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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine

Use Reaction
Product Name
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine
CAS No.
932710-63-9
Chemical Name
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine
Synonyms
AMPhos;AMGN-Phos;4-(di-tert-butylphosphanyl)-N,N-dimethylaniline;95% A-taPhos;Di-tert-butyl(4-diMethylaMinophenyl)phosphine;4-(Di-tert-butylphosphino)-N,N-dimethylaniline;(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95%;(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95% A-taPhos;AmtPhos;Aphos 95%
CBNumber
CB31180195
Molecular Formula
C16H28NP
Formula Weight
265.37
MOL File
932710-63-9.mol
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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Property

Melting point:
57-61°C
Boiling point:
349.1±25.0 °C(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
soluble in Acetone
pka
4.73±0.24(Predicted)
form 
crystal
color 
white to light-brown
InChI
InChI=1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3
InChIKey
IQTHEAQKKVAXGV-UHFFFAOYSA-N
SMILES
C1(N(C)C)=CC=C(P(C(C)(C)C)C(C)(C)C)C=C1
CAS DataBase Reference
932710-63-9
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
677264
Product name
(4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine
Purity
95%
Packaging
1g
Price
$80.1
Updated
2024/03/01
Sigma-Aldrich
Product number
677264
Product name
(4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine
Purity
95%
Packaging
5g
Price
$121.8
Updated
2024/03/01
TCI Chemical
Product number
D4531
Product name
(4-Dimethylaminophenyl)di-tert-butylphosphine
Packaging
1g
Price
$86
Updated
2024/03/01
TCI Chemical
Product number
D4531
Product name
(4-Dimethylaminophenyl)di-tert-butylphosphine
Packaging
5g
Price
$266
Updated
2024/03/01
Strem Chemicals
Product number
15-1248
Product name
[4-(N,N-Dimethylamino)phenyl]di-t-butylphosphine, min. 95% amphos
Packaging
1g
Price
$58
Updated
2024/03/01
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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Chemical Properties,Usage,Production

Use

Bis(di-tert-butyl)-4-dimethylaminophenylphosphine is an organophosphine compound and can be used as an organophosphine ligand.

Reaction

  1. Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride.
  2. Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions.

Uses

Amphos can be used as an electrophotographic photoreceptor, process cartridge, and image forming electrode.

Uses

Ligand used to prepare a palladium dichloride catalyst (678740) on treatment with PdCl2(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.

Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Suppliers

Americas 1 Canada 1 China 195 Europe 1 France 1 Germany 4 India 6 Japan 3 Russia 1 United Kingdom 5 United States 23 Global 241
Ark Pharm, Inc.
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View Lastest Price from Bis(di-tert-butyl)-4-dimethylaminophenylphosphine manufacturers

Henan Fengda Chemical Co., Ltd
Product
[(4-Dimethylaminophenyl)]di(tert-butyl)phosphine 932710-63-9
Price
US $200.00-1.00/KG
Min. Order
1KG
Purity
99%, 99.5% Sublimated
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-31
XINXIANG RUNYU MATERIAL CO., LTD.
Product
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine 932710-63-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.98
Supply Ability
500kg
Release date
2021-12-02
Shaanxi Dideu Medichem Co. Ltd
Product
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine 932710-63-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-27

932710-63-9, Bis(di-tert-butyl)-4-dimethylaminophenylphosphineRelated Search:

N-Phenylmaleimide N-Phenyl-bis(trifluoromethanesulfonimide) N-Methylaniline 4-Aminodiphenylamine Acetanilide FORMANILIDE 1.1'-Binaphthyl-2.2'-diphemyl phosphine Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Bis(di-tert-butyl)-4-dimethylaminophenylphosphine DI-TERT-BUTYLPHENYLPHOSPHINE

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