ChemicalBook > CAS DataBase List > 4-Hydroxyphenylboronic acid
4-Hydroxyphenylboronic acid
- Product Name
- 4-Hydroxyphenylboronic acid
- CAS No.
- 71597-85-8
- Chemical Name
- 4-Hydroxyphenylboronic acid
- Synonyms
- ACF2;AKOS BRN-0188;4-BORONOPHENOL;RARECHEM AH PB 0222;4-Hydroxybenzeneboronic;4-DIHYDROXYBORANYL-PHENOL;4-Hydroxyphenylboronicaci;4-HYDROXYPHENYLBORONIC ACID;4-HYDROXYBENZENEBORONIC ACID;(P-HYDROXYPHENYL)BORONIC ACID
- CBNumber
- CB5691083
- Molecular Formula
- C6H7BO3
- Formula Weight
- 137.93
- MOL File
- 71597-85-8.mol
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4-Hydroxyphenylboronic acid Property
- Melting point:
- >230 °C (lit.)
- Boiling point:
- 351.4±44.0 °C(Predicted)
- Density
- 1.32±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- soluble in Acetonitrile, DMSO, Methanol
- form
- Powder
- pka
- 9.09±0.10(Predicted)
- color
- Off-white to light brown
- Water Solubility
- 25 g/L
- BRN
- 2963491
- InChIKey
- COIQUVGFTILYGA-UHFFFAOYSA-N
- CAS DataBase Reference
- 71597-85-8(CAS DataBase Reference)
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Safety
- Hazard Codes
- Xi,C
- Risk Statements
- 36/37/38-34
- Safety Statements
- 26-36-37/39-45-36/37/39-27
- WGK Germany
- 3
- TSCA
- No
- HS Code
- 2931 90 00
- HazardClass
- IRRITANT
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 8.43854
- Product name
- 4-Hydroxyphenylboronic acid
- Purity
- ≥97% (acidimetric)
- Packaging
- 1g
- Price
- $80.1
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 8.43854
- Product name
- 4-Hydroxyphenylboronic acid
- Purity
- ≥97% (acidimetric)
- Packaging
- 5G
- Price
- $287
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 523976
- Product name
- 4-Hydroxyphenylboronic acid
- Purity
- ≥95.0%
- Packaging
- 1g
- Price
- $62.2
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 523976
- Product name
- 4-Hydroxyphenylboronic acid
- Purity
- ≥95.0%
- Packaging
- 5g
- Price
- $134
- Updated
- 2024/03/01
TCI Chemical
- Product number
- H1228
- Product name
- 4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $44
- Updated
- 2024/03/01
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4-Hydroxyphenylboronic acid Chemical Properties,Usage,Production
Chemical Properties
off-white to light brown powder
Uses
4-Hydroxybenzeneboronic acid is used for Suzuki-Miyaura coupling and Stille coupling and potential for introducing different alkyl groups, palladium-catalyzed aminocarbonylation and cross-coupling reactions, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles. It is also used in preparation of rod-like dendronized polymers.
Uses
4-Hydroxyphenylboronic acid can be used as a reactant in:
- Suzuki-Miyaura coupling and Stille coupling reactions.
- Palladium-catalyzed aminocarbonylation and cross-coupling reactions.
- Suzuki reaction for preparation of bio-supported palladium nanoparticles as phosphine-free catalysts.
- Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles.
It can also be used to prepare/promote:
- PDK1 inhibitory activity (cancer cell growth, survival, and tumorigenesis inhibitor).
- Rod-like dendronized polymers containing G4 and G5 ester dendrons via macromonomer approach by living ROMP.
- Estrone-derived cyclopamine analogs as Sonic Hedgehog signaling inhibitors for anti-cancer chemotherapeutics.
- Enzymatic inhibitors for the treatment of Gram-negative bacterial infections.
- Oligoarenes by Suzuki-Miyaura palladium-catalyzed cross-coupling.
Synthesis Reference(s)
Tetrahedron Letters, 37, p. 6705, 1996 DOI: 10.1016/S0040-4039(96)01468-2
4-Hydroxyphenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Hydroxyphenylboronic acid manufacturers
Henan Fengda Chemical Co., Ltd
- Product
- 4-Hydroxyphenylboronic acid 71597-85-8
- Price
- US $34.00-1.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
Shanghai Daken Advanced Materials Co.,Ltd
- Product
- (4-hydroxyphenyl)boronic acid 71597-85-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 1000KG/month
- Release date
- 2021-11-02
Hebei Xinsheng New Material Technology Co., LTD.
- Product
- 4-Hydroxyphenylboronic acid 71597-85-8
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-10-30
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