ChemicalBook > CAS DataBase List > 6-Nitro-1,2,3,4-tetrahydroquinoline

6-Nitro-1,2,3,4-tetrahydroquinoline

Product Name
6-Nitro-1,2,3,4-tetrahydroquinoline
CAS No.
14026-45-0
Chemical Name
6-Nitro-1,2,3,4-tetrahydroquinoline
Synonyms
Quinoline, 1,2,3,4-tetrahydro-6-nitro-
CBNumber
CB31117320
Molecular Formula
C9H10N2O2
Formula Weight
178.19
MOL File
14026-45-0.mol
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6-Nitro-1,2,3,4-tetrahydroquinoline Property

Melting point:
161-162 °C(Solv: acetic acid, 50% (64-19-7))
Boiling point:
341.4±31.0 °C(Predicted)
Density 
1.236±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
0.87±0.20(Predicted)
Appearance
Yellow to brown Solid
InChI
InChI=1S/C9H10N2O2/c12-11(13)8-3-4-9-7(6-8)2-1-5-10-9/h3-4,6,10H,1-2,5H2
InChIKey
ASVYHMUYLBMSKW-UHFFFAOYSA-N
SMILES
N1C2=C(C=C([N+]([O-])=O)C=C2)CCC1
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Safety

HS Code 
2933499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
N497665
Product name
6-nitro-1,2,3,4-tetrahydroquinoline
Packaging
100mg
Price
$65
Updated
2021/12/16
TRC
Product number
N497665
Product name
6-nitro-1,2,3,4-tetrahydroquinoline
Packaging
500mg
Price
$240
Updated
2021/12/16
Apolloscientific
Product number
OR951068
Product name
6-Nitro-1,2,3,4-tetrahydroquinoline
Purity
96%
Packaging
250mg
Price
$115
Updated
2021/12/16
ChemScene
Product number
CS-0043686
Product name
6-Nitro-1,2,3,4-tetrahydroquinoline
Purity
98.61%
Packaging
1g
Price
$117
Updated
2021/12/16
AK Scientific
Product number
V3050
Product name
6-Nitro-1,2,3,4-tetrahydroquinoline
Packaging
250mg
Price
$124
Updated
2021/12/16
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6-Nitro-1,2,3,4-tetrahydroquinoline Chemical Properties,Usage,Production

Synthesis

613-50-3

14026-45-0

General procedure for the synthesis of 6-nitro-1,2,3,4-tetrahydroquinoline from 6-nitroquinoline: in a 10 mL Schlenk tube, Fe(OTf)2 (0.005 mmol, 1.8 mg), 6-nitroquinoline (0.5 mmol, 72 mg), Hantzsch ester A (1.25 mmol, 318 mg) and 1.0 mL of CHCl3. The reaction mixture was stirred at 40 °C for 2 hours. After completion of the reaction, the reaction solution was concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography to afford the target product 6-nitro-1,2,3,4-tetrahydroquinoline (63.8 mg, 96% yield).

References

[1] Tetrahedron Letters, 2004, vol. 45, # 16, p. 3215 - 3217
[2] ChemCatChem, 2017, vol. 9, # 13, p. 2496 - 2505
[3] Tetrahedron Letters, 2017, vol. 58, # 36, p. 3571 - 3573
[4] Chemical Communications, 2018, vol. 54, # 62, p. 8622 - 8625
[5] Chemical Science, 2017, vol. 8, # 12, p. 8164 - 8169

6-Nitro-1,2,3,4-tetrahydroquinoline Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Nitro-1,2,3,4-tetrahydroquinoline Suppliers

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View Lastest Price from 6-Nitro-1,2,3,4-tetrahydroquinoline manufacturers

Career Henan Chemical Co
Product
6-Nitro-1,2,3,4-tetrahydroquinoline 14026-45-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-09