DIETHYL DIALLYLMALONATE
- Product Name
- DIETHYL DIALLYLMALONATE
- CAS No.
- 3195-24-2
- Chemical Name
- DIETHYL DIALLYLMALONATE
- Synonyms
- diethyldiallylmalonat;DIETHYL DIALLYLMALONATE;Valproic Acid Impurity 19;Diethyl diallylmalonate 98%;DIETHYL 2,2-DIALLYLMALONATE;Diethyl Diallylmalonate >DIETHYL DI-2-PROPENYLMALONATE;dienepropyldiacidiethyl ester;DIALLYLMALONIC ACID DIETHYL ESTER;Diethyl-2-allyl-2-butenylmalonate
- CBNumber
- CB6278931
- Molecular Formula
- C13H20O4
- Formula Weight
- 240.3
- MOL File
- 3195-24-2.mol
DIETHYL DIALLYLMALONATE Property
- Boiling point:
- 128-130 °C/12 mmHg (lit.)
- Density
- 0.994 g/mL at 25 °C (lit.)
- vapor pressure
- 4.266Pa at 25℃
- refractive index
- n20/D 1.446(lit.)
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform, DMSO, Methanol
- form
- Oil
- color
- Clear Colourless
- Water Solubility
- Sparingly Soluble in water. (0.72 g/L) (25°C)
- BRN
- 1790529
- InChI
- 1S/C13H20O4/c1-5-9-13(10-6-2,11(14)16-7-3)12(15)17-8-4/h5-6H,1-2,7-10H2,3-4H3
- InChIKey
- LYUUVYQGUMRKOV-UHFFFAOYSA-N
- SMILES
- CCOC(=O)C(CC=C)(CC=C)C(=O)OCC
- LogP
- 3.46
- CAS DataBase Reference
- 3195-24-2(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 283479
- Product name
- Diethyl diallylmalonate
- Purity
- 98%
- Packaging
- 5g
- Price
- $60.61
- Updated
- 2025/07/31
- Product number
- 283479
- Product name
- Diethyl diallylmalonate
- Purity
- 98%
- Packaging
- 25g
- Price
- $232
- Updated
- 2025/07/31
- Product number
- D1183
- Product name
- Diethyl Diallylmalonate
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $165
- Updated
- 2025/07/31
- Product number
- D1183
- Product name
- Diethyl Diallylmalonate
- Purity
- min. 98.0 %
- Packaging
- 100ML
- Price
- $494
- Updated
- 2025/07/31
- Product number
- D444190
- Product name
- Diethyl diallylmalonate
- Packaging
- 1g
- Price
- $120
- Updated
- 2021/12/16
DIETHYL DIALLYLMALONATE Chemical Properties,Usage,Production
Uses
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Definition
ChEBI: Diethyl diallylmalonate is a fatty acid ester.
General Description
Low catalyst loading in ring-closing metathesis reaction of diethyl diallylmalonate has been reported. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Synthesis
To a mixture of diethyl malonate (10 g, 62.5 mmol) and allyl bromide (14.25 g, 187.5 mmol), a concentrated solution of sodium ethanolate (70 mL ethanol solution of 8.6 g sodium) was slowly added between 5-10??C with continuous stirring. After the addition of sodium ethoxide, the reaction mixture was stirred at the same temperature for another 1 h. The cold water bath was then removed and the mixture was stirred at room temperature overnight. The excess solvent was removed and the residue was added to water and extracted with ethyl acetate. The organic phase was dried over Na2SO4 and evaporated to give a light yellow liquid. The crude substance was purified by vacuum distillation to give a colorless liquid.
DIETHYL DIALLYLMALONATE Preparation Products And Raw materials
Raw materials
Preparation Products
DIETHYL DIALLYLMALONATE Suppliers
- Tel
- 022-83946278 13820503911
- Fax
- 022-83945176
- sales@creasyn.com
- Country
- China
- ProdList
- 991
- Advantage
- 68
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 13355009207 13355009207
- Fax
- 0539-6365991
- 3007715519@qq.com
- Country
- China
- ProdList
- 18729
- Advantage
- 57
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12984
- Advantage
- 57
- Tel
- 86-21-63210123
- Fax
- 86-21-63290778 86-21-63218885
- sj_scrc@sinopharm.com
- Country
- China
- ProdList
- 9815
- Advantage
- 79
- Tel
- +86 (573) 82222445 (0)18006601000 452520369
- Fax
- +86 (573) 82222643
- sales@maya-r.com
- Country
- China
- ProdList
- 11707
- Advantage
- 57
- Tel
- 800-810-5118
- Fax
- +86-10-84193589
- cnchemical@thermofisher.com
- Country
- China
- ProdList
- 17770
- Advantage
- 75
View Lastest Price from DIETHYL DIALLYLMALONATE manufacturers
- Product
- DIETHYL DIALLYLMALONATE 3195-24-2
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 85.0-99.8%
- Supply Ability
- 20tons
- Release date
- 2020-10-28