2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER

Product Name: 2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER
CAS No.: 13051-21-3
Chemical Name: 2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER
Synonyms: 3-Methoxy-2,2-diMethyl-3-oxopropanoic acid;2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER;Propanedioic acid, 2,2-dimethyl-, 1-methyl ester
CBNumber: CB31009847
Molecular Formula: C6H10O4
Formula Weight: 146.14
MOL File: 13051-21-3.mol

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2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER Property

Melting point:: 35-38 °C
Boiling point:: 78.5 °C(Press: 20 Torr)
Density: 1.0624 g/cm3
storage temp.: Sealed in dry,Room Temperature
pka: 2.92±0.36(Predicted)
Appearance: Colorless to off-white <35°C Solid,>38°C Liquid

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Safety

HS Code: 2917198090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M269738
Product name: 3-Methoxy-2,2-dimethyl-3-oxopropanoicacid
Packaging: 100mg
Price: $45
Updated: 2021/12/16

Apolloscientific

Product number: OR903534
Product name: 3-Methoxy-2,2-dimethyl-3-oxopropanoicacid
Purity: 98%
Packaging: 1g
Price: $115
Updated: 2021/12/16

Apolloscientific

Product number: OR903534
Product name: 3-Methoxy-2,2-dimethyl-3-oxopropanoicacid
Purity: 98%
Packaging: 5g
Price: $356
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0382545
Product name: 3-METHOXY-2,2-DIMETHYL-3-OXOPROPANOIC ACID
Purity: 95.00%
Packaging: 5MG
Price: $501.62
Updated: 2021/12/16

AK Scientific

Product number: X0146
Product name: 2,2-Dimethylmalonicacidmonomethylester
Packaging: 10g
Price: $611
Updated: 2021/12/16

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2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER Chemical Properties,Usage,Production

Synthesis

67-56-1

15568-97-5

13051-21-3

To a round-bottomed flask containing a solution of THF:MeOH (50 mL, 1:5, v/v) with KOH (46.46 mmol) was slowly added 2,2,5,5-tetramethyl-1,3-dioxane-4,6-dione (11.61 mmol) at 0 °C. The reaction mixture was stirred at room temperature for 24 hours. After completion of the reaction, the mixture was poured into a solution of 1 M HCl (50 mL) and extracted with ether. The organic phases were combined, washed with saturated brine, dried over anhydrous Na2SO4, filtered and concentrated under reduced pressure to give monomethyl 2,2-dimethylmalonate in 88% yield.

References

[1] European Journal of Medicinal Chemistry, 2013, vol. 64, p. 169 - 178

2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER Suppliers

China 47 India 1 United States 4 Global 52

Changzhou Huanling Chemical Co., Ltd.

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View Lastest Price from 2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 3-Methoxy-2,2-dimethyl-3-oxopropanoic acid 13051-21-3
Price: US $3.90-5.90/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-13

Career Henan Chemical Co

Product: 2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER 13051-21-3
Price: US $1.00/g
Min. Order: 1g
Purity: ≥98%
Supply Ability: g/kg/Ton
Release date: 2019-12-25

13051-21-3, 2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTERRelated Search:

Diethyl 1,1-cyclopropanedicarboxylate Diethyl 1,1-cyclobutanedicarboxylate BIS[(12-CROWN-4)METHYL] DODECYLMETHYLMALONATE DIETHYL DIMETHYLMALONATE Diethyl dipropylmalonate Diethyl ethyl(isoamyl)malonate DIALLYL GLUTARATE DIETHYL DIETHYLMALONATE DIETHYL BIS(2-CYANOETHYL)MALONATE DIETHYL DIALLYLMALONATE Dimethyl diethylmalonate Diethyl 2-ethyl-2-phenylmalonate Diethyl bis(hydroxymethyl)malonate Diethyl dibutylmalonate DIETHYL 2-ETHYL-2-(P-TOLYL)MALONATE DIETHYL METHYLPHENYLMALONATE TRIETHYL 1-CYANO-3,3,4-PENTANE-TRICARBOXYLATE ALLYL-1-METHYLBUTYLDIETHYL MALONATE

2,2-DIMETHYL-MALONIC ACID MONOMETHYL ESTER

3-Methoxy-2,2-diMethyl-3-oxopropanoic acid

Propanedioic acid, 2,2-dimethyl-, 1-methyl ester

13051-21-3