2-METHYLDIPHENYLAMINE
- Product Name
- 2-METHYLDIPHENYLAMINE
- CAS No.
- 1205-39-6
- Chemical Name
- 2-METHYLDIPHENYLAMINE
- Synonyms
- Phenyl o-tolylamine;2-METHYLDIPHENYLAMINE;2-Methyl-N-phenylephrine;N-Phenyl-2-methylaniline;2-Methyl-N-phenylaniline;2-Methyl-N-phenylbenzenamine;N-(2-Methylphenyl)benzenamine;Benzenamine, 2-methyl-N-phenyl-
- CBNumber
- CB3143689
- Molecular Formula
- C13H13N
- Formula Weight
- 183.25
- MOL File
- 1205-39-6.mol
2-METHYLDIPHENYLAMINE Property
- Melting point:
- 130-140 °C
- Boiling point:
- 305 °C(Press: 727 Torr)
- Density
- 1.066±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 0.65±0.20(Predicted)
- Appearance
- Yellow to brown Solid
- InChI
- InChI=1S/C13H13N/c1-11-7-5-6-10-13(11)14-12-8-3-2-4-9-12/h2-10,14H,1H3
- InChIKey
- JTMODJXOTWYBOZ-UHFFFAOYSA-N
- SMILES
- C1(NC2=CC=CC=C2)=CC=CC=C1C
Safety
- HS Code
- 2921440020
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M3718
- Product name
- 2-Methyl-N-phenylaniline
- Purity
- min. 98.0 %
- Packaging
- 200MG
- Price
- $117
- Updated
- 2025/07/31
- Product number
- M3718
- Product name
- 2-Methyl-N-phenylaniline
- Purity
- min. 98.0 %
- Packaging
- 1G
- Price
- $351
- Updated
- 2025/07/31
- Product number
- 2698CS
- Product name
- 2-Methyl-N-phenylaniline
- Packaging
- 5g
- Price
- $385
- Updated
- 2021/12/16
- Product number
- OR54435
- Product name
- 2-Methyl-N-phenylaniline
- Packaging
- 1g
- Price
- $163
- Updated
- 2021/12/16
- Product number
- 3731-1-17
- Product name
- 2-Methyl-N-phenylaniline
- Purity
- 98%
- Packaging
- 1g
- Price
- $192
- Updated
- 2021/12/16
2-METHYLDIPHENYLAMINE Chemical Properties,Usage,Production
Synthesis
16419-60-6
62-53-3
1205-39-6
GENERAL STEPS: In a typical experiment, 2-methylphenylboronic acid (1.22 g, 10 mmol) was added to a flask containing K2CO3 (2.76 g, 20 mmol) and water (2 mL) as solvent. Aniline (0.93 g, 10 mmol) and Cu-Mn catalyst were subsequently added and the reaction mixture was stirred at room temperature. The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, the base in the reaction mixture was neutralized with 2N HCl solution and the catalyst was removed by filtration. The filtrate was washed thoroughly with water and then extracted with ethyl acetate. The organic layer was separated and concentrated and dried under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: ethyl acetate/petroleum ether, ratio 1:5) to give white crystalline 2-methyldiphenylamine (1.60 g, 95% yield). All reactions were carried out in a similar manner.
References
[1] Tetrahedron Letters, 2013, vol. 54, # 39, p. 5351 - 5354
[2] RSC Advances, 2014, vol. 4, # 90, p. 49273 - 49279
[3] Bulletin of the Korean Chemical Society, 2012, vol. 33, # 5, p. 1785 - 1787
[4] Journal of Organic Chemistry, 2006, vol. 71, # 25, p. 9522 - 9524
[5] Tetrahedron Letters, 2014, vol. 55, # 17, p. 2813 - 2817
2-METHYLDIPHENYLAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
2-METHYLDIPHENYLAMINE Suppliers
- Tel
- --
- Fax
- --
- kevinbanks@molekula.com
- Country
- United Kingdom
- ProdList
- 6140
- Advantage
- 66
View Lastest Price from 2-METHYLDIPHENYLAMINE manufacturers
- Product
- 2-Methyl-N-phenylaniline 1205-39-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 100 tons
- Release date
- 2022-01-17