ChemicalBook > CAS DataBase List > Phenylpropyl aldehyde

Phenylpropyl aldehyde

Product Name
Phenylpropyl aldehyde
CAS No.
104-53-0
Chemical Name
Phenylpropyl aldehyde
Synonyms
3-PHENYLPROPANAL;HYDROCINNAMALDEHYDE;Benzenepropanal;3-PHENYLPROPIONALDEHYDE;HYDROZIMTALDEHYD;3-PHENYL-1-PROPANAL;Dihydrocinnamaldehyde;NSC 9271;FEMA 2887;Hydrocinnamide
CBNumber
CB3143311
Molecular Formula
C9H10O
Formula Weight
134.18
MOL File
104-53-0.mol
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Phenylpropyl aldehyde Property

Melting point:
-42 °C
Boiling point:
97-98 °C/12 mmHg (lit.)
Density 
1.019 g/mL at 25 °C (lit.)
vapor pressure 
15 hPa (98 °C)
FEMA 
2887 | 3-PHENYLPROPIONALDEHYDE
refractive index 
n20/D 1.523(lit.)
Flash point:
203 °F
storage temp. 
Store below +30°C.
solubility 
0.74mg/l
form 
Liquid
color 
Clear colorless to light yellow
Odor
at 10.00 % in dipropylene glycol. fresh cortex green leaf foliage balsam storax
Odor Type
green
Water Solubility 
Miscible with chloroform, dichloromethane, ethyl acetate, alcohol and ether. Immiscible with water.
Sensitive 
Air Sensitive
JECFA Number
645
BRN 
1071910
InChIKey
YGCZTXZTJXYWCO-UHFFFAOYSA-N
LogP
2.04
CAS DataBase Reference
104-53-0(CAS DataBase Reference)
NIST Chemistry Reference
3-Phenylpropanal(104-53-0)
EPA Substance Registry System
Benzenepropanal (104-53-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38-36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
2
RTECS 
MW4890000
F 
10-23
Autoignition Temperature
245 °C DIN 51794
TSCA 
Yes
HS Code 
29122900
Toxicity
LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 5000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.04542
Product name
3-Phenylpropionaldehyde
Purity
for synthesis
Packaging
100mL
Price
$84.5
Updated
2024/03/01
Sigma-Aldrich
Product number
393193
Product name
Hydrocinnamaldehyde
Purity
technical grade, 90%
Packaging
100ml
Price
$119
Updated
2024/03/01
TCI Chemical
Product number
P0217
Product name
3-Phenylpropionaldehyde
Purity
>93.0%(GC)
Packaging
25g
Price
$55
Updated
2024/03/01
TCI Chemical
Product number
P0217
Product name
3-Phenylpropionaldehyde
Purity
>93.0%(GC)
Packaging
100g
Price
$182
Updated
2024/03/01
Alfa Aesar
Product number
A10367
Product name
3-Phenylpropionaldehyde, 95%
Packaging
50g
Price
$49.2
Updated
2024/03/01
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Phenylpropyl aldehyde Chemical Properties,Usage,Production

Chemical Properties

Pale Yellow Oil

Chemical Properties

Phenylpropyl aldehyde occurs in Sri Lanka cinnamon bark oil, among others. The aldehyde is a colorless liquid with a strong, floral, slightly balsamic, heavy hyacinth-like odor. It tends to undergo self-condensation. Dihydrocinnamaldehyde can be obtained with scarcely any byproducts by selective hydrogenation of cinnamaldehyde. It is used in perfumery for hyacinth and lilac compositions.

Chemical Properties

3-Phenylpropionaldehyde has a strong, pungent, floral odor reminiscent of hyacinth with a balsamic, green, warm (almost burning) flavor.

Occurrence

Reported found in the essential oil of Ceylon cinnamon and in strawberry. Also reported found in tomato, cinnamon, cassia leaf, Gruyere de Comte cheese, beer, cooked trassi, origanum (Spanish) and strawberry.

Uses

3-Phenylpropanal (cas# 104-53-0) is a compound useful in organic synthesis.

Definition

ChEBI: 3-phenylpropanal is a benzene which is substituted by a 3-oxopropyl group at position 1. It has a role as a flavouring agent and a plant metabolite. It is an aldehyde and a member of benzenes. It is functionally related to a benzene.

Production Methods

Henylpropyl aldehyde is most commonly prepared by the partial hydrogenation of cinnamaldehyde. The 3-phenylpropanal that is formed during the hydroformylation of styrene can be separated from the isomeric 2-phenylpropanal as the bisulfite adduct. The Rosenmund reduction of dihydrocinnamoyl chloride in the presence of Pd/BaSO4 gives good yields of the aldehyde. The reaction of 2-propen-1-ol and phenylmercury chloride with CuCl2 and LiPdCl4 catalysts in methanol, and the reaction of phenyl bromide and allyl alcohol in the presence of PdCl2 and NaHCO3 in nonpolar solvents also lead to the formation of 3-phenylpropanal.

Preparation

From phenyl propionitrile; also from cinnamic aldehyde diethylacetal.

Taste threshold values

Taste characteristics at 20 ppm: green, melon, fruity and citrus.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 42, p. 1041, 1994 DOI: 10.1248/cpb.42.1041
Tetrahedron Letters, 35, p. 1275, 1994 DOI: 10.1016/0040-4039(94)88042-5

General Description

Hydrocinnamaldehyde is C=C double bond hydrogenated cinnamaldehyde. It has been synthesized by the selective hydrogenation of C=C double bond of cinnamaldehyde by various methods. Hydrocinnamaldehyde and nitromethane undergoes Henry reaction to form nitroaldols. The C1 and C3 position labelled with 13C of hydrocinnamaldehyde was subjected to mass spectrometry and the fragmentation pattern was elucidated.

Phenylpropyl aldehyde Preparation Products And Raw materials

Raw materials

Acetal trans-Cinnamaldehyde

Preparation Products

2-phenylpropionaldehyde dimethyl acetal
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Phenylpropyl aldehyde Suppliers

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View Lastest Price from Phenylpropyl aldehyde manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
3-Phenylpropanal 104-53-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99.7%
Supply Ability
200000kg
Release date
2024-04-26
Hebei Kingfiner Technology Development Co.Ltd
Product
Phenylpropyl aldehyde 104-53-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500000
Release date
2023-06-02
Hebei Guanlang Biotechnology Co., Ltd.
Product
Phenylpropyl aldehyde 104-53-0
Price
US $10.00/PCS
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2021-04-26

104-53-0, Phenylpropyl aldehydeRelated Search:

BENZYL GLYCIDYL ETHER Propionaldehyde Benzyltriethylammonium chloride Paraldehyde N,N-Dimethylbenzylamine Benzyltrimethylammonium chloride Benzyl chloride 1-Nonanal Cinnamaldehyde 4-Morpholinopiperidine Phenylpropiolaldehyde 3-Phenylpropionic acid methyl ester Ethyl 3-phenylpropionate 3-Phenylpropionic acid 3-Phenyl-1-propanol Phenylphosphonic dichloride Phenylpropiolic acid Phenylphosphinic acid

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  • C6H5CH2CH2CHO
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