ChemicalBook > CAS DataBase List > 2-CHLORO-4-METHOXYPHENOL

2-CHLORO-4-METHOXYPHENOL

Product Name: 2-CHLORO-4-METHOXYPHENOL
CAS No.: 18113-03-6
Chemical Name: 2-CHLORO-4-METHOXYPHENOL
Synonyms: 2-CHLORO-4-METHOXYPHENOL;3-CHLORO-4-HYDROXYANISOLE;2-chloro-4-methoxylphenol;Phenol, 2-chloro-4-methoxy-;2-Chloro-4-methoxyphenol,97%;2-Chloro-4-methoxyphenol >2-Chloro-4-Methoxyphenol, 97% 5GR;2-Chlorohydroquinonemonomethylether;3-Chloro-4-hydroxyanisole, 2-Chloro-p-guaiacol
CBNumber: CB3100611
Molecular Formula: C7H7ClO2
Formula Weight: 158.58
MOL File: 18113-03-6.mol

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2-CHLORO-4-METHOXYPHENOL Property

Melting point:: 41-44 °C(lit.)
Boiling point:: 241°C (rough estimate)
Density: 1.153 g/mL at 25 °C(lit.)
Flash point:: 185 °F
storage temp.: Sealed in dry,2-8°C
form: Crystalline Low Melting Solid
pka: 8.98±0.18(Predicted)
Specific Gravity: 1.153
color: White to light yellow
BRN: 1936412
CAS DataBase Reference: 18113-03-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29071990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 412007
Product name: 2-Chloro-4-methoxyphenol
Purity: 98%
Packaging: 5g
Price: $73.2
Updated: 2023/01/07

TCI Chemical

Product number: C1487
Product name: 2-Chloro-4-methoxyphenol
Purity: >98.0%(GC)
Packaging: 5g
Price: $154
Updated: 2025/07/31

TCI Chemical

Product number: C1487
Product name: 2-Chloro-4-methoxyphenol
Purity: >98.0%(GC)
Packaging: 25g
Price: $540
Updated: 2025/07/31

TRC

Product number: C596683
Product name: 2-Chloro-4-methoxyphenol
Packaging: 250mg
Price: $45
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK100642
Product name: 2-Chloro-4-methoxyphenol
Purity: 97%
Packaging: 5g
Price: $51
Updated: 2021/12/16

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2-CHLORO-4-METHOXYPHENOL Chemical Properties,Usage,Production

Chemical Properties

WHITE TO LIGHT YELLOW CRYST. LOW MELTING SOLID

Synthesis

935-50-2

18113-03-6

General procedure for the synthesis of 2-chloro-4-methoxyphenol from 4,4-dimethoxycyclohexa-2,5-dien-1-one: 4,4-dimethoxycyclohexa-2,5-dien-1-one (1.0 mmol) was added to the reaction vessel, followed by the addition of a solution of 1,4-dioxane in 4N HCl (0.5 mL, 2 mmol) dropwise. The yellow color of the reaction mixture faded rapidly. After completion of the reaction, the solvent was removed by vacuum evaporation. The residue was diluted with ethyl acetate (10 mL) and washed with saturated aqueous NaHCO3 solution (5 mL). The organic layer was dried with anhydrous Na2SO4, filtered and concentrated to give 2-chloro-4-methoxyphenol in 95% yield. If necessary, it can be purified by column chromatography using ethyl acetate/hexane gradient elution.

References

[1] Organic and Biomolecular Chemistry, 2014, vol. 12, # 18, p. 2854 - 2858
[2] Tetrahedron Letters, 2016, vol. 57, # 1, p. 15 - 19

2-CHLORO-4-METHOXYPHENOL Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-CHLORO-4-METHOXYPHENOL manufacturers

Career Henan Chemical Co

Product: 2-CHLORO-4-METHOXYPHENOL 18113-03-6
Price: US $2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customise
Release date: 2018-08-09

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Phenol, 2-chloro-4-methoxy-

18113-03-6

C7H7ClO2

ClC6H3OCH3OH

Building Blocks

Oxygen Compounds

Phenols

Organic Building Blocks

Aromatic Hydrocarbons (substituted) & Derivatives

Phenol&Thiophenol&Mercaptan

Anisoles, Alkyloxy Compounds & Phenylacetates

Chlorine Compounds

Phenols

Organic Building Blocks

Oxygen Compounds