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Praseodymium oxide

Product Name
Praseodymium oxide
CAS No.
12037-29-5
Chemical Name
Praseodymium oxide
Synonyms
IV);Praseodymium(III;raseodymium oxide;praseodymium oxid;PRASEODIMIUM OXIDE;PRASEODYMIUM OXIDE;Praseodymium(III,I;Praseodynium oxide;Praseodym(III,IV)oxid;PraseodyMiuM(III, IV)
CBNumber
CB2747664
Molecular Formula
O3Pr2
Formula Weight
329.81
MOL File
12037-29-5.mol
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Praseodymium oxide Property

Melting point:
2500°C
Density 
6.5 g/mL at 25 °C(lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
nanopowder
color 
Dark green to dark brown or black
Water Solubility 
insoluble
InChI
InChI=1S/3O.2Pr/q3*-2;2*+3
InChIKey
MMKQUGHLEMYQSG-UHFFFAOYSA-N
SMILES
[Pr+3].[Pr+3].[O-2].[O-2].[O-2]
CAS DataBase Reference
12037-29-5(CAS DataBase Reference)
EPA Substance Registry System
Praseodymium oxide (Pr6O11) (12037-29-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
1
RTECS 
TU1480000
TSCA 
Yes
HS Code 
28469017
Toxicity
rat,LD50,oral,> 5gm/kg (5000mg/kg),Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 12, Pg. 626, 1993.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
205176
Product name
Praseodymium(III,IV) oxide
Purity
99.9% trace metals basis
Packaging
50g
Price
$167
Updated
2024/03/01
Sigma-Aldrich
Product number
205176
Product name
Praseodymium(III,IV) oxide
Purity
99.9% trace metals basis
Packaging
250g
Price
$432.8
Updated
2024/03/01
Alfa Aesar
Product number
010914
Product name
Praseodymium(III, IV) oxide, REacton?, 99.996% (REO)
Packaging
5g
Price
$75.65
Updated
2024/03/01
Alfa Aesar
Product number
010914
Product name
Praseodymium(III, IV) oxide, REacton?, 99.996% (REO)
Packaging
25g
Price
$253
Updated
2023/06/20
Strem Chemicals
Product number
93-5910
Product name
Praseodymium(III,IV) oxide (99.99%-Pr) (REO) PURATREM
Packaging
1g
Price
$29
Updated
2024/03/01
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Praseodymium oxide Chemical Properties,Usage,Production

Description

Praseodymium Oxide, or praseodymia, is a dark brown powder that is insoluble in water and only in strong acids. Praseodymium Oxide is stable under average temperatures and pressures. Praseodymium Oxide is a rare earth oxide compound, which is a basic anhydride and can react with acids and with potent reducing agents in redox reactions. Rare earth oxide compounds contain at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable, which makes them useful in ceramic structures. For this reason, Praseodymium Oxide has a wide range of applications, from producing clay bowls to advanced electronics. Praseodymium Oxide is also valuable for lightweight structural components in aerospace and electrochemical applications such as fuel cells due to its ionic conductivity.

Chemical Properties

dark green to dark brown or black powder.
Praseodymium oxide is a weak coloring oxide that melts at (1710°F)932°C. One of the lanthanide oxides, praseodymium is classified in the periodic table as a rare earth oxide. It's not used extensively in ceramics but is used in yellow stains with zirconium silicate. This oxide is slightly soluble in water and is very toxic.

Praseodymium can be obtained as an oxide but it's usually introduced into a glaze recipe in the form of a commercial stain such as Mason 6433,6405, or 6407.

Uses

Glass and ceramic pigment, laboratory reagent.

Uses

This compound is a yellow powder used to color glass and ceramics.

Uses

Used in ceramic structures. Have a wide range of applications from producing clay bowls to advanced electronics. Praseodymium oxide is also useful in light weight structural components in aerospace and electrochemical applications such as fuel cells due to its ionic conductivity. Component of didymium glass which is a colorant for welder's goggles, also as important additive of Praseodymium yellow pigments.

Application

Praseodymium oxide nanoparticle is widely used in magnetic materials. It has also applications in catalysis.

Production Methods

1. Monazite concentrates go through the alkali solution, phosphorus moving out, leaching of diluted hydrochloric acid to get the rare earth chloride solvent;
2. Next, extract with P2O4-kerosene-HCl-ReCl system to divide it into three groups, which are light, middle, and heavy rare earth;
3. Then raffinate La-Nd light rare earth is divided according to the oxalate sediment sequence, which is samarium-neodymium(Nd)-praseodymium-cerium-lanthanum;
4. oxalate sediment could produce a soluble complex and then separate and dry to get the Praseodymium oxide(Pr6O11) at 1000℃.
Chemical equation: 3Pr2(C2O4)3→Pr6O11+7CO2+11CO.

Flammability and Explosibility

Non flammable

reaction suitability

reagent type: catalyst
core: praseodymium

Purification Methods

Dissolve the oxide in acid (perchloric acid), precipitate it as the oxalate and the salt is ignited at 650o to give the oxide.

Toxics Screening Level

Due to a lack of available toxicity data by the inhalation route of exposure, the ITSL for praseodymium oxide is being set at the default value of 0.1 μg/m3 with annual averaging.

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View Lastest Price from Praseodymium oxide manufacturers

Hebei Saisier Technology Co., LTD
Product
Praseodymium oxide 12037-29-5
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-03-25
HebeiShuoshengImportandExportco.,Ltd
Product
Praseodymium oxide
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-06
Hebei Longbang Technology Co., Ltd
Product
Praseodymium oxide 12037-29-5
Price
US $6.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-30

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