2(1H)-Pyrimidinone, hydrazone (9CI)

Product Name: 2(1H)-Pyrimidinone, hydrazone (9CI)
CAS No.: 7504-94-1
Chemical Name: 2(1H)-Pyrimidinone, hydrazone (9CI)
Synonyms: 2-HydrazinylpyriMidine;2-Pyrimidinylhydrazine;Pyrimidine, 2-hydrazinyl-;1-(2-Pyrimidinyl)hydrazine;2(1H)-Pyrimidinone hydrazone;1-(Pyrimidine-2-yl)hydrazine;2-Hydrazono-2,3-dihydropyrimidine;2(1H)-Pyrimidinone, hydrazone (9CI);2-hydrazinopyrimidine(SALTDATA: FREE);2(1H)-Pyrimidinone, hydrazone (9CI) ISO 9001：2015 REACH
CBNumber: CB31081108
Molecular Formula: C4H6N4
Formula Weight: 110.12
MOL File: 7504-94-1.mol

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2(1H)-Pyrimidinone, hydrazone (9CI) Property

Melting point:: 86-88 °C(Solv: benzene (71-43-2))
Boiling point:: 246.3±23.0 °C(Predicted)
Density: 1.39±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
form: solid
pka: 6.17±0.20(Predicted)
color: Off-white
InChI: InChI=1S/C4H6N4/c5-8-4-6-2-1-3-7-4/h1-3H,5H2,(H,6,7,8)
InChIKey: QDGHXQFTWKRQTG-UHFFFAOYSA-N
SMILES: C1(NN)=NC=CC=N1
CAS DataBase Reference: 7504-94-1

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Safety

Risk Statements: 36/37/38
Safety Statements: 26
HazardClass: IRRITANT
HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 758094
Product name: 2-Hydrazinopyrimidine hydrate
Purity: 95%
Packaging: 500MG
Price: $143
Updated: 2023/06/20

TCI Chemical

Product number: H1906
Product name: 2-Hydrazinopyrimidine
Purity: min. 95.0 %
Packaging: 1G
Price: $40
Updated: 2025/07/31

TCI Chemical

Product number: H1906
Product name: 2-Hydrazinopyrimidine
Purity: min. 95.0 %
Packaging: 5G
Price: $120
Updated: 2025/07/31

TRC

Product number: H714413
Product name: 2-Hydrazinopyrimidine
Packaging: 500mg
Price: $70
Updated: 2021/12/16

Ark Pharm

Product number: AK-81374
Product name: 2-Hydrazinylpyrimidine
Purity: 97%
Packaging: 250mg
Price: $10
Updated: 2021/12/16

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2(1H)-Pyrimidinone, hydrazone (9CI) Chemical Properties,Usage,Production

Uses

2-Hydrazinopyrimidine and other pyrimidinylhydrazones have been used to study the fungicidal activity of heteroaromatic aldehyde and ketone pyrimidinylhydrazones.

Synthesis

1722-12-9

7504-94-1

The general procedure for the synthesis of 2-hydrazinopyrimidine from 2-chloropyrimidine was as follows: first, 2-chloropyrimidine (1.145 g, 20 mmol) was dissolved in ethanol (30 mL). Subsequently, an excess of 85% hydrazine hydrate (6 mL) was slowly added to the above solution under continuous stirring. The reaction mixture gradually changed to a bright yellow solution and white needle-like crystals were precipitated after 2 hours. The crystals were collected by filtration and recrystallized in ethanol to afford the target product 2-hydrazinopyrimidine in 80% yield. Next, 3-methylsalicylaldehyde (1.36 g, 10 mmol) was added to an ethanolic solution (30 mL) of 2-hydrazinopyrimidine (1.10 g, 10 mmol) and the formation of a pale yellow precipitate was immediately observed. After refluxing the reaction mixture for 3 h, the precipitate was filtered and collected and washed with ethanol to give a final light yellow H2mphp powder in 95% yield.

References

[1] Patent: WO2018/64119, 2018, A1. Location in patent: Paragraph 1484
[2] Journal of Organic Chemistry, 1999, vol. 64, # 15, p. 5644 - 5649
[3] Patent: US2003/187014, 2003, A1
[4] Journal of Coordination Chemistry, 2016, vol. 69, # 7, p. 1218 - 1225
[5] Journal of Physical Organic Chemistry, 2015, vol. 28, # 2, p. 108 - 115

2(1H)-Pyrimidinone, hydrazone (9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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2(1H)-Pyrimidinone, hydrazone (9CI) Suppliers

China 95 Europe 1 Finland 1 India 3 Ukraine 1 United Kingdom 1 United States 11 Global 113

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View Lastest Price from 2(1H)-Pyrimidinone, hydrazone (9CI) manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 2(1H)-Pyrimidinone, hydrazone (9CI) 7504-94-1
Price: US $50.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-11-13

Henan Aochuang Chemical Co.,Ltd.

Product: 2(1H)-Pyrimidinone, hydrazone (9CI) 7504-94-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-28

Shaanxi Dideu Medichem Co. Ltd

Product: 2(1H)-Pyrimidinone, hydrazone (9CI) 7504-94-1
Price: US $1.00-1.00/Kg/Drum
Min. Order: 1g
Purity: 99%
Supply Ability: 20ton
Release date: 2020-05-14

7504-94-1, 2(1H)-Pyrimidinone, hydrazone (9CI)Related Search:

2-Hydrazino-4-(trifluoromethyl)pyrimidine 2-Hydrazino-4,6-dimethylpyrimidine 2,4(1H,3H)-Pyrimidinedione, 6-methyl-, 2-hydrazone (9CI) Binodenoson 5-(4-CHLOROBENZYLOXYCARBONYL)-4-(TRIFLUOROMETHYL)PYRIMIDIN-2-YL HYDRAZINE CHEMBRDG-BB 4021967 5-(METHOXYCARBONYL)-4-(TRIFLUOROMETHYL)PYRIMIDINE-2-HYDRAZINE 2,4-DIHYDRAZINOPYRIMIDINE METHYL 2-[2-(2,3,3-TRICHLOROACRYLOYL)HYDRAZINO]-4-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBOXYLATE 4-CHLOROBENZYL 2-[2-(2,3,3-TRICHLOROACRYLOYL)HYDRAZINO]-4-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBOXYLATE 2,4-DIHYDRAZINO-5-NITRO-6-METHYLPYRIMIDINE 2,4-DIHYDRAZINO-5-NITROPYRIMIDINE 4-CHLOROBENZYL 2-[2-(2-CHLOROACETYL)HYDRAZINO]-4-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBOXYLATE 2-(CINNAMYLIDENEHYDRAZINO)-4-HYDROXY-6-METHYLPYRIMIDINE 2-HYDRAZINO-4,6-DIPHENYL-PYRIMIDINE N'-(4-HYDROXY-6-METHYLPYRIMIDIN-2-YL)ACETOHYDRAZIDE 4-(DIMETHYLAMINO)BENZALDEHYDE (4,6-DIMETHYLPYRIMIDIN-2-YL)HYDRAZONE ETHYL 2-OXO-2-(2-[4-(TRIFLUOROMETHYL)PYRIMIDIN-2-YL]HYDRAZINO)ACETATE

2(1H)-Pyrimidinone, hydrazone (9CI)

1-(2-Pyrimidinyl)hydrazine

1-(Pyrimidine-2-yl)hydrazine

2(1H)-Pyrimidinone hydrazone

2-Hydrazono-2,3-dihydropyrimidine

2-Pyrimidinylhydrazine

2-hydrazinopyrimidine(SALTDATA: FREE)

2-HydrazinylpyriMidine

Pyrimidine, 2-hydrazinyl-

2(1H)-Pyrimidinone, hydrazone (9CI) ISO 9001：2015 REACH

7504-94-1

PYRIMIDINE

Heterocycle-Pyrimidine series