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4-Mercaptopyridine

Product Name
4-Mercaptopyridine
CAS No.
4556-23-4
Chemical Name
4-Mercaptopyridine
Synonyms
NOLA-009;NSC 76036;4-Thiopyridine;4-PYRIDINETHIOL;4-Pyridimethiol;Mercaptopyridine;Pyridine-4-thiol;4-Mecaptopyridine;4-mercatopyridine;4-Sulfanylpyridine
CBNumber
CB2748207
Molecular Formula
C5H5NS
Formula Weight
111.16
MOL File
4556-23-4.mol
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4-Mercaptopyridine Property

Melting point:
182-189 °C
Boiling point:
194.0±13.0 °C(Predicted)
Density 
1.161 (estimate)
refractive index 
1.5605 (estimate)
storage temp. 
2-8°C
solubility 
DMSO, Methanol
pka
pK1:1.43(+1);pK2:8.86(0) (20°C)
form 
Crystalline Powder
color 
Yellow to yellow-green or brown
InChIKey
FHTDDANQIMVWKZ-UHFFFAOYSA-N
CAS DataBase Reference
4556-23-4(CAS DataBase Reference)
NIST Chemistry Reference
4-Pyridinethiol(4556-23-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39-24/25
WGK Germany 
3
RTECS 
UT8578000
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
148202
Product name
4-Mercaptopyridine
Purity
95%
Packaging
1g
Price
$45.8
Updated
2024/03/01
Sigma-Aldrich
Product number
148202
Product name
4-Mercaptopyridine
Purity
95%
Packaging
10g
Price
$216
Updated
2024/03/01
TCI Chemical
Product number
M0630
Product name
4-Mercaptopyridine
Purity
>97.0%(T)
Packaging
5g
Price
$79
Updated
2024/03/01
TCI Chemical
Product number
M0630
Product name
4-Mercaptopyridine
Purity
>97.0%(T)
Packaging
25g
Price
$214
Updated
2024/03/01
TRC
Product number
M225500
Product name
4-Mercaptopyridine
Packaging
1g
Price
$45
Updated
2021/12/16
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4-Mercaptopyridine Chemical Properties,Usage,Production

Chemical Properties

4-Mercaptopyridine is Yellow to light yellow crystalline powder

Uses

4-Mercaptopyridine is a pyridine derivative used as a redox reagents for the in vitro refolding of a recombinantly expressed single-chain Fv fragment (scFvOx). Used in studies along with thiosulfate to measure alliinase activity.

Uses

mercaptopyridine is also known as sodium pyrithione. It is a preservative that is not commoly used.

Uses

4-Mercaptopyridine was used as a probe molecule to study the performance of the gold nanorod (AuNR)/polycaprolactone (PCL) fibrous mesh.

Purification Methods

Purify the thiol by dissolving ~45g in boiling H2O (100mL) (charcoal), filter and precipitate it by adding 50% aqueous NaOH (~80mL) to pH ~6. Dissolve the precipitate in EtOH, evaporate it to dryness, then crystallise it from boiling EtOH (~100mL, charcoal) to give yellow flat hexagonal plates (m 186o). It sublimes readily in vacuo. [King & Ware J Chem Soc 873 1939.] The picrate forms yellow needles from H2O with m 222o(dec). The 4-methylmercaptopyridine derivative crystallises from pet ether (m 47o , also 44-45o was reported, with a pK2 0 of 5.97) and was prepared by treatment with MeI/NaOH. Its picrate has m 2 4 5o (from H2O, MeOH or EtOH). The N-methyl-4-pyridinethiol derivative has m 168.5-170o (from EtOH), a pK2 0 of 1.30 and is soluble in CHCl3. [Albert & Barlin J Chem Soc 2384 1959, Beilstein 21 II 35, 22 III/IV 373, 22/7 V 147.]

4-Mercaptopyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Mercaptopyridine Suppliers

Ring Specialty Chemicals Inc.
Tel
+1 416 493 6870
Fax
+1 416 499 9759
Email
info@ringchemicals.com
Country
Canada
ProdList
468
Advantage
58
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View Lastest Price from 4-Mercaptopyridine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
4-Mercaptopyridine 4556-23-4
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
1000kgs
Release date
2021-11-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Mercaptopyridine 4556-23-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Hebei shuoxi biotechnology co. LTD
Product
4-pyridinethiol 4556-23-4
Price
US $90.00/g
Min. Order
10g
Purity
99.8%
Supply Ability
10tons
Release date
2020-04-26

4556-23-4, 4-MercaptopyridineRelated Search:


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