4-Chlorobenzyl alcohol

Description Referrence

Product Name: 4-Chlorobenzyl alcohol
CAS No.: 873-76-7
Chemical Name: 4-Chlorobenzyl alcohol
Synonyms: (4-CHLOROPHENYL)METHANOL;4-chlorobenzyl;ai3-20628;p-Chlorotoluol;RARECHEM AL BD 0077;4-Chlorobenzyl alcoh;p-chloro-benzylalcoho;Chlorophenyl Methanol;P-CHLOROBENZYL ALCOHOL;LABOTEST-BB LT02085068
CBNumber: CB2714497
Molecular Formula: C7H7ClO
Formula Weight: 142.58
MOL File: 873-76-7.mol

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4-Chlorobenzyl alcohol Property

Melting point:: 68-71 °C(lit.)
Boiling point:: 234 °C(lit.)
Density: 1.1104 (rough estimate)
refractive index: 1.5390 (estimate)
Flash point:: 70 °C
storage temp.: Sealed in dry,Room Temperature
solubility: 2.5g/l
pka: 14.16±0.10(Predicted)
form: Crystalline Needles or Powder
color: Almost white to beige
Water Solubility: Soluble in water (2.5 mg/ml at 20°C), and methanol.
BRN: 636502
Stability:: Stable. Incompatible with acid chlorides, acid anhydrides, acids, oxidizing agents. Combustible.
CAS DataBase Reference: 873-76-7(CAS DataBase Reference)
NIST Chemistry Reference: 4-Chlorobenzyl alcohol(873-76-7)
EPA Substance Registry System: 4-Chlorobenzenemethanol (873-76-7)

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
RTECS: DN9242000
HS Code: 29062900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C27115
Product name: 4-Chlorobenzyl alcohol
Purity: 99%
Packaging: 25g
Price: $120
Updated: 2024/03/01

TCI Chemical

Product number: C0565
Product name: 4-Chlorobenzyl Alcohol
Purity: >99.0%(GC)
Packaging: 25g
Price: $85
Updated: 2024/03/01

Alfa Aesar

Product number: A11504
Product name: 4-Chlorobenzyl alcohol, 99%
Packaging: 25g
Price: $53.65
Updated: 2024/03/01

Alfa Aesar

Product number: A11504
Product name: 4-Chlorobenzyl alcohol, 99%
Packaging: 100g
Price: $146.65
Updated: 2024/03/01

Sigma-Aldrich

Product number: C27115
Product name: 4-Chlorobenzyl alcohol
Purity: 99%
Packaging: 100g
Price: $175.2
Updated: 2024/03/01

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4-Chlorobenzyl alcohol Chemical Properties,Usage,Production

Description

It is usually used as the intermediate in organic synthesis and pharmaceutical industry. Specifically, this chemical can react with o-xylene in the presence of HAuCl4 or AuCl3 at 80 ℃ to generate the corresponding benzylated product.¹ Moreover, the acetylation of 4-chlorobenzyl alcohol in presence of catalytic amounts of Ce(OTf)4 has been performed in acetic acid to produce the desired esters in the excellent yields.² In addition, this chemical may function as the raw material to produce its corresponding carboxylic acids and ketones in good yields through the oxidation reaction by using hydrogen peroxide and cobalt(Ⅱ) complex.³ Besides, the formylation and acetylation of 4-chlorobenzyl alcohol may be carried out in the presence of Silphos [PCl3?n(SiO2)n] in ethyl formate and ethyl acetate.⁴

Referrence

Mertins, K.; Lovel, I.; Kischel, J.; Zapf, A.; Beller, M., Gold-catallyzed benzylation of arenes and heteroarenes. Adv. Synth. Catal. 2006, 348, 691-695.
Iranpoor, N.; Shekarriz, M., Catalytic Esterification of Alcohols, Carboxylic Acids and Transesterification Reactions with Cerium(IV) Triflate. Bull. Chem. Soc. Jpn. 1999, 72, 455-458.
Das, S.; Punniyamurthy, T., Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide. Tetrahedron Lett. 2003, 44, 6033-6035.
Iranpoor, N.; Firouzabadi, H.; Jamalian, A., Silphos PCl3-n(SiO2)(n) : a heterogeneous phosphine reagent for formylation and acetylation of alcohols and amines with ethyl formate and acetate. Tetrahedron Lett. 2005, 46, 7963-7966.

Chemical Properties

white crystalline powder

Uses

Reagent for carboxyl group protection.

Uses

4-Chlorobenzyl alcohol acts as a reagent for the protection of carboxyl groups as their 4-chlorobenzyl esters, more stable to acid than the corresponding benzyl esters. It is used as solvent in paint stripper and waterborne coatings. It acts as curing agent. It is also used in pharmaceuticals, cosmetics, preservatives, and flavoring & fragrance agents.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 681, 1960 DOI: 10.1021/ja01488a045

4-Chlorobenzyl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Chlorobenzyl alcohol Suppliers

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View Lastest Price from 4-Chlorobenzyl alcohol manufacturers

Speranza Chemical Co., Ltd.

Product: 4-Chlorobenzyl alcohol 873-76-7
Price: US $100.00/kg
Min. Order: 25kg
Purity: 98%
Supply Ability: 300 tons
Release date: 2023-09-05

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4-Chlorobenzyl alcohol 873-76-7
Price: US $30.00-10.00/kg
Min. Order: 10kg
Purity: 99%
Supply Ability: 100000kg
Release date: 2024-08-23

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Chlorobenzyl alcohol 873-76-7
Price: US $10.00-8.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2022-09-19

873-76-7, 4-Chlorobenzyl alcoholRelated Search:

2-Chlorobenzaldehyde Benzyl alcohol 1,2,4-Trichlorobenzene 1,3-Dichlorobenzene Chlorphenamine maleate 1,2-Dichlorobenzene Ethyl acetate 4,4'-DICHLORO-ALPHA-METHYLBENZHYDROL 3,4-Dichlorobenzoic acid 4-CHLOROPHTHALIC ACID MONOSODIUM SALT ALPHA-(CHLOROMETHYL)-2,4-DICHLOROBENZYL ALCOHOL 2,4-DICHLORO-ALPHA-METHYLBENZYL ALCOHOL 4-Chloro-2-methoxybenzoic acid p-Dichlorobenzene IMP. A (EP): CHLORPHENAMINE (USP: CHLORPHENIRAMINE) 4,4'-Dichlorobenzhydrol 3,4-Dichlorobenzyl alcohol 4-Chlorobenzhydrol

4-CHLOROBENZYL ALCOHOL

(4-CHLOROPHENYL)METHANOL

4-chlorobenzylic alcohol

4-Chlorobenzylalcohol,99%

LABOTEST-BB LT02085068

P-CHLOROBENZYL ALCOHOL

RARECHEM AL BD 0077

4-chloro-benzenemethano

4-chlorobenzenemethanol

4-chlorobenzyl

ai3-20628

Benzenemethanol, 4-chloro-

Benzyl alcohol, p-chloro-

p-chloro-benzylalcoho

4-Chlorobenzyl alcohol 98%

4- CHLOROMETHYL ALCOHOL

PARA-CHLOROBENZYLALCOHOL

p-Chlorotoluol

1-Hydroxymethyl-4-chlorobenzene

4-Chlorobenzyl alcoh

Chlorophenyl Methanol

4-CHLOROBENZYL ALCOHOL FOR SYNTHESIS

4-Chlorobenzyl Alcohol &gt

4-Chloro benzyl alcohol, 98%+

4-Chlorobenzyl Alcohol/Para Chlorobenzyl Alcohol

Oxiconazole Impurity 12

Chlorpheniramine Impurity 43

873-76-7

837-76-7

8763-76-7

C7H7ClO

Oxygen Compounds

Organic Building Blocks

C7 to C8

Alcohols

Building Blocks

C7 to C8

Chemical Synthesis

Organic Building Blocks

Oxygen Compounds

Benzhydrols, Benzyl & Special Alcohols

Alcohol

Alcohols

Chlorine Compounds

C7 to C8

Oxygen Compounds

Alcohols and Derivatives