)

p-hydroxy-benzeneboronic acid

4-Hydroxyphenylboronic acid >=95.0%

4-Hydroxyphenylboronicaci

ACF2

71597-85-8

71579-85-8

C5H7BO2

C6H7BO3

C6H7O3B

BORONIC ACID

Boronic Acids and Derivatives

Boronic Acids

Aryl

Organometallic Reagents

OLED materials,pharm chemical,electronic

Boronate Ester

Potassium Trifluoroborate

Boronic Acids

Boronic Acid

Boronic Acids

Boronic Acids and Derivatives

Organic acids

B (Classes of Boron Compounds)

Alcohols and Derivatives

Boron, Nitrile, Thio,& TM-Cpds

Aryl

Organoborons

blocks

BoronicAcids

bc0001